589 research outputs found

    Selknamella: a new agglutinated foraminiferal genus from the early Eocene southern high latitudes

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    A new, unusual agglutinated foraminifera, Selknamella basketi n. gen., n. sp. is described from the Fuegian lower Eocene, Magallanes Basin, southernmost South America. It has a morphology and paleohabitat similar to those of the subfamily Remaneicinae Loeblich and Tappan, 1964, particularly to the Holocene genera Bruneica Brönnimann, Keij and Zaninetti, 1983, and Remaneica Rhumbler, 1938: It has a low trochospirally coiled to patelliform small test; the first two or three embryonic chambers are globular and undivided; following chambers are semilunate-shaped from spiral view and mushroom-shaped from umbilical view, and subdivided by radial secondary septula. Selknamella n. gen. differs from all the organically-cemented Remaneicinae by the perforate rigid wall, completely calcareous in the initial chambers to very finely agglutinated in the last whorls. The new genus is the only case of calcareous cemented agglutinated foraminifera in the Cretaceous and Cenozoic of the Magallanes Basin, and is restricted to the early Eocene, coincident with the warmest time in the high southern latitudes.Fil: Malumian, Norberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; ArgentinaFil: Nañez, Carolina Adela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; ArgentinaFil: Jannou, Gabriel Eugenio. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; ArgentinaFil: Arenillas, I.. Universidad de Zaragoza; Españ

    NotĂ­cia dels ingressos recents del Gabinet de Dibuixos i Gravats

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    El Gabinet de Dibuixos i Gravats (GDG) ha promogut els darrers anys una activa polĂ­tica de captaciĂł de bĂ©ns que ha fet augmentar el seu nodrit fons –format per mĂ©s de 140.000 obres– amb ingressos de gran qualitat. AixĂ­, cal remarcar l’enriquiment i la diversificaciĂł que ha suposat la presĂšncia d’artistes que no estaven representats o no eren prou ben representats a la col‱lecciĂł com, entre d’altres, Carles Casagemas, Cassandre, Josep Renau o Antoni ClavĂ©. El destacat conjunt d’obres incorporades recentment contribuirĂ  sens dubte a consolidar el GDG com a principal centre pĂșblic catalĂ  dedicat a la conservaciĂł i l’estudi d’obra sobre paper.In recent years the Cabinet of Drawings and Prints (GDG) has pursued an active policy of asset raising that has increased its sizeable collection – made up of over 140,000 works – with admissions of great quality. Thus, the collection has been enriched and diversified by the presence of artists that were previously either not represented or not well enough represented like, among others, Carles Casagemas, Cassandre, Josep Renau or Antoni ClavĂ©. The outstanding group of works recently incorporated will doubtlessly contribute to consolidating the GDG as the principal Catalan public centre devoted to the conservation and study of works on paper.El Gabinete de Dibujos y Grabados (GDG) ha promovido en los Ășltimos años una activa polĂ­tica de captaciĂłn de bienes que ha hecho aumentar sus nutridos fondos –formados por mĂĄs de 140.000 obras– con ingresos de gran calidad. AsĂ­, hay que destacar el enriquecimiento y la diversificaciĂłn que ha supuesto la presencia de artistas que no estaban representados o no estaban suficientemente bien representados en la colecciĂłn como, entre otros, Carles Casagemas, Cassandre, Josep Renau o Antoni ClavĂ©. El destacado conjunto de obras incorporadas recientemente contribuirĂĄ sin duda a consolidar el GDG como el principal centro pĂșblico catalĂĄn dedicado a la conservaciĂłn y estudio de obra sobre papel

    The use of in situ hybridisation and immunocytochemistry to characterise coiled bodies in plant meiocytes

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    2 pĂĄginas, 2 figuras.-- Trabajo presentado a la XI European Conference on Electron Microscopy- EUREM11 celebrada en DublĂ­n (Irlanda) del 26 al 30 de Agosto de 1996.This study was supported by project DGICYT PB92-0079-CO3-O3.Peer reviewe

    Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis

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    This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 14928 14934, which has been published in final form at https://doi.org/10.1002/chem.201903539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving[EN] A mechanistic study is herein presented for the use of heterogeneous photocatalysts based on perylene moieties. First, the successful immobilization of perylene diimides (PDI) on silica matrices is demonstrated, including their full characterization by means of electronic microscopy, surface area measurements, powder XRD, thermogravimetric analysis, and FTIR, Si-29 and C-13 solid-state NMR, fluorescence, and diffuse reflectance spectroscopies. Then, the photoredox activity of the material was tested by using two model reactions, alkene oxidation and 4-nitrobenzylbromide reduction, and mechanistic studies were performed. The mechanistic insights into their photoredox activity show they have promising dual photocatalytic activity for both organic oxidations and reductions.This work was supported by the Natural Sciences and Engineering Research Council of Canada and the Canada Foundation for Innovation. The authors are grateful to Prof. J.C. Scaiano for his generous support.Carrillo, AI.; Elhage, A.; MarĂ­n GarcĂ­a, ML.; Lanterna, AE. (2019). Perylene-Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis. Chemistry - A European Journal. 25(65):14928-14934. https://doi.org/10.1002/chem.201903539S14928149342565Marzo, L., Pagire, S. K., Reiser, O., & König, B. (2018). Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? Angewandte Chemie International Edition, 57(32), 10034-10072. doi:10.1002/anie.201709766Marzo, L., Pagire, S. K., Reiser, O., & König, B. (2018). Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie fĂŒr die organische Synthese? Angewandte Chemie, 130(32), 10188-10228. doi:10.1002/ange.201709766Miranda, M. A., & Marin, M. L. (2017). Photocatalytic functionalization for the synthesis of drugs and analogs. Current Opinion in Green and Sustainable Chemistry, 6, 139-149. doi:10.1016/j.cogsc.2017.05.001Yoon, T. P. (2016). Photochemical Stereocontrol Using Tandem Photoredox–Chiral Lewis Acid Catalysis. Accounts of Chemical Research, 49(10), 2307-2315. doi:10.1021/acs.accounts.6b00280Pitre, S. P., McTiernan, C. D., & Scaiano, J. C. (2016). Understanding the Kinetics and Spectroscopy of Photoredox Catalysis and Transition-Metal-Free Alternatives. Accounts of Chemical Research, 49(6), 1320-1330. doi:10.1021/acs.accounts.6b00012Lang, X., Chen, X., & Zhao, J. (2014). Heterogeneous visible light photocatalysis for selective organic transformations. Chem. Soc. Rev., 43(1), 473-486. doi:10.1039/c3cs60188aSchultz, D. M., & Yoon, T. P. (2014). Solar Synthesis: Prospects in Visible Light Photocatalysis. Science, 343(6174), 1239176-1239176. doi:10.1126/science.1239176Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013). Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis. Chemical Reviews, 113(7), 5322-5363. doi:10.1021/cr300503rNarayanam, J. M. R., & Stephenson, C. R. J. (2011). Visible light photoredox catalysis: applications in organic synthesis. Chem. Soc. Rev., 40(1), 102-113. doi:10.1039/b913880nSarina, S., Waclawik, E. R., & Zhu, H. (2013). Photocatalysis on supported gold and silver nanoparticles under ultraviolet and visible light irradiation. Green Chemistry, 15(7), 1814. doi:10.1039/c3gc40450aQu, Y., & Duan, X. (2013). Progress, challenge and perspective of heterogeneous photocatalysts. Chem. Soc. Rev., 42(7), 2568-2580. doi:10.1039/c2cs35355eJiang, J.-X., Li, Y., Wu, X., Xiao, J., Adams, D. J., & Cooper, A. I. (2013). Conjugated Microporous Polymers with Rose Bengal Dye for Highly Efficient Heterogeneous Organo-Photocatalysis. Macromolecules, 46(22), 8779-8783. doi:10.1021/ma402104hFox, M. A., & Dulay, M. T. (1993). Heterogeneous photocatalysis. Chemical Reviews, 93(1), 341-357. doi:10.1021/cr00017a016Sun, H., Wang, L., Wang, Y., & Guo, X. (2018). Imide‐Functionalized Polymer Semiconductors. Chemistry – A European Journal, 25(1), 87-105. doi:10.1002/chem.201803605Nowak-KrĂłl, A., Shoyama, K., Stolte, M., & WĂŒrthner, F. (2018). Naphthalene and perylene diimides – better alternatives to fullerenes for organic electronics? Chemical Communications, 54(98), 13763-13772. doi:10.1039/c8cc07640eArzoumanian, E., Ronzani, F., Trivella, A., Oliveros, E., Sarakha, M., Richard, C., 
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 Miao, Z. C. (2018). The Effect of Reduction Potential on the Generation of the Perylene Diimide Radical Anions. Russian Journal of Physical Chemistry A, 92(7), 1261-1265. doi:10.1134/s003602441807035xDaw, P., Petakamsetty, R., Sarbajna, A., Laha, S., Ramapanicker, R., & Bera, J. K. (2014). A Highly Efficient Catalyst for Selective Oxidative Scission of Olefins to Aldehydes: Abnormal-NHC–Ru(II) Complex in Oxidation Chemistry. Journal of the American Chemical Society, 136(40), 13987-13990. doi:10.1021/ja5075294Nyawade, E. A., Friedrich, H. B., Omondi, B., & Mpungose, P. (2015). Synthesis and Characterization of New (η5-Cyclopentadienyl)dicarbonylruthenium(II) Amine Complexes: Their Application as Homogeneous Catalysts in Styrene Oxidation. Organometallics, 34(20), 4922-4931. doi:10.1021/acs.organomet.5b00564Muthumari, S., & Ramesh, R. (2018). Synthesis and Structure of Ru(II) Complexes of Thiosemicarbazone: Highly Selective Catalysts for Oxidative Scission of Olefins to Aldehydes. ChemistrySelect, 3(11), 3036-3041. doi:10.1002/slct.20180016
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