17 research outputs found
Assembly of petrol engine and conversion to LPG system / Tg. Mohd. Tg. Ab. Rahman, Yusoff Yaacob and Rasdi Deraman
There are two separate frames made in this project. i. Frame for engine petrol. ii. Frame for L.P.G. system. All the dimensions for the frames are measured according to the engine and L.P.G. equipments sizes. The components of the frames are joint by using arc welding. The types of joint used is square butt-joint. (See Fig: 1.1a and 1.1b Page and ) 1.1.1. PROCEDURE FOR ARC WELDING i. The place to be welded must be clean and free from dust, paint or any other contaminants. ii. Set the voltage according to the thickness of the plate to be joint. iii. Set correct clearance between two plate to be joint
The Experimental Study On The Potential Of Waste Cooking Oil As A New Transformer Insulating Oil
Power transformers use mineral oil as an insulating liquid due to its outstanding dielectric properties. The poor biodegradability and toxicity of mineral oil have increased the interest in the use of a more environmentally friendly product such as ester-based oil. Generally, natural ester insulating oils (NEI) have a higher flash point and breakdown voltage compared to existing mineral oils. However, the higher price of NEI is the main obstacle to widely applied in power transformers. Therefore, alternative cheaper feedstock processing is required. This paper proposed waste cooking oil (WCO) as a potential alternative to the existing transformer insulating oil. The used of WCO promotes the optimal consumption of plant-based resources and more efficient waste management. Transesterification method is performed to remove the free fatty acids in the WCO and reduce the viscosity. The transesterification process is based on the chemical modification reaction between WCO, methyl alcohol
(methanol) and sodium hydroxide (NaOH) catalyst lye that produces waste cooking oil methyl ester (WCOME). Chemical and electrical properties i.e. water content, acidity and breakdown voltage of the developed WCOME are compared with the existing WCO according to IEEE Guide for Acceptance and Maintenance of Natural Ester Fluids in Transformers (IEEE C57.147
Reusable Gypsum Based Catalyst for Synthesis of Glycerol Carbonate from Glycerol and Urea
In this study, the catalytic carbonylation of glycerol with urea in the presence of gypsum based heterogeneous catalyst is reported for the first time. Gypsum (CaSO4·2H2O) is one of the two calcium sulphate minerals found in nature and also one of the waste materials produced from advanced material industrial processing plant. The effect of physical and chemical pre-treatment procedures on gypsum was investigated. To obtain the catalyst structure-activity relationship, the treated catalysts were characterized by means of several characterization techniques (i.e. XRD, TGA, BET surface area, SEM, FTIR, CO2–TPD, NH3–TPD and Hammett test). Tuneable physico-chemical properties of gypsum based catalysts were successfully prepared by varying the pre-treatment techniques, which later on contributed to the variation of catalytic activity toward glycerol carbonate formation from glycerol. The highest catalytic activity obtained was for catalyst consisting β-CaSO4 phase where it produced 92.8% conversion of glycerol, 90.1% selectivity and 83.6% yield of glycerol carbonate, respectively. The gypsum catalyst is easily recoverable and reusable for subsequent cycles of reaction. Similar physico-chemical properties of fresh and used catalyst were confirmed through XRD, FTIR and Hammett test analysis. Besides, the mechanistic pathway of glycerol carbonate was confirmed through the formation of glycerol carbamate as intermediate compound which was further established through time online analysis study using 13C NMR and ATR–FTIR, respectively. The study also clearly supports conversion of waste into wealth while promising proper disposal of waste to produce value added product
Non-noble supported catalyst for oxidation of glucose under mild reaction conditions
Catalytic oxidation of D-glucose to D-gluconic acid derivative with H2O2 has been studied using non-noble Cobalt supported catalyst. The catalysts were synthesized using the scalable incipient wetness impregnation method of Co/Al2O3 and Co/TS1. The catalysts have been characterized by TGA, XRD, FESEM-EDX, BET, FTIR, and Hammett test. The oxidation of the D-glucose into D-gluconic acid with yield of 82% (as sodium gluconate) and selectivity is about 100 % have been achieved in the presence of 5 wt.% Co/Al2O3 as a catalyst under mild reaction conditions (60 oC, pH 9, 1atm, 3h). Reusability study of Co/Al2O3 was proven to be stable for subsequent cycles of reaction with no notable changes in selectivity. Besides, the physic-chemical properties of spent catalyst were similarly characterized through FTIR and Hammett test analysis. The presence of gluconic acid was confirmed by HPLC. The apparent activation energy of reaction is 15 kJ mol-1 which is lower than the value reported by prior-art using gold catalysts suggesting different mechanism with dissimilar rate-determining step. The activation of H2O2 is mediated by Co crystallites on the catalyst surfaces, forming active oxygen species via hydroxyl and peroxyl radical intermediates and/or oxometal species. The basic sites on catalyst facilitate the activation of glucose. The findings could help to make a cost-effective catalyst for D-glucose conversion into valuable organic acid chemical
Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
Dual-layer hollow fiber (DLHF) micro-tubular solid oxide fuel cell (MT-SOFC)
consