The thermophysical properties of australian opal

The characterisation of the surface area and porosity of opals derived from Tintenbar, a volcanic environment, and Lightning Ridge, a sedimentary environment, using nitrogen gas adsorption at -196°C is reported. Both opal types were found to have relatively low surface areas and displayed little porosity. The low surface areas observed is indicative of the ability of silica to infill voids and interstices. Thermogravimetric analysis of the samples before and after degassing was carried out to determine the amount of water removed by the degassing process. Negligible difference was found in the water content before and after degassing in the case of the Lightning Ridge sedimentary opal, while the Tintenbar volcanic opal was found to have lost more that 60 per cent of its water during the degassing process. These differences were ascribed to the differences in the silica structure of the opals with the Lightning Ridge opal having a denser cage structure, which traps the molecular water, while a more open structure is postulated for the Tintenbar opal, allowing the water to be relatively easily removed

Drying shrinkage of hydrothermally cured cements with reactive magnesia and clay brick waste

In recent years, worldwide research and development in the cement industry has gathered momentum with an aim to explore innovative and sustainable methods to deliver environmentally responsible Portland Cement (PC) based construction products. This study investigated physical and mechanical properties of autoclaved cement-quartz sand blends with the addition of clay-brick waste (CB waste) and reactive magnesia (MgO) with the aim to lower CO2 emissions through the reduction of PC consumption. Mechanical properties and drying shrinkage showed improvements with the incorporation of CB waste due to increased amounts and crystallinity of Al-tobermorite. The addition of reactive MgO to PC in hydrothermal conditions was observed to have a negative effect on the compressive strength. XRD data indicated that MgO did not take part in the reaction during the hydration of the cement and may even retard tobermorite formation. However, the expansive nature from the hydration of MgO to brucite may have compensated for drying shrinkage

A spectroscopic investigation of the weathering of a heritage Sydney sandstone

Infrared spectroscopy has been employed in a study of the degradation of heritage Sydney sandstone used in St. Mary's Cathedral in Sydney, Australia. Spectra were used to characterise the clay components taken from weathered and unweathered sandstone blocks removed from the Cathedral as part of a restoration programme. Two types of kaolin clays - kaolinite and its polymorph, dickite - have been identified. A higher amount of dickite present in the clay of weathered sandstone indicated that a kaolinite-to-dickite transformation occurs upon weathering. X-ray photoelectron spectroscopy was also used to confirm the presence of a more thermally stable polymorph of the kaolinite in the sandstone. © 2008 Elsevier B.V. All rights reserved

Pitchstone Fines: A New Inorganic Binder For Portland Cement-Based Construction Products

The findings of this investigation into the performance pitchstone fines (PF) sourced from a naturally occurring pitchstone deposit in Queensland Australia as a potential pozzolanic supplementary cementitious material (SCM) are reported. 50 mm mortar cubes were prepared by replacement of 20% of the Portland cement (PC) with PF and PF blended with silica fume (SF) in a 1:1 ratio. Mortar cubes were also prepared with a 20% PC substitution level using fly ash (FA) and FA blended with SF also in a 1:1 ratio for comparison as the SCM. Control mortar cubes without PC substitution were also prepared. The compressive strength results for PF blended mortars were comparable to FA mortars, were within 75% of the control mortar at 7 and 28 days and approached the strength of the control mortar at 91 days curing. PF and FA blends containing SF produced compressive strength which surpassed the control mortar. Drying shrinkage measurements are also reported for up to 28 days storage in air. The PF mortar was found to have comparable shrinkage to the control mortar; the shrinkage of the FA mortar was found to be significantly greater. The differences were attributed to the particle shape, angularity and size resulting in greater capillary forces in the FA mortars resulting in greater shrinkage

Development of shrinkage resistant cement-based materials using fibers

Copyright © 2011 by Research Publishing Services. Drying shrinkage is themajor contributor to volume changes in normal strength concrete. Several classes of shrinkage compensating admixtures are known to the concrete industry. This study deals with the literature review and categorization of different classes of shrinkage reducing fibers, especially polyethylene fibers, with the objective of introducing new types of shrinkage reducing fiber. In this investigation a special type of hydrophobic polyethylene minifibers has been used in different dosages in mortar samples. The experimental results on drying shrinkage aswellasonseveralotherpropertiesarereported.Thehydrophobicminifibersshowedremarkable improvement in shrinkage reduction even at very lowconcentrations (0.1%of cementweight)

Characterisation of Portland cement blended with pitchstone fines aiding carbon dioxide emission reduction

