Mass attenuation coefficients, water and tissue equivalence properties of some tissues by Geant4, XCOM and experimental data

The mass attenuation coefficients (μ/ρ) of some tissues such as muscle (ICRU-44), adipose (ICRP) and blood (Whole) and tissue equivalents such as soft tissue model (H63C6O28N) and water have been investigated using Geant4 simulation tool kit. Appreciable variations have been noted for μ/ρ values by changing the photon energy for the studied tissues. The simulated μ/ρ have been compared with experimental data available in the literature and theoretical XCOM results in the energy region 1 keV–100 GeV, and good agreement has been observed. Also, mass attenuation coefficients relative to water have been calculated in the entire energy region to evaluate the water equivalence of the studied tissues. It is shown that a maximum difference of 8.8 % between water and mentioned soft tissue is observed at 8 keV and soft tissue is found to be a good tissue equivalent for blood and muscle tissue

Ciprofloxacin removal from non-clinical environment: A critical review of current methods and future trend prospects

Antibiotics in the environment represent a significant threat to global public health. Ciprofloxacin (CIP) is one of the second generation groups of synthetic fluoroquinolones and the most widely used antibiotics worldwide. The current work aimed to review and analyze the current methods used for eliminating CIP and identify the ap�proaches for more advanced technologies that could provide more removal efficiency for CIP removal from the non-clinical environment. The VOSviewer software tool was used to build and visualize bibliometric networks by creating a map based on bibliographic data for keywords and most countries published on the CIP removal from the Scopus database. The present review analyses the sustainable methods for removing CIP from the non-clinical environment and highlights the most efficient techniques used to remove CIP. The adsorption process of CIP is highly efficient, with a removal percentage of 95%. The microbial electrolysis ultraviolet cell (MEUC) procedure removed 100% of CIP. The degradation of CIP by UV/H2O2/O3 and its sub-processes increased the degradation of CIP from 41.2% to 98.5%. The photocatalytic degradation exhibit 92.81% removal of CIP from wastewater samples. The three-dimensional (3D) porous graphene has excellent adsorption properties to eliminate CIP by 93% in water purification. Each method has advantages and disadvantages based on price, time and presence of toxic by-products. This review is expected to serve as a base for recent research and assist researchers in developing alternative CIP treatment approaches with more efficient removal methods

Negative Poisson’s ratio polyethylene matrix and 0.5BaCa0.8Zr0.2O3-0.5Ba0.7Ca0.3TiO3 based piezocomposite for sensing and energy harvesting applications

Abstract Finite element studies were conducted on 0.5Ba(Zr0.2 Ti0.8) O3–0.5(Ba0.7 Ca0.3)TiO3 (BCZT) piezoelectric particles embedded in polyethylene matrix to create a piezocomposite having a positive and negative Poisson's ratio of −0.32 and 0.2. Polyethylene with a positive Poisson's ratio is referred to as non-auxetic while those with negative Poisson's ratio are referred to as auxetic or inherently auxetic. The effective elastic and piezoelectric properties were calculated at volume fractions of (4%, 8% to 24%) to study their sensing and harvesting performance. This study compared lead-free auxetic 0–3 piezocomposite for sensing and energy harvesting with non-auxetic one. Inherently auxetic piezocomposites have been studied for their elastic and piezoelectric properties and improved mechanical coupling, but their sensing and energy harvesting capabilities and behavior patterns have not been explored in previous literatures. The effect of Poisson's ratio ranging between −0.9 to 0.4 on the sensing and energy harvesting performance of an inherently auxetic lead free piezocomposite composite with BCZT inclusions has also not been studied before, motivating the author to conduct the present study. Auxetic piezocomposite demonstrated an overall improvement in performance in terms of higher sensing voltage and harvested power. The study was repeated at a constant volume fraction of 24% for a range of Poisson's ratio varied between −0.9 to 0.4. Enhanced performance was observed at the extreme negative end of the Poisson's ratio spectrum. This paper demonstrates the potential improvements by exploiting auxetic matrices in future piezocomposite sensors and energy harvesters

Influence of lead and zinc oxides on the radiation shielding properties of tellurite glass systems

