Correlation between Hardness and Water Absorption Properties of Saudi Kaolin and White Clay Geopolymer Coating

Geopolymer is an uprising technology that is being studied worldwide. Geopolymer raw materials are basically aluminosilicate source materials. However, this technology is yet to infiltrate into pipelines and coating industries which initiated our research idea. The idea of creating universal geopolymer based coating material is mainly to help oil and gas industry reduce its maintenance cost. Kaolin based geopolymer paste was coated on glass reinforced epoxy (GRE) substrates which are majorly used as pipeline material in the oil and gas industry at Saudi Arabia. Kaolin and white clay was chosen as raw material to study the possibilities of utilizing underused aluminosilicate raw materials for geopolymer coating. To obtain suitable formulation, Na2SiO3/NaOH ratio was varied from 0.40 untill 0.60 while other parameters such as solid/liquid ratio and NaOH molarity were kept constant at values as per previous works. Geopolymer coated GRE substrates were then subjected to water absorption, flexural strength and hardness test to validate our findings. Water absorption is a crucial test as for coating materials which justifies the pratical usability of the coating product. Upon testing, kaolin and white clay based geopolymer coating each shows promising properties at Na2SiO3/NaOH ratio of 0.45 and 0.50 each

Use of calcium carbonate nanoparticles in production of nano-engineered foamed concrete

Researchers have shown significant interest in the incorporation of nanoscale components into concrete, primarily driven by the unique properties exhibited by these nanoelements. A nanoparticle comprises numerous atoms arranged in a cluster ranging from 10 nm to 100 nm in size. The brittleness of foamed concrete (FC) can be effectively mitigated by incorporating nanoparticles, thereby improving its overall properties. The objective of this investigation is to analyze the effects of incorporating calcium carbonate nanoparticles (CCNPs) into FC on its mechanical and durability properties. FC had a 750 kg/m3 density, which was achieved using a binder-filler ratio of 1:1.5 and a water-to-binder ratio of 0.45. The CCNPs material exhibited a purity level of 99.5% and possessed a fixed grain size of 40 nm. A total of seven mixes were prepared, incorporating CCNPs in FC mixes at the specific weight fractions of 0% (control), 1%, 2%, 3%, 4%, 5%, and 6%. The properties that were assessed included the slump, bulk density, flexural strength, splitting tensile strength, compressive strength, permeable porosity, water absorption, drying shrinkage, softening coefficient, and microstructural characterization. The results suggested that incorporating CCNPs into FC enhanced its mechanical and durability properties, with the most optimal improvement observed at the CCNPs addition of 4%. In comparison to the control specimen, it was witnessed that specimens containing 4% CCNPs demonstrated remarkably higher capacities in the compressive, splitting tensile, and flexural tests, with the increases of 66%, 52%, and 59%, respectively. The addition of CCNPs resulted in an improvement in the FC porosity and water absorption. However, it also led to a decrease in the workability of the mixtures. Furthermore, the study provided the correlations between the compressive strength and splitting tensile strength, as well as the correlations between the compressive strength and flexural strength. In addition, an artificial neural network approach was employed, utilizing k-fold cross-validation, to predict the compressive strength. The confirmation of the property enhancement was made through the utilization of a scanning electron microscope

Behavior of Alkali-Activated Fly Ash through Underwater Placement

Underwater concrete is a cohesive self-consolidated concrete used for concreting underwater structures such as bridge piers. Conventional concrete used anti-washout admixture (AWA) to form a high-viscosity underwater concrete to minimise the dispersion of concrete material into the surrounding water. The reduction of quality for conventional concrete is mainly due to the washing out of cement and fine particles upon casting in the water. This research focused on the detailed investigations into the setting time, washout effect, compressive strength, and chemical composition analysis of alkali-activated fly ash (AAFA) paste through underwater placement in seawater and freshwater. Class C fly ash as source materials, sodium silicate, and sodium hydroxide solution as alkaline activator were used for this study. Specimens produced through underwater placement in seawater showed impressive performance with strength 71.10 MPa on 28 days. According to the Standard of the Japan Society of Civil Engineers (JSCE), the strength of specimens for underwater placement must not be lower than 80% of the specimen’s strength prepared in dry conditions. As result, the AAFA specimens only showed 12.11% reduction in strength compared to the specimen prepared in dry conditions, thus proving that AAFA paste has high potential to be applied in seawater and freshwater applications.</jats:p

Formation of one-part-mixing geopolymers and geopolymer ceramics from geopolymer powder

publisher: Elsevier articletitle: Formation of one-part-mixing geopolymers and geopolymer ceramics from geopolymer powder journaltitle: Construction and Building Materials articlelink: http://dx.doi.org/10.1016/j.conbuildmat.2017.08.110 content_type: article copyright: © 2017 Elsevier Ltd. All rights reserved

Thermal conductivity, microstructure and hardened characteristics of foamed concrete composite reinforced with raffia fiber

Researchers have become enthralled with using natural fiber, which is a waste product from industrial processes, as an additive in cement-based materials. This is due to the fact that natural fiber is inexpensive, has principal carbon neutrality, and is obtainable in large quantities. Additionally, this fiber is made from a renewable resource. Hence it has a low density and is amenable to undergoing chemical alteration. The idea of this investigation is to discover the reactivity of raffia (raphia vinifera) fiber (RF) in low-density foamed concrete (FC). FC density of 950 kg/m3 was utilized. Workability, density, thermal conductivity, SEM analysis, compressive, bending, and tensile strengths were the parameters that were quantified and assessed. Based on the outcomes, it has been determined that the mechanical properties and thermal conductivity of FC-RF composites may be enhanced by using RF with an ideal reinforcing fraction content of 6%. Slump flow gradually decreased from 2% to 8% RF fraction content. The lowest slump flow was achieved by adding RF to the FC mixture at a fraction content of 8%. The density of FC-RF composites shows a developing tendency, likely because of the RF's comparatively high specific gravity and increasing fraction content. The addition of RF to FC considerably enhances the material's compressive, bending, and tensile strength. The optimal strength characteristics emerged when 6% RF was added to FC. Besides, the FC thermal conductivity improves as the weight percent of RF increases because the porous structure of FC with RF allows it to absorb heat

Recent Developments in Steelmaking Industry and Potential Alkali Activated Based Steel Waste: A Comprehensive Review

The steel industry is responsible for one-third of all global industrial CO2 emissions, putting pressure on the industry to shift forward towards more environmentally friendly production methods. The metallurgical industry is under enormous pressure to reduce CO2 emissions as a result of growing environmental concerns about global warming. The reduction in CO2 emissions is normally fulfilled by recycling steel waste into alkali-activated cement. Numerous types of steel waste have been produced via three main production routes, including blast furnace, electric arc furnace, and basic oxygen furnace. To date, all of the steel waste has been incorporated into alkali activation system to enhance the properties. This review focuses on the current developments over the last ten years in the steelmaking industry. This work also summarizes the utilization of steel waste for improving cement properties through an alkali activation system. Finally, this work presents some future research opportunities with regard to the potential of steel waste to be utilized as an alkali-activated material.</jats:p

FINITE ELEMENT ANALYSIS ON STRUCTURAL BEHAVIOUR OF GEOpOLYMER REINFORCED CONCRETE BEAM USING JOHNSON-COOK DAMAGE IN ABAQUS

This paper details a finite element analysis of the behaviour of Si-Al geopolymer concrete beam reinforced steel bar under an impulsive load and hyper velocity speed up to 1 km/s created by an air blast explosion. The initial torsion stiffness and ultimate torsion strength of the beam increased with increasing compressive strength and decreasing stirrup ratio. The study involves building a finite element model to detail the stress distribution and compute the level of damage, displacement, and cracks development on the geopolymer concrete reinforcement beam. This was done in ABAQUS, where a computational model of the finite element was used to determine the elasticity, plasticity, concrete tension damages, concrete damage plasticity, and the viability of the Johnson-Cook Damage method on the Si-Al geopolymer concrete. The results from the numerical simulation show that an increase in the load magnitude at the midspan of the beam leads to a percentage increase in the ultimate damage of the reinforced geopolymer beams failing in shear plastic deformation. The correlation between the numerical and experimental blasting results confirmed that the damage pattern accurately predicts the response of the steel reinforcement Si-Al geopolymer concrete beams, concluded that decreasing the scaled distance from 0.298 kg/m3 to 0.149 kg/m3 increased the deformation percentage

The Suitability of Photocatalyst Precursor Materials in Geopolymer Coating Applications: A Review

Today, the building and construction sector demands environmentally friendly and sustainable protective coatings using inorganic coating materials for safe, non-hazardous, and great performance. Many researchers have been working on sustainable solutions to protect concrete and metal infrastructures against corrosion and surface deterioration with the intention of introducing green alternatives to conventional coatings. This article presents a review of developments of geopolymer pastes doped with different types of photocatalyst precursors including factors affecting geopolymer properties for enhancing coating with photocatalytic performance. Photodegradation using geopolymer photocatalyst has great potential for resolving harmless substances and removing pollutants when energized with ultraviolet (UV) light. Although geopolymer is a potentially new material with great properties, there has been less research focusing on the development of this coating. This study demonstrated that geopolymer binders are ideal precursor support materials for the synthesis of photocatalytic materials, with a significant potential for optimizing their distinctive properties

Diverse material based geopolymer towards heavy metals removal: A review

Metakaolin is a commonly used aluminosilicate material for the synthesis of geopolymer based adsorbent. However, it presents characteristics that restrict its uses such as weak rheological properties brought on by the plate-like structure, processing challenges, high water demand and quick hydration reaction. Industrial waste, on the other hand, contains a variety of components and is a potential source of aluminosilicate material. Geopolymer adsorbent synthesized by utilizing industrial waste contains a wide range of elements that offer better ion-exchangeability and increase active sites on the surface of geopolymer. However, limited studies focused on the synthesized of geopolymer based adsorbent by utilizing industrial waste for heavy metal adsorption in wastewater treatment. Therefore, this paper reviews on the raw materials used in the synthesis of geopolymer for wastewater treatment. This would help in the development of low cost geopolymer based adsorbent that has a great potential for heavy metal adsorption, which could deliver double benefit in both waste management and wastewater treatment