Mercury accumulation in fishes from tropical aquatic ecosystems in the Niger Delta, Nigeria

Fishes are important biomarkers of trace elements in aquatic ecosystems, and are used to evaluate the status of water pollution by mercury in tropical aquatic ecosystems in Nigeria. Common fishes, Chrysichthys nigrodigitatus,Brycinus nurse, Hemichromis fasciatus, Lutianus ava, Oreochromis nilotica, Pomadasys jubelini, Stellifer stellifer and Tilapia guineensis were analysed for Hg accumulation using the cold vapour atomic absorption spectrophotometry technique. The results showed that Hg concentration in P. jubelini was relatively the highest, with a mean concentration of 0.063 ± 0.03 mg kg–1. Other concentration values were 0.044 ± 0.031 mg kg–1 for O. nilotica, 0.026 ± 0.013 mg kg–1 for B. nurse, 0.034 ± 0.034 mg kg–1 for H. fasciatus, 0.023 ± 0.020 mg kg–1 for C. nigrodigitatus and 0.33 ± 0.016 mg kg–1 for L. ava. Concentrations of Hg accumulated by the fishes were low and within internationally accepted limit, not likely to cause mercury poisoning. Because of the high Hg accumulating potential of P. jubelini, it is recommended as a biomarker for assessment of Hg toxicity in a tropical aquatic environment

Petroleum hydrocarbons and limiting nutrients in Macura reptantia, Procambarus clarkii and benthic sediment from Qua Iboe Estuary, Nigeria

The levels of total petroleum hydrocarbons in two commonly consumed benthopelagic shellfishes, Macura reptantia and Procambarus clarkii, harvested from benthic sediment of Qua Iboe Estuary were determined using a gas chromatography with flame-ionization detector. Seventy-two (72) samples each of benthic sediment and the shellfishes were collected monthly between June 2003 and February 2004 covering the peak periods of the wet and dry seasons. Concentrations of hydrocarbons were highly variable and ranged between 5.00 and 232.00 μg/g dry weight of benthic sediment, 3.05 and 11.30 μg/g dry weight of M. reptantia, 1.62 and 9.00 μg/g dry weight of P. clarkii. Pearson’s correlation analysis of total hydrocarbon concentrations in subtidal sediments with levels in the fauna species yielded positive significant (P < 0.05) correlations in M. reptantia (r = 0.737) and P. clarkii (r = 0.924). This is indicative of a long term and chronic accumulation of hydrocarbons in the estuarine ecosystem, reflecting the potential for exposure of the resident biota and the risk to human health

Petroleum Hydrocarbons Accumulation Potential of Shellfishes from Littoral Waters of the Bight of Bonny, Niger Delta, Nigeria.

Total hydrocarbons concentration in four commercially available shellfishes (Ocypoda africanus, Macura reptantia, Procambarus clarkii and Penaeus notialis) from coastal waters of the Niger Delta region of Nigeria were investigated between June 2003 and February 2004 using standard methods. Levels of total hydrocarbons varied significantly depending on biota species, feeding habit and season. The seasonal mean concentrations reported were: 3.98±0.69, 7.95±1.18, 2.24±0.39 and 5.85±0.57 μg g -1 dry weight for M. reptantia, O. africanus, P. clarkii and P. notialis respectively during the wet season. Enhanced concentrations recorded during the dry season were 7.81±2.32, 11.59±2.63, 6.16±2.12 and 9.69±1.90 μg g-1 dry weight for M. reptantia, O. africanus, P. clarkii and P. notialis, respectively. The results obtained indicated seasonal variations which might have been associated with an incidental crude oil spill recorded during the investigation. In general, O. africanus showed higher levels of total hydrocarbons than other species investigated. However, biota species demonstrated hydrocarbon bioaccumulation potential. Regression between the monthly concentrations of total hydrocarbons in each of the biospecimens with the levels in the surface water and sediments indicated statistically significant (p&lt;0.05) relationships. Moreover, comparison of the seasonal mean concentrations using paired sample t-test at 95% confidence level indicated that the concentrations between the dry and wet seasons were statistically significant

Carcinogenicity and Mutagenicity Assessments of Dietary Exposure to PAHs in Imported Fish Products in Nigeria.

Polycyclic aromatic hydrocarbons (PAHs) occurrence and assessment of dietary exposure from imported canned sardines (Sardinops sagax) commercially marketed in local stores and supermarkets in Nigeria were evaluated for the first time. PAHs determinations were performed using high performance liquid chromatography (HPLC) (Agilent 1290 model) equipped with UV-VIS diodes array detector (DAD) at λ =210 nm and 214 nm. The percentages recoveries were higher than 96%. The degree of contamination expressed as total concentrations of PAH (TPAHs) congeners ranged between 2.53 and 35.55 μg kg−1 dry weight (d.w.) at λ = 210 nm, and 1.30 and 27.93 μg kg−1 (d.w.) at λ = 214 nm. The carcinogenic (BaP-TEQ) and mutagenic toxicities (BaP-MEQ) of eight priority PAHs were evaluated. Benzo(a)pyrene, benzo(b)fluoranthene, benzo(k)fluoranthene and indeno(1,2,3-d) pyrene contributed significantly to the total carcinogenic equivalents of PAHs. The mutagenic equivalents were largely influenced by equivalence factors of benzo(a)anthracene, and benzo(a)pyrene and indeno(1,2,3-d) pyrene. The estimated daily intake (EDI) and excess cancer rate (ECR) were evaluated for adults and children exposure related risks

Green synthesis of iron-based nanomaterials for environmental remediation: A review

The ever-increasing importance of green-based iron nanoparticles within the last decade and their environmental applications is a compelling reason to probe novel routes for their synthesis. Therefore, the principles of green chemistry, waste prevention, energy efficiency, safer solvents, and the benign precursor materials have become fundamental considerations in the synthesis process of these materials, birthing extensive study in this field. In this light, a comprehensive discussion of the successes of greener techniques and other biological nanotechnologies including the use of microorganisms (fungi, bacteria, actinomycetes, and viruses), algae, plant and their extracts for the synthesis of iron (Fe) nanoparticles (NPs) is presented. Although promising findings have been reported, substantial research gaps and the opportunity to capitalize on the emergence and rise of these eco-friendly sources have been identified. The application of synthesized nanoparticles for environmental remediation and their toxicological implications are also discussed

Absence of Germline BRCA1 c.68_69delAG and c.5266dupC Mutations among Hormone Receptor-negative Breast Cancer Patients: A First Impression at a Tertiary Cancer-care Facility in Tanzania

The germline BRCA1 c.68_69delAG (185delAG) and c.5266dupC (5382insC) mutations are associated with hormone receptor-negative breast cancer (BC).&nbsp; Limited studies have examined their contribution to alarming BC incidence in Sub Saharan Africa (SSA). Our study aimed to examine the contribution of &nbsp;germline BRCA1 c.68_69delAG and c.5266dupC mutations to BC incidence among hormone receptor-negative BC patients admitted to Ocean Road Cancer Institute in Tanzania. Face-to-face interviews were conducted to capture socio-demographic characteristics, anthropometric measurements, family history of cancer and reproductive information from each patient. Their &nbsp;histopathological data were extracted from the hospital medical records. The germline BRCA1 founder mutations were analyzed on blood samples using Sanger sequencing technology. The patients mean age at diagnosis was 47.05 ± 12.82 years. A family history of cancer was observed in 13.6% of patients. The germline BRCA1 c.68_69delAG and c.5266dupC mutations were not detected in the study group. Our findings indicate that the germline BRCA1 c.68_69delAG and c.5266dupC mutations do not contribute to BC manifestation in hormone receptor-negative BC patients in Tanzania. Thus, screening BC patients for these mutations has no clinical relevance. Our data further suggest that the c.68_69delAG and the c.5266dupC mutations should not be considered when developing genetic testing guidelines in Tanzania. Keywords: Breast cancer, germline BRCA1 mutation, c.68_69delAG (185delAG), c.5266dupC (5382insC), Tanzani

