D region formation

Ionospheric absorption of charged particles and photons, and ionization by solar radiation, cosmic rays, and Lyman alpha radiatio

The influence of ionization events on atmospheric ozone

Atmospheric ionization events can modify the concentration of neutral species in the stratosphere and mesosphere. In particular, ozone is destroyed because of the production of significant quantities of odd nitrogen and hydrogen compounds which react photochemically to destroy ozone. Direct evidence of ozone depletion comes from data taken during and following two solar flares generating large fluxes of 10-100 Mev protons, which bombarded the polar stratosphere and mesosphere. Observations of ozone taken during X-ray emission by solar flares and energetic electron precipitation during aurorae indicates ozone destruction above 50 km by ionization produced odd hydrogen. Lightning is apparently a large contributor to the tropospheric odd nitrogen budget. Ion propulsion induced dumping of the inner proton radiation belt represents a human activity which may influence stratospheric NOx

SMM mesospheric ozone measurements

The main objective was to understand the secular and seasonal behavior of ozone in the lower mesosphere, 50 to 70 km. This altitude region is important in understanding the factors which determine ozone behavior. A secondary objective is the study of stratospheric ozone in the polar regions. Use is made of results from the SBUV satellite borne instrument. In the Arctic the interaction between chlorine compounds and low molecular weight hydrocarbons is studied. More than 30,000 profiles were obtained using the UVSP instrument on the SMM spacecraft. Several orbits of ozone data per day were obtained allowing study of the current rise in solar activity from the minimum until the present. Analysis of Nimbus 7 SBUV data in Antarctic spring indicates that ozone is depleted within the polar vortex relative to ozone outside the vortex. This depletion confirms the picture of ozone loss at altitudes where polar stratospheric clouds exist. In addition, there is ozone loss above the cloud level indicating that there is another mechanism in addition to ozone loss initiated by heterogeneous chlorine reactions on cloud particles

Ion clusters and the Venus ultraviolet haze layer

The daytime ionosphere of Venus is observed between 100 and 500 km altitude with a peak electron concentration of 100,000/cc at 140 km. It is suggested that at altitudes less than 130 km the ion CO2(+)-CO2 is an important ionic constituent of the Venus ionosphere. Below 100 km ion clustering processes combine with the low temperature at the mesopause to form coagulates, giving rise to the ultraviolet haze layer observed. An atmospheric model is presented

Nighttime ion composition measurements at the geomagnetic equator

Two ion composition profiles, representative of the nighttime equatorial ionosphere between 90 km and 300 km, are presented. These profiles were obtained by two rocket-borne ion mass spectrometers on a single night for solar zenith angles of 112 deg and 165 deg. For both flights, the principal ion above 200 km is O(+). The downward drift of the atomic ions O(+) and N(+), coinciding with the postsunset lowering of the F2 peak, is observed through an enhancement of the density of O(+) at altitudes above 200 km and N(+) above 240 km. Below the drift region, O(+) and N(+) are observed in concentrations larger than expected. The NO(+) altitude distribution retains its shape throughout the night, and below 210 km, is the principal ion. The behavior of O2(+) can be explained by the O(+), electron density and theoretical neutral nitric oxide concentrations. Light metallic ions, including Mg(+), Na(+), and possibly Si(+), are observed to altitudes approaching 300 km and are affected by vertical drift

Some results of rocket experiments in the quiet d region

Electron density profiles for quiet day mid- latitude d region using nike-apache sounding rocket

