950 research outputs found

    Impact differences among the landing phases of a drop vertical jump in soccer players

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    The aim of this study was to examine the differences of landing phase biomechanics between the players who had anterior cruciate ligament (ACL) reconstruction and healthy participants during single leg drop vertical jump. In this study, 11 soccer players who had anterior cruciate ligament reconstruction (aged 23.0±3.6 years, height 177±5.0 cm, weight 83.8±11.7 kg) and 9 healthy soccer players( aged 22.2±2.4 years, height 178±3.0 cm, weight 74.3±6.1 kg) participated voluntarily. During the data collection phase three high speed cameras synchronized to each other and force plate were used. Visual analysis programme and MATLAB were used to calculate kinetic and kinematic variables. Landing techniques of the subjects' were examined by flexion angle of knee, ground reaction force and moment parameters. The statistical analyses of the measured results were performed by t-test and Pearson Correlation analysis. According to the results, it was determined that peak vertical ground reaction force exhibited significant phase differences (p=0.00, and p=0.00, respectively) between the groups. Obtained results can be explained with "quadriceps avoidance" motion pattern which is characterized by decreased quadriceps activity and lower external knee flexion moment in an effort to control anterior translation of the tibia in subjects with ACL reconstruction. A better understanding of the different phases during single-leg landings can shed a light on mechanism of non-contact anterior crucaite ligament injuries therefore future researches should assess how phase differences affect drop vertical jump performance. © 2018 Montenegrin Sports Academy. All rights reserved

    Cascading of Molecular Logic Gates for Advanced Functions: A Self-Reporting, Activatable Photosensitizer

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    Cataloged from PDF version of article.Logical progress: Independent molecular logic gates have been designed and characterized. Then, the individual molecular logic gates were coerced to work together within a micelle. Information relay between the two logic gates was achieved through the intermediacy of singlet oxygen. Working together, these concatenated logic gates result in a self-reporting and activatable photosensitizer. GSH=glutathione

    Expanded Bodipy Dyes: Anion Sensing Using a Bodipy Analog with an Additional Difluoroboron Bridge

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    Cataloged from PDF version of article.Oxalyl-tethered pyrroles can be doubly bridged with two difluoroboron chelating units to yield bright orange dyes. Interestingly, in polar organic solvents, the addition of fluoride and cyanide result in reversible detachment of the otherwise stable difluoroboron bridges, resulting in sharp changes in color. Thus, this novel compound behaves as a highly selective chromogenic sensor for fluoride and cyanide ions

    From Virtual to Physical: Integration of Chemical Logic Gates

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    Cataloged from PDF version of article.Integration by parts: Advanced information processing at the molecular level requires integrated logic gates, which has to date been possible only virtually. Now, two independently working AND molecular logic gates are brought together by "click" chemistry to form integrated logic gates which respond exactly as predicted from such an integration scheme (see picture, EET=excitation energy transfer). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

    Atropisomeric Dyes: Axial Chirality in Orthogonal BODIPY Oligomers

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    Cataloged from PDF version of article.A dissymmetrically substituted orthogonal BODIPY dimer and an orthogonal BODIPY trimer exist as two stable conformers, which are in fact atropisomeric enantiomers. The racemic mixture can be separated by HPLC using a chiral stationary phase. These enantiomeric derivatives hold great potential as chiral agents in asymmetric synthesis, fluorogenic/chromogenic sensing, and biological applications

    Evaluation of metabolic profiles of Saanen goats in the transition period

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    ΔΕΝ ΔΙΑΤΙΘΕΤΑΙ ΠΕΡΙΛΗΨΗHealthy Saanen goats (n=30) in periparturient period were used in the present study. Blood samples were collected 21, 14 and 7 days before parturition, at the time of birth and postpartum days 7, 14 and 21. Non-esterifiedfatty acids (NEFA), betahydroxy butyric acid (BHBA), Total protein (TP), albumin (ALB), blood urea nitrogen (BUN), creatinine (CREA) aspartate amino transferase (AST), gamma glutamyl transferase (GGT), sorbitol dehydrogenase (SDH), glucose (GLU), cholesterol (CHOL), triglyceride (TG), calcium (Ca), phosphorus (P), and magnesium (Mg) levels were evaluated. During the study period, NEFA, SDH, CREA levels increased and CHOL and TG levels decreased at time of parturition. When the changes of parameters in prepartum and postpartum period were compared, the concentrations of NEFA, CHOL, GLU, TG, Ca were higher (p <0.001) in prepartum period;however BHBA, Mg, ALB, GGT, AST, TP, P, BUN, SDH and CREA concentrations were detected to be higher (p <0.001) in postpartum period. Metabolic Profile Test based on biochemical parameters evaluated in our study would be beneficial for diagnosis, prevention and control of diseases such as pregnancy toxemia, hypocalcemia, infertility in goats

    Chromogenic and Fluorogenic Sensing of Biological Thiols in Auqeous Solutions Using BODIPY-Based Reagents

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    Cataloged from PDF version of article.udicious design of BODIPY dyes carrying nitroethenyl substituents in conjugation with the BODIPY core yields dyes that respond to biological thiols by both absorbance and emission changes. Incorporation of solubilizing ethyleneglycol units ensures water solubility. The result is bright signaling of biologically relevant thiols in the longer wavelength region of the visible spectrum and in aqueous solutions
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