Comparison of the Structural Configuration of Cobalt Nanoparticles on Titania and Titania Nanotube Supports

In this study, two cobalt based catalyst samples were prepared on titania and titania nanotubes supports using the deposition precipitation method. Their structural configurations were characterized and compared using BET, and TRP analyses. The BET analysis showed that the surface area of TiO2 is much higher than that of TNT which was due to their structural differences. Analyses of the results obtained revealed that the surface area of the 10 % Co/TNT catalyst sample is higher than that of the 10 % Co/TiO2. The TPR analysis showed that it is much easier to reduce 10 % Co/TiO2, than 10 % Co/TNT. This is attributed to be due to the fact that the cobalt particles were adsorbed on the surface of the TiO2, and formed covalent bonds with TNT. Therefore reduction temperature was higher with TNT than TiO2. The investigation of structural changes of these catalysts when they were coated with carbon, using chemical vapour deposition method was also conducted. The catalyst prepared on TNT support showed better properties in terms of average pore diameter, pore volume and surface area than the catalyst sample prepared on TiO2 support when the two samples were exposed to carbon environment for the same period of time. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2488

Comparison of the structural configuration of Cо nanoparticles on Ti02 and TNT supports

In this study, two cobalt based catalyst samples were prepared on titania and tita- nia nanotubes supports using the deposition precipitation method. Their structural con- figurations were characterized and compared using BET, and TRP analyses. The BET analysis showed that the surface area of TiO2 is much higher than that of TNT which was due to their structural differences. Analyses of the results obtained revealed that the surface area of the 10%Co/TNT catalyst sample is higher than that of the 10%Co/TiO2. The TPR analysis showed that it is much easier to reduce 10%Co/TiO2, than 10%Co/TNT. This is attributed to be due to the fact that the cobalt particles were ad- sorbed on the surface of the TiO2, and formed covalent bonds with TNT. Therefore reduction temperature was higher with TNT than TiO2. The investigation of structural changes of these catalysts when they were coated with carbon, using chemical vapour deposition method was also conducted. The catalyst prepared on TNT support showed better properties in terms of average pore diameter, pore volume and surface area than the catalyst sample prepared on TiO2 support when the two samples were exposed to carbon environment for the same period of time. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2060

An analysis of algebraic pattern of a first order and an extended second order Runge-Kutta Type Method

The algebraic pattern of a 6-Stage Block Hybrid Runge –Kutta Type Methods (BHRKTM) for the solution of Ordinary Differential Equations (ODEs) is carefully analyzed. The analysis of the methods expressed in the Butcher Tableau led to the evolvement of two equations that satisfy the Runge – Kutta consistency conditions. The reason behind the uniform order and error constant for the developed first order and extended second order methods is explained using the theory of linear transformation and monomorphism. The pattern was retained during the transformation

Adsorptive and Photocatalytic Properties of Green Synthesized ZnO and ZnO/NiFe2O4 Nanocomposites for Tannery Wastewater Treatment

This study investigated adsorptive and catalytic behaviour of ZnO and ZnO/NiFe2O4 nanocomposites for the removal and degradation of organic pollutants in tannery wastewater. ZnO and ZnO/NiFe2O4 nanomaterials were synthesized via a green method using Zn, Fe and Ni salts precursor and leaves extract of Anacardium occidentale (linn.). Subsequently, the synthesized samples were characterized by different analytical tools. The adsorptive and catalytic performance of the prepared nanomaterial were assessed using reduction in Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD) and Total Organic Carbon (TOC) in tannery wastewater as indicator parameters. High Resolution Scanning Electron Microscope (HRSEM), High Resolution Transmission Electron Microscope (HRTEM), and X-Ray Diffraction (XRD) analysis of ZnO and ZnO/NiFe2O4 confirmed the formation of hexagonal wurtzite nanoparticle and cubic spinel phase with an average crystallite sizes in the range of 13- 28 nm and 30.44 – 42.53 nm respectively. XRD analysis confirmed no change in the polymorph of ZnO upon the addition NiFe2O4. XPS spectrum showed the existence of the elements in the following oxidation state (+2) for Zn, (+1, +2) for Ni and (+2 and +3) for Fe. BET analysis revealed order of the specific surface area of ZnO/NiFe2O4 (44.61 m2/g) > NiFe2O4 (40.39 m2/g) > ZnO (8.91 m2 /g). The adsorptive and photocatalytic results revealed that 3% ZnO/NiFe2O4 exhibits higher efficiency compared to ZnO and NiFe2O4 nanoparticles alone and in the order of 3% ZnO/NiFe2O4 > NiFe2O4 > ZnO. The study revealed that the prepared nanomaterial behaved better as photocatalyst than as nanoadsorbent. Keywords: Adsorption, photocatalytic technology; ZnO; ZnO/NiFe2O4, tannery wastewate

Determination of work index of graphite from Samanburkono (Nigeria) using modified bond's method

This report covers the work index determination of Saman-Burkono graphite. The test sample was obtained from Saman-Burkono in Ningi Local Government Area of Bauchi state, while reference material (coal) was sourced from Okaba coal mine, Ankpa Local Government Area of Kogi State. A known weight of graphite sample and coal were crushed, pulverized and ground using the laboratory milling machine. The two samples were grinded with two cells of diameter 3.5cm and 222g weight. The analysis of the feed size fort the two samples was found graphically to be 180μm and 175μm, and ball mill discharge was 130μm and 140μm respectively. The work index of a coal as reference material was 7.65 kWh/ short ton, this was used to calculate the work index of the graphite which was found to be 11.047 kWh/short ton, being the required energy to comminute one ton of graphite.Keywords: Comminution, Graphite, Saman-Burkono, Nigeria, Modified Bonds metho