The radiation shielding properties of xPbO-(100-x)TeO2, x = 10, 20, and 30 mol% binary glasses and y[ZnO]-(100-y)[70(TeO2)-30(PbO)] y = 15, 20, and 25 mol% ternary glasses were investigated using Geant4 simulations and the newly developed Phy-X/PSD program. The glasses’ gamma shielding abilities were assessed using their mass attenuation coefficient (μ/ρ), mean free path (MFP), effective atomic number (Zeff), and half value layer (HVL) values. The neutron shielding ability was evaluated by determining the removal cross-section (RCS) values, which were 0.097, 0.101, and 0.103 cm-1 for binary PbO-TeO2 (PT) glasses and 0.118, 0.116, and 0.114 cm-1 for ternary ZnO-PbO-TeO2 (PTZ) glasses. The gamma and neutron shielding features of the glasses were compared with those of various ordinary concretes and Pb-free, Pb-based, and commercial glasses. The addition of PbO changed the gamma and neutron properties of the PT glasses, while the addition of ZnO demonstrated a different trend in the gamma properties of the PTZ glass system

Gamma, Neutron, and Heavy Charged Ion Shielding Properties of Er3+-Doped and Sm3+-Doped Zinc Borate Glasses

This study aimed to investigate the nuclear radiation shielding properties of erbium (Er)-reinforced and samarium (Sm)-reinforced borate glasses. In the 0.015-15 MeV photon energy range, attenuation coefficients, as well as half-value layer tenth-value layers, and the mean-free path have been calculated. Additionally, effective, and equivalent atomic numbers, effective atomic weight, electron density, and exposure and energy absorption build-up factors were also calculated. To evaluate the overall nuclear radiation attenuation competencies of Er-rich and Sm-rich glasses, effective removal cross-section values for fast neutrons and projected range/mass stopping power values for alpha and proton particles were also determined. The glass sample BZBEr2.0 had the highest linear and mass attenuation coefficients (μ and μm), effective conductivity (Ceff), the effective number of electrons (Neff), and effective atomic number (Zeff) values as well as the lowest half-value layer (T1/2), tenth value layers (T1/10), mean free path (λ), exposure build-up factor, and energy absorption build-up factor values. μm values were reported as 2.337, 2.556, 2.770, 2.976, 2.108, 2.266, 2.421, 2.569, and 2.714 for BZBEr0.5, BZBEr1.0, BZBEr1.5, BZBEr2.0, BZBSm0.0, BZBSm0.5, BZBSm1.0, BZBSm1.5, and BZBSm2.0 glass samples at 0.06 MeV, respectively. The results showed that Er has a greater effect than Sm regarding the gamma-ray shielding properties of borate glasses. The results of this investigation could be used in further investigations and added to older investigations with the same aim, to aid the scientific community in determining the most appropriate rare-earth additive, to provide adequate shielding properties based on the requirement. © 2022 Huseyin Ozan Tekin et al., published by De Gruyter

Molecular Polar Surface Area, Total Solvent Accessible Surface Area (SASA), Heat of Formation, and Gamma-Ray Attenuation Properties of Some Flavonoids

The chemical and physical characteristics of several flavonoid compounds such as geraniol, thymoquinone, betaine, apigenin, N-acetylcysteine, catechin, l-carnosine, epigallocatachin, and saponarin were examined in this work. Numerous molecular properties of all flavonoid compounds used in this study were calculated using the Calculate Molecular Properties module of Accelrys Discovery Studio v20.1.0.19295.0. These properties included molecular polar surface area, total solvent accessible surface area, and heat of formation. We used the MCNPX general-purpose Monte Carlo code in combination with the Phy-X PSD software to determine gamma-ray interaction parameters such as attenuation coefficients, effective atomic numbers, and buildup factors. The findings indicate that the flavonoids’ elemental compositions have a direct effect on their chemical and physical properties. Additionally, a synergistic interaction of chemical and physical behaviors has been observed. Among the flavonoids studied, saporanin was shown to have the highest polar surface area and solvent accessible surface area, as well as the highest stability. Additionally, saporanin had the strongest gamma-ray attenuation characteristics across a broad photon energy range. It may be inferred that saporanin’s elemental structure enables a synergistic relationship between its chemical and physical characteristics. The findings of this study may contribute to the evaluation of saporanin’s hypoglycemic, antibacterial, and hepatoprotective effects. Copyright © 2022 Tekin, ALMisned, Issa, Kasikci, Arooj, Ene, Al-Buriahi, Konuk and Zakaly.Princess Nourah Bint Abdulrahman University, PNU: PNURSP2022R149The authors express their sincere gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project Number (PNURSP2022R149) and Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia

Investigation of photon, neutron and proton shielding features of H3BO3–ZnO–Na2O–BaO glass system

The current study aims to explore the shielding properties of multi-component borate-based glass series. Seven glass-samples with composition of (80-y)H3BO3–10ZnO–10Na2O–yBaO where (y = 0, 5, 10, 15, 20, 25 and 30 mol.%) were synthesized by melt-quench method. Various shielding features for photons, neutrons, and protons were determined for all prepared samples. XCOM, Phy-X program, and SRIM code were performed to determine and explain several shielding properties such as equivalent atomic number, exposure build-up factor, specific gamma-ray constants, effective removal cross-section (SR), neutron scattering and absorption, Mass Stopping Power (MSP) and projected range. The energy ranges for photons and protons were 0.015–15 MeV and 0.01–10 MeV, respectively. The mass attenuation coefficient (µ/?) was also determined experimentally by utilizing two radioactive sources (166Ho and 137Cs). Consistent results were obtained between experimental and XCOM values in determining µ/? of the new glasses. The addition of BaO to the glass matrix led to enhance the µ/? and specific gamma-ray constants of glasses. Whereas the remarkable reductions in SR, MSP, and projected range values were reported with increasing BaO concentrations. The acquired results nominate the use of these glasses in different radiation shielding purposes

Effect of Ag2O substituted in bioactive glasses: a synergistic relationship between antibacterial zone and radiation attenuation properties

In this study, a promising relationship between antibacterial zone and radiation attenuation properties was investigated in Ag2O doped bioactive glasses with a chemical composition of xAg2O–20Li2O–25TeO2-(55-x)B2O3 (where x = 0, 0.5, 1.0, 1.5, and 2.0 mol%). For this aim, a wide-ranging radiation attenuation characterization procedure was performed on Ag2O substituted bioactive glasses. The general-purpose Monte Carlo code MCNPX (v.2.7.0) was used to model bioactive glasses. The mass attenuation coefficients were calculated using a gamma-ray transmission setup. The coefficients obtained were used to determine other important attenuation properties. Finally, for particular behaviors, exposure (EBF) and energy absorption (EABF) build-up factors were calculated for specific attitudes of Ag2O substitutions in bioactive glasses during the interaction process. The results showed that there is direct relationship between Ag2O substitution amount and radiation attenuation properties. In addition to its well-behaviors on inhibition zone against bacterial occurrences, it can be concluded that increasing Ag2O would increase the gamma-ray attenuation properties of studied bioactive glass system. © 2021 The AuthorsThe authors thank for the scholar and research grant under Universiti Putra Malaysia , Taif University Researchers Supporting Project number (TURSP-2020/12), Taif University , Saudi Arabia and Deanship of Scientific Research at King Khalid University for financial support through General Research Project under grant number ( G.R.P/81/42 )

Developed selenium dioxide-based ceramics for advanced shielding applications: Au2O3 impact on nuclear radiation attenuation

The current research article aims to study the radiation shielding competence of a newly developed PbO-B2O3-SeO2-Er2O3:Au2O3 glass ceramic. The concentrations of the constituent oxides were 40, 10, 49.5, and 0.5 mol % for PbO, B2O3, SeO2, and Er2O3, respectively. The studied ceramic specimens were denoted by EA0, EA25, EA50, EA75 and EA100, and their density values were 5.87, 5.92, 5.94, 6.09, and 6.10 g/cm3, respectively. The radiation shielding competence and photon buildup factors of the present ceramics were investigated under the Au2O3/SeO2 substitution with ratio up to 0.1 mol %. The obtained results reveal that the MAC values were reported with 0.233 cm2/g difference between the minimum and the maximum Au2O3 reinforced samples. The highest MAC values were reported for EA100 sample, which has the highest Au2O3 additive in its chemical structure. At 4 MeV photon energy, HVL values were reported as 3.2658 cm, 3.2352 cm, 3.2212 cm, 3.139 cm and 3.1309 cm for EA0, EA25, EA50, EA75 and EA100, respectively. Moreover, the highest values of EBF were observed for the EA100, and the lowest values of EBF were observed for EA0. Therefore, it can be concluded that the present ceramics possess high level shielding competence to use for various applications of gamma radiation. © 2021The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for the financial support through research groups program under grant number (R.G.P2/98/41)