Free energy determination of phase coexistence in model C60: A comprehensive Monte Carlo study

The free energy of the solid and fluid phases of the Girifalco C60 model are determined through extensive Monte Carlo simulations. In this model the molecules interact through a spherical pair potential, characterized by a narrow and attractive well, adjacent to a harshly repulsive core. We have used the Widom test particle method and a mapping from an Einstein crystal, in order to estimate the absolute free energy in the fluid and solid phases, respectively; we have then determined the free energy along several isotherms, and the whole phase diagram, by means of standard thermodynamic integrations. We highlight how the interplay between the liquid-vapor and the liquid-solid coexistence conditions determines the existence of a narrow liquid pocket in the phase diagram, whose stability is assessed and confirmed in agreement with previous studies. In particular, the critical temperature follows closely an extended corresponding-states rule recently outlined by Noro and Frenkel [J. Chem. Phys. 113:2941 (2000)]. We discuss the emerging "energetic" properties of the system, which drive the phase behavior in systems interacting through short-range forces [A. A. Louis, Phil. Trans. R. Soc. A 359:939 (2001)], in order to explain the discrepancy between the predictions of several structural indicators and the results of full free energy calculations, to locate the fluid phase boundaries. More generally, we aim to provide extended reference data for calculations of the free energy of the C60 fullerite in the low temperature regime, as for the determination of the phase diagram of higher order fullerenes and other fullerene-related materials, whose description is based on the same model adopted in this work.Comment: RevTeX, 11 pages, 9 figure

Energy-Momentum Tensor of Cosmological Fluctuations during Inflation

We study the renormalized energy-momentum tensor (EMT) of cosmological scalar fluctuations during the slow-rollover regime for chaotic inflation with a quadratic potential and find that it is characterized by a negative energy density which grows during slow-rollover. We also approach the back-reaction problem as a second-order calculation in perturbation theory finding no evidence that the back-reaction of cosmological fluctuations is a gauge artifact. In agreement with the results on the EMT, the average expansion rate is decreased by the back-reaction of cosmological fluctuations.Comment: 19 pages, no figures.An appendix and references added, conclusions unchanged, version accepted for publication in PR

One Loop Back Reaction On Power Law Inflation

We consider quantum mechanical corrections to a homogeneous, isotropic and spatially flat geometry whose scale factor expands classically as a general power of the co-moving time. The effects of both gravitons and the scalar inflaton are computed at one loop using the manifestly causal formalism of Schwinger with the Feynman rules recently developed by Iliopoulos {\it et al.} We find no significant effect, in marked contrast with the result obtained by Mukhanov {\it et al.} for chaotic inflation based on a quadratic potential. By applying the canonical technique of Mukhanov {\it et al.} to the exponential potentials of power law inflation, we show that the two methods produce the same results, within the approximations employed, for these backgrounds. We therefore conclude that the shape of the inflaton potential can have an enormous impact on the one loop back-reaction.Comment: 28 pages, LaTeX 2 epsilo

Gill histopathology in zebrafish model following exposure to aquacultural disinfectants

The effect of acute exposure of four disinfectants commonly used in aquacultural practice (formalin, potassium permanganate, benzalkonium chloride and malachite green) was studied on the histological structure of adult zebrafish (Danio rerio) gills. Groups of 8 individuals were exposed to a dose of each disinfectant corresponding to the therapeutic dose (TD) and five folds of the therapeutic dose (5xTD). Gills of all exposed zebrafish showed a higher occurrence of histopathological changes. These alterations included a slightly focal proliferation of interlamellar cells with obliteration of interlamellar spaces, mild infiammatory reaction with leucocyte infiltration and lifting of the epithelial layer from gill lamellae. Fish exposed to potassium permanganate showed more severe histopathological changes consisting of necrotic change of lamellar cells, distorsion and apical necrosis of secondary lamellae

One Loop Back Reaction On Chaotic Inflation

We extend, for the case of a general scalar potential, the inflaton-graviton Feynman rules recently developed by Iliopoulos {\it et al.} As an application we compute the leading term, for late co-moving times, of the one loop back reaction on the expansion rate for $V(\phi) = \frac12 m^2 \phi^2$. This is expressed as the logarithmic time derivative of the scale factor in the coordinate system for which the expectation value of the metric has the form: $dx^{\mu} dx^{\nu} = - d{\bar t}^2 + a^2({\bar t}) d{\vec x} \cdot d{\vec x}$. This quantity should be a gauge independent observable. Our result for it agrees exactly with that inferred from the effect previously computed by Mukhanov {\it et al.} using canonical quantization. It is significant that the two calculations were made with completely different schemes for fixing the gauge, and that our computation was done using the standard formalism of covariant quantization. This should settle some of the issues recently raised by Unruh.Comment: 41 pages, LaTeX 2 epsilo

Low-energy graceful exit in anisotropic string cosmology backgrounds

We discuss the possibility of a smooth transition from the pre- to the post-big bang regime, in the context of the lowest-order string effective action (without higher-derivative corrections), taking into account with a phenomenological model of source the repulsive gravitational effects due to the back-reaction of the quantum fluctuations outside the horizon. We determine a set of necessary conditions for a successful and realistic transition, and we find that such conditions can be satisfied (by an appropriate model of source), provided the background is higher-dimensional and anisotropic.Comment: 13 pages, latex, 2 figures included using epsfi

Second Order Perturbations of Flat Dust FLRW Universes with a Cosmological Constant

We summarize recent results concerning the evolution of second order perturbations in flat dust irrotational FLRW models with $\Lambda\ne 0$. We show that asymptotically these perturbations tend to constants in time, in agreement with the cosmic no-hair conjecture. We solve numerically the second order scalar perturbation equation, and very briefly discuss its all time behaviour and some possible implications for the structure formation.Comment: 6 pages, 1 figure. to be published in "Proceedings of the 5th Alexander Friedmann Seminar on Gravitation and Cosmology", Int. Journ. Mod. Phys. A (2002). Macros: ws-ijmpa.cls, ws-p9-75x6-50.cl