Ion composition and drift observations in the nighttime equatorial ionosphere

The first in situ measurements of ion composition in the nighttime equatorial E and F region ionospheres (90-300 km) are presented and discussed. These profiles were obtained by two rocket-borne ion mass spectrometers launched from Thumba, India on March 9-10, 1970 at solar zenith angles of 112 deg and 165 deg. Ionosonde data established that the composition was measured at times bounding a period of F region downward drift. During this period the ions O(+) and N(+) were enhanced by one to three orders of magnitude between 220 and 300 km. Below the drift region (200 km), O(+) ceased to be the major ionic constituent, but the concentrations of O(+) and N(+) remained larger than predicted from known radiation sources and loss processes. Here also, both the O2(+) and NO(+) profiles retained nearly the same shape and magnitude throughout the night in agreement with theories assuming scattered UV radiation to be the maintaining source. Light metallic ions including Mg(+), Na(+) and possibly Si(+) were observed to altitude approaching 300 km, while the heavier ions Ca(+) and K(+) were seen in reduced quantity to 200 km. All metal ion profiles exhibited changes which can be ascribed to vertical drifting

Space-borne measurements of mesospheric magnesium species ? a retrieval algorithm and preliminary profiles

International audienceWe present a joint retrieval as well as first results for mesospheric air density and mesospheric Magnesium species (Mg and Mg+) using limb data from the SCIAMACHY instrument on board the European ENVISAT satellite.considered. These species feature Metallic species like neutral Mg, ionized Mg+ and others (Fe, Si, Li, etc.) ablate from meteoric dust, enter the gas phase and occur at high altitudes (?70 km). Emissions from these species are clearly observed in the SCIAMACHY limb measurements. These emissions are used to retrieve total and thermospheric column densities as well as preliminary profiles of metallic species in the altitude range of 70?92 km. In this paper, neutral Magnesium as well as its ionized counterpart Mg+ is considered. These species feature resonance fluorescence in the wavelength range 279 and 285 nm and thus have a rather simple excitation process. A radiative transfer model (RTM) for the mesosphere has been developed and validated. Based on a ray tracing kernel, radiances in a large wavelength range from 240?300 nm covering limb as well as nadir geometry can be calculated. The forward model has been validated and shows good agreement with established models in the given wavelength range and a large altitude range. The RTM has been coupled to a retrieval based on Optimal Estimation. Air density is retrieved from Rayleigh backscattered light. Mesospheric Mg and Mg+ number densities are retrieved from their emission signals observed in the limb scans of SCIAMACHY. Other species like iron, silicon, OH and NO can be investigated in principle with the same algorithm. Based on the retrieval presented here, SCIAMACHY offers the opportunity to investigate mesospheric species on a global scale and with good vertical resolution for the first time

Natural Cycles, Gases

The major gaseous components of the exhaust of stratospheric aircraft are expected to be the products of combustion (CO2 and H2O), odd nitrogen (NO, NO2 HNO3), and products indicating combustion inefficiencies (CO and total unburned hydrocarbons). The species distributions are produced by a balance of photochemical and transport processes. A necessary element in evaluating the impact of aircraft exhaust on the lower stratospheric composition is to place the aircraft emissions in perspective within the natural cycles of stratospheric species. Following are a description of mass transport in the lower stratosphere and a discussion of the natural behavior of the major gaseous components of the stratospheric aircraft exhaust

Controlled Thermal Expansion Coat for Thermal Barrier Coatings

A improved thermal barrier coating and method for producing and applying such is disclosed herein. The thermal barrier coating includes a high temperature substrate, a first bond coat layer applied to the substrate of MCrAlX, and a second bond coat layer of MCrAlX with particles of a particulate dispersed throughout the MCrAlX and the preferred particulate is Al2O3. The particles of the particulate dispersed throughout the second bond coat layer preferably have a diameter of less then the height of the peaks of the second bond coat layer, or a diameter of less than 5 microns. The method of producing the second bond coat layer may either include the steps of mechanical alloying of particles throughout the second bond coat layer, attrition milling the particles of the particulate throughout the second bond coat layer, or using electrophoresis to disperse the particles throughout the second bond coat layer. In the preferred embodiment of the invention, the first bond coat layer is applied to the substrate, and then the second bond coat layer is thermally sprayed onto the first bond coat layer. Further, in a preferred embodiment of die invention, a ceramic insulating layer covers the second bond coat layer