Coupled degassing and crystallization: experimental study at continuous pressure drop, with application to volcanic bombs

Experiments on degassing of water-saturated granite melts with a pressure drop from 100 and 450 MPa to 40 and 120 MPa, respectively, at temperatures close to feldspar liquidus (750-700 degrees C), were carried out to determine the modality of water exsolution and vesicle formation at the liquidus temperature. Pressure-drop rates as small as approximately 100 bar/day were used. Uniform space distributions of bubbles of exsolved water were obtained with starting glass containing a small fraction (approximate to 0.5 vol.%) of trapped air bubbles. Volume crystallization of feldspar was observed in degassed melts supplied with seeds. Bubble size distributions (BSD) measured in granite glasses after degassing are presented. Data on vesicle characteristics (number, radius, area, elongation) were acquired on images digitized with standard software, while the reconstruction of size distributions was performed with the Schwartz-Saltikov "unfolding" procedure. Bubble size distributions of size classes in the range 5-1000 mu m were acquired with proper magnification and satisfactory statistical reliability of determined number densities. The BSDs of the experimental samples are compared with the results of measurements of rapidly degassed products of Mt. Etna and Vulcano Island. Many particular features of the bubble nucleation and growth can be distinguished in an individual BSD. However, the general BSD of the whole data set, including natural ones, can be relatively well described with linear regression in bilogarithmic coordinates. The slope of this regression is approximately 2.8 +/- 0.1. This dependence is in striking contrast with distributions theoretically predicted with classical nucleation models based on homogeneous nucleation of vesicles. The theoretical distribution requires the occurrence of strong maxima that are not observed in our experimental and natural samples, thus arguing for heterogeneous nucleation mechanisms

Kinetics of clinopyroxene growth from a hydrous hawaiite melt

Melting phase relations were studied for a hawaiitic composition with 2.4 +/- 0.1 wt % water under a pressure of 600 bar and oxygen fugacity near the Ni-NiO buffer. These conditions correspond to the degassing and eruption of Etna Volcano, Sicily. The experimental liquidus temperatures of olivine (1120degreesC) and clinopyroxene (1105degreesC) are in agreement with the values calculated by the MELTS software package. The growth rates of olivine and clinopyroxene were estimated by the quench method using forsterite and diopside seeds. At an undercooling of DeltaT= 25 +/- 5 K, lathlike clinopyroxene grew at a rate of (2.0-2.5) x 10(-5) cm/s and contained 6.5-8.5 wt % Al-O-2(3). Under similar conditions, diopside seeds are evenly overgrown at an order of magnitude lower rate, (2-3) x 10(-6) cm/s. At DeltaT approximate to 5 K (T = 1100degreesC), diopside seeds are evenly overgrown with the formation of growth steps on the surface of crystals. The growth rate of olivine is low, 7 x 10(-7) cm/s at 1075degreesC (DeltaT = 45 +/- 5 K). This is consistent with the small amount of olivine forming during cooling of hydrous hawaiite melt calculated by the MELTS program

Balancing bulk gas accumulation and gas output before and during lava fountaining episodes at Mt. Etna

We focus on a sequence of 9 lava fountains from Etna that occurred in 2011, separated by intervals of 5 to 10 days. Continuous measurements allowed to discover the occurrence of gravity decreases before the onset of most fountaining episodes. We propose that the gravity changes are due to the pre-fountaining accumulation of a foam layer at shallow levels in the plumbing system of the volcano. Relying on the relationship between amount of gas trapped in the foam and amount of gas emitted during each episode, we develop a conceptual model of the mechanism controlling the passage from Strombolian to lava fountaining activity. Gas leakage from the foam layer during the late stages of its accumulation increases the gas volume fraction at upper levels, thus inducing a decrease of the magma-static pressure in the trapping zone and a further growth of the foam. This feedback mechanism eventually leads to the collapse of the foam layer and to the onset of lava fountaining. The possibility to detect the development of a foam layer at depth and to set quantitative constraints on the amount of trapped gas is important because of the implications for forecasting explosive eruptions and predicting their intensity

Magma reservoir dynamics at Toba caldera, Indonesia, recorded by oxygen isotope zoning in quartz

Quartz is a common phase in high-silica igneous rocks and is resistant to post-eruptive alteration, thus offering a reliable record of magmatic processes in silicic magma systems. Here we employ the 75 ka Toba super-eruption as a case study to show that quartz can resolve late-stage temporal changes in magmatic δ18O values. Overall, Toba quartz crystals exhibit comparatively high δ18O values, up to 10.2‰, due to magma residence within, and assimilation of, local granite basement. However, some 40% of the analysed quartz crystals display a decrease in δ18O values in outermost growth zones compared to their cores, with values as low as 6.7‰ (maximum ∆core−rim = 1.8‰). These lower values are consistent with the limited zircon record available for Toba, and the crystallisation history of Toba quartz traces an influx of a low-δ18O component into the magma reservoir just prior to eruption. Here we argue that this late-stage low-δ18O component is derived from hydrothermally-altered roof material. Our study demonstrates that quartz isotope stratigraphy can resolve magmatic events that may remain undetected by whole-rock or zircon isotope studies, and that assimilation of altered roof material may represent a viable eruption trigger in large Toba-style magmatic systems

Bubble development in explosive silicic eruptions: insights from pyroclast vesicularity textures from Raoul volcano (Kermadec arc)

Critical to understanding explosive eruptions is establishing how accurately representative pyroclasts are of processes during magma vesiculation and fragmentation. Here, we present data on densities, and vesicle size and number characteristics, for representative pyroclasts from six silicic eruptions of contrasting size and style from Raoul volcano (Kermadec arc). We use these data to evaluate histories of bubble nucleation, coalescence, and growth in explosive eruptions and to provide comparisons with pumiceous dome carapace material. Density/vesicularity distributions show a scarcity of pyroclasts with ∼65–75 % vesicularity; however, pyroclasts closest to this vesicularity range have the highest bubble number density (BND) values regardless of eruptive intensity or style. Clasts with vesicularities greater than this 65–75 % “pivotal” vesicularity range have decreasing BNDs with increasing vesicularities, interpreted to reflect continuing bubble growth and coalescence. Clasts with vesicularities less than the pivotal range have BNDs that decrease with decreasing vesicularity and preserve textures indicative of processes such as stalling and open system degassing prior to vesiculation in a microlite-rich magma, or vesiculation during slow ascent of degassing magma. Bubble size distributions (BSDs) and BNDs show variations consistent with 65–75 % representing the vesicularity at which vesiculating magma is most likely to undergo fragmentation, consistent with the closest packing of spheres. We consider that the observed vesicularity range may reflect the development of permeability in the magma through shearing as it flows through the conduit. These processes can act in concert with multiple nucleation events, generating a situation of heterogeneous bubble populations that permit some regions of the magma to expand and bubbles to coalesce with other regions in which permeable networks are formed. Fragmentation preserves the range in vesicularity seen as well as any post-fragmentation/pre-quenching expansion which may have occurred. We demonstrate that differing density pyroclasts from a single eruption interval can have widely varying BND values corresponding to the degree of bubble maturation that has occurred. The modal density clasts (the usual targets for vesicularity studies) have likely undergone some degree of bubble maturation and are therefore may not be representative of the magma at the onset of fragmentation