Climate change and global wanning present a significant challenge as unsustainable levels of greenhouse gas emissions arising from human activities continue to be emitted. The cement industry is responsible for between five and ten per cent of annual world carbon dioxide emissions; most arising from the manufacture of Portland cement (PC). An effective way of reducing emissions is by incorporating supplementary cementitious materials (SCMs) as partial PC replacements. SCMs are silicate or aluminosilicate based pozzolanic materials which, in finely divided form, combine with water and calcium hydroxide (lime), liberated by cement hydration, to form compounds exhibiting cementitious properties. Pitchstone is such an aluminosilicate and has the potential to act as an effective pozzolan for partial replacement of PC. In North Queensland, Australia, a vast deposit of pitchstone is mined and processed for expandable perlite aggregate. During the classification stage of the excavated natural material, waste pitchstone fines (PF) less than 0.5 mm in size are generated. This study evaluates the waste PF as a viable, eco-friendly pozzolan for the partial replacement of PC. The reactivity of the PF is compared to fly ash (FA), using the pozzolanic compressive strength activity index (SAI) after seven, 28, and 91 days ageing at 20 per cent and 40 per cent PC substitutions. PF was found to be comparable to FA as a pozzolan at 20 per cent PC substitution at all ages tested. However, for the 40 per cent substitution blends significant strength was only achieved at 91 days ageing for the FA blend. The pozzolanic reactivity was also investigated using thermogravimetric analysis to determine the degree of free lime present after 91 days. In all cases where an SCM was added, the free lime was observed to be consumed with increasing age

Pin1 promotes GR transactivation by enhancing recruitment to target genes

The glucocorticoid receptor (GR) is a ligand activated transcription factor, serving to regulate both energy metabolism and immune functions. Factors that influence cellular sensitivity to glucocorticoids (GC) are therefore of great interest. The N-terminal of the GR contains numerous potential proline-directed phosphorylation sites, some of which can regulate GR transactivation. Unrestricted proline isomerisation can be inhibited by adjacent serine phosphorylation and requires a prolyl isomerise, Pin1. Pin1 therefore determines the functional outcome of proline-directed kinases acting on the GR, as cis/trans isomers are distinct pools with different interacting proteins. We show that Pin1 mediates GR transactivation, but not GR trans-repression. Two N-terminal GR serines, S203 and S211, are targets for Pin1 potentiation of GR transactivation, establishing a direct link between Pin1 and the GR. We also demonstrate GC-activated co-recruitment of GR and Pin1 to the GILZ gene promoter. The Pin1 effect required both its WW and catalytic domains, and GR recruitment to its GRE was Pin1-dependent. Therefore, Pin1 is a selective regulator of GR transactivation, acting through N-terminal phospho-serine residues to regulate GR recruitment to its target sites in the genome. As Pin1 is dysregulated in disease states, this interaction may contribute to altered GC action in inflammatory conditions

Evaluation of a hybrid system of admixture and fibre for development of shrinkage resistant cement-based material

Shrinkage is a crucial feature in concrete and mortar members as it results in volume change that can lead to cracking and consequently to serviceability problems. Different additives and methods have been proposed to compensate for this problem mainly through the use of shrinkage reducing admixtures, fibres and expansive agents. In this paper, several combination systems of polyethylene micro-fibre along with an inorganic expansive agent have been studied for their influence on drying shrinkage. This special type of fibre, reported to act as shrinkage reducer, had been used in different concentrations in mortars and had been shown to have advantages and disadvantages. On the other hand, expansive agent, ammonium polyphosphate, had been shown to reduce drying shrinkage and modify most of mechanical properties. Free shrinkage strains as well as some physical properties of new mixes which contain polyphosphate and polyethylene micro-fibre are reported in this study. Several combinations were used and have been shown to have promising results in drying shrinkage, physical and mechanical properties

Large firm dominance on country’s entrepreneurship potentials

This paper aims to determine whether countries where large firms are very dominant have less entrepreneurial activities. There is anecdotal evidence that the continued decline in the business dynamism or the number of start-ups in the United States is said to be partly attributed to large firms. One key explanation is that the regulatory environment tends to favor existing large firms - an environment that allows near monopolies and a protection of tiny entrepreneurial elite. Using the Global Entrepreneurship Monitor (GEM) data together with the World Bank - International Finance Corporation's MSME country indicators, I empirically test whether large firm dominance influences entrepreneurial activities as well as intentions. Using fixed effects regression analysis on unbalanced panel of 40 countries over the period 2002-2007, I found that the entrepreneurship potential of a country is potentially at risk if the growth of large firms' stake in the economy is left unchallenged. In particular, a one percentage point increase in the share of large firms to total employment is associated with 0.35 percentage point lower total early-stage entrepreneurial activity rate, holding other factors constant. Also, worth noting is the sensitivity of entrepreneurial intentions to large firm dominance. A one percentage point increase in the share of large firms to total employment dampens (i.e., by 0.56 percentage point) intentions of latent entrepreneurs to start a business within the next 3 years, other factors remaining constant. This second-order effect of large firm dominance depends heavily on the country's institutions. Thus, it is critical for governments to foster a dynamic system that guarantees free competition and rewards creativity. Likewise, it is necessary to review and amend policies that seem to favor large firms that compromise the establishment as well as growth of smaller enterprises