Hydrodynamic Analysis of a Wave Energy Converter (WEC)

Honorable Mention Winner The UNF CREW competing in the U.S. Department of Energy 2021 Marine Energy Collegiate Competition developed a Wave Energy Converter (WEC) for quick deployment in disaster relief areas. When natural disasters disable coastal power grids, a WEC can be easily deployed close to shore and serve as a source of electricity. The ocean waves move magnets through a coil wired within the WEC to generate electricity. To initiate the design process, ANSYS AQWA software simulated both the oceanic environment and the device’s response in the WEC’s testing conditions. AQWA allows the user to change device dimensions easily and optimize the design ahead of physical construction. The resulting WEC proof of concept minimized prototype manufacturing waste and cost by eliminating poor designs in advance. The simulated geometry neglected hollow sections and used unidirectional, regular waves to account for software limitations. The software simulated the WEC for 20 seconds in an oceanic environment with a 40-meter depth and a 0.25-meter amplitude regular wave. Simulations produced graphs and animations describing the forces acting on the WEC as well as the WEC’s movement. The animation proved that the WEC reacts well in similar physical testing conditions. Based on the simulation results, the team constructed a 3D model for small-scale testing. Future investigations will involve more complex designs. Research conducted onward will focus on mass-damper systems and contact surfaces provided in the software

Optimization of Power Performance of a Wave Energy Converter

With climate change on the rise, unprecedented dependence on electricity, and an increased incidence of extreme weather, the UNF team participating in the U.S. Department of Energy 2021 Marine Energy Collegiate Competition: Powering the Blue Economy wants to give an alternative solution to provide renewable energy in areas that lose electricity as a result of a natural disaster, or that due to their isolated location cannot use traditional renewable energy sources. This led to the creation of the Osprey C.R.E.W (Cheap Reliable Energy from Waves). The Osprey C.R.E.W. is a wave energy converter that uses the vertical motion of the ocean waves to generate electricity. The principle of energy conversion is Faraday’s Law of Electromagnetic Induction, which states that a magnetic field moving past a conductor will generate electricity. The UNF team has developed a numerical simulation to test how different parameters influence the output and has built three small-scale prototypes that have been tested in a wave tank. A medium-sized prototype and a wave pool are being constructed, with the expectation that the size will also increase the output

Cost Analysis of Osprey C.R.E.W.

Renewable energy adoption is on the rise in the U.S. and abroad. More than ever, energy sourcing needs to shift away from harmful fossil fuels and towards fully renewable energy sources. Adapting from traditional fossil fuel energy sources to renewable energy sources is paramount for environmental health and public health. Fossil fuels emit harmful pollutants, which have led to changing weather conditions and exasperated natural disasters. Existing renewable sources are not ideal, either. For instance, solar cannot run continuously and wind turbines are subject to weather changes. The recent energy debacle in Texas shows the need for alternative renewable energy sources. The Osprey C.R.E.W. wave energy converter (WEC) alleviates many of the current problems existing renewable energy systems cannot solve. First, it provides reliable and constant service. With other renewable energy services, there will be stops in production. However, there are no stops in wave energy because the waves are constant. Another positive of the WEC device is that their deployments are flexible and scalable. This means that energy production levels can be changed rapidly and without delay. The average cost per device falls significantly with seamless scalability, making large increments of devices procured in a relatively cost-effective manner. Cost comparisons between competing energy sources show that the WEC is very cost-efficient as well. The cost of producing wave energy is found to be more efficient than solar energy and wind alternatives. Our cost figures also show that Osprey C.R.E.W provides a very competitive alternative to the primary fossil fuel producers such as coal and fuel