Alignment Studies for Tungsten Near L3 Sub-Shell Threshold Via Theoretical, Experimental and Empirical Methods

Alignment studies are made for tungsten near L3 sub-shell threshold using theoretical, experimental and empirical approaches. Experimentally to measure alignment parameter, the angular distribution of L x-rays of tungsten (W-74) is measured in the angular range 0° to 120°, where maximum anisotropy is expected. The experimental measurements are performed in XRF laboratories of Raja Ramanna Center for Advanced Technology (RRCAT), Indore, India using a three-dimensional double reflection set-up. The weighted average of alignment values with 10% error comes 0.155 ± 0.009. Theoretically, the value of alignment parameter A20 is calculated using non-relativistic dipole approximation in a point Coulomb potential and is found 0.151 at L3 threshold energy (10.676 keV). For empirical A20 evaluations, IGELCS interpolated experimental LXRF cross-section σ*Lg (g = α, ℓ) values of Mann et al with 8% reported errorsare used along with the radiative decay rates. The comparison among theoretical, experimental and empirical values are similar and values being >0.1 at L3 threshold energy are certainly higher than the 5 to 8 percent uncertainties quoted in earlier experimental results

Analytic perturbation theory to study the effect of screening on alignment of atomic inner shell vacancies

An analytic perturbation theory has been developed for screened Coulomb radial wave functions by interpolating the screened Coulomb potential of McEnnan for elements lanthanum to uranium and was used to calculate alignment of vacancies in L3 sub shell. To check the authenticity of the present method of calculation, the intermediate steps are compared with our earlier formulation of point Coulomb potential for the calculations. A close agreement has been obtained among the values of intermediate steps involved in both the formulations that proved the reliability of present calculations and prompted us to extend the calculations for the elements lanthanum to uranium in the energy region threshold to 60 keV

Vitamin D Intoxication in An Elderly: A Case Report

Vitamin D is a very common prescribed drug for numerous indications. Due to scarce knowledge and poor awareness of the various formulations, preparations and dosages of Vitamin D, there are many chances of prescription errors, medication errors, product use issue and undesirable adverse drug reactions. We hereby detail case of 70-year-old ex-army gentleman reported to us with a history of lethargy, confusion, reduced appetite and gait imbalance since few days with a history of knee replacement surgery 2 years back. Medical history was not of much relevance before it was revealed that he was getting cholecalciferol injection with a strength of 600000 IU once a week for few months. He was detected to have very high serum vitamin D level and hypercalcemia. He was started on intravenous fluids, diuretics and glucocorticoids. In a few days, after effective treatment, the patient was discharged in a recovering stage and advised to stop intake calcium and vitamin D in any form. At his last follow up, after a few months of discharge, he had totally recovered

Impact of human intervention and climate change on natural flow regime

According to the ‘natural flow paradigm’, any departure from the natural flow condition will alter the river ecosystem. River flow regimes have been modified by anthropogenic interventions and climate change is further expected to affect the biotic interactions and the distribution of stream biota by altering streamflow. This study aims to evaluate the hydrologic alteration caused by dam construction and climatic changes in a mesoscale river basin, which is prone to both droughts and monsoonal floods. To analyse the natural flow regime, 15 years of observed streamflow (1950–1965) prior to dam construction is used. Future flow regime is simulated by a calibrated hydrological model Soil and Water Assessment Tool (SWAT), using ensemble of four high resolution (~25 km) Regional Climate Model (RCM) simulations for the near future (2021–2050) based on the SRES A1B scenario. Finally, to quantify the hydrological alterations of different flow characteristics, the Indicators of Hydrological Alteration (IHA) program based on the Range of Variability Approach (RVA) is used. This approach enables the assessment of ecologically sensitive streamflow parameters for the pre- and post-impact periods in the regions where availability of long-term ecological data is a limiting factor. Results indicate that flow variability has been significantly reduced due to dam construction with high flows being absorbed and pre-monsoon low flows being enhanced by the reservoir. Climate change alone may reduce high peak flows while a combination of dam and climate change may significantly reduce variability by affecting both high and low flows, thereby further disrupting the functioning of riverine ecosystems. We find that, in the Kangsabati River basin, influence of dam is greater than that of the climate change, thereby emphasizing the significance of direct human intervention

Excited state dynamics of Michler's ketone: a laser flash photolysis study

Steady state absorption and fluorescence as well as the time resolved absorption studies in the pico and subpicosecond time domain have been performed to characterize the excited singlet and triplet states of Michler's ketone (MK). The nature of the lowest excited singlet (S1) and triplet (T1) states depends on the polarity of the solvent - in nonpolar solvents they have either pure nπ∗ character or mixed character of π ∗ and π π ∗ states but in more polar solvents the states have CT character. Concentration dependence of the shapes of the fluorescence as well the excited singlet and triplet absorption spectra provide the evidence for the association of the MK molecules in the ground state

Study of prevalence of thyroid dysfunction in type 2 diabetes mellitus

Background: Type 2 diabetes mellitus (T2DM) is associated with increased incidence of thyroid dysfunction (TD). The coexistence of thyroid dysfunction in T2DM patient is an important barrier in achieving treatment goal. The study regarding prevalence of TD in T2DM has not been done in patients of Eastern Uttar Pradesh. The present study was aimed to know the prevalence of thyroid dysfunction in T2DM in patients of Eastern Uttar Pradesh.Methods: This is an observational cross sectional prevalence study of thyroid dysfunction in 250 diagnosed T2DM patients deleat diagnosed based on ADA criteria attending the department of medicine Baba Raghav Das Medical College, Gorakhpur, Uttar Pradesh, Study was India, done over a period of 1 year. Thyroid dysfunction was classified on the basis of ATA criteria. All subjects underwent a detailed history, clinical examination and relevant biochemical tests.Results: The prevalence of thyroid dysfunction in T2DM patients was found to be 20.4% in this study.Conclusions: The prevalence of thyroid dysfunction was found to be higher in type 2 diabetes mellitus patients in comparison to general population as mentioned in different literature

Analysis of hybrid elliptical air hole ring As2Se3 glass PCF for Zero Dispersion

Volume 1 Issue 3 (May 2013

Integrated assessment of no-regret climate change adaptation options for reservoir catchment and command areas

The need for credible, salient and legitimate climate change adaptation options in the water sector, which target location specific adaptation requirements, is well recognized. In developing countries, the low-hanging fruit; no-regret options, should be identified with stakeholders and assessed against future changes in water availability and demand, for comparing effectiveness and robustness. Such integrated basin-scale assessments, including reservoir catchment and command areas, can suitably inform adaptation decision-making. In this study, we integrate participatory and modelling approaches for evaluation of reservoir catchment and command area no-regret options addressing water availability and demand in the Kangsabati river basin. Through multi-level stakeholder workshops we identify and prioritize options, followed by evaluation of two reservoir catchment options; check dams and increasing forest cover and three reservoir command options; changing cropping pattern, traditional ponds and waste water reuse, using the Water Evaluation And Planning (WEAP) model. We use four high resolution (~25 km) regional climate model simulations of future climatic factors, along with non-climatic factors affecting water demand, for forcing WEAP. We find that options have varied ability in addressing adaptation requirements. Amongst catchment options, increasing forest cover addresses adaptation requirements more suitably than check dams, while in the command areas we observe mixed abilities of options, leading to the inference that combining complementary options may be a more useful strategy. We conclude by discussing our experiences with this approach in a developing country context, in terms of benefits, limitations, lessons learnt and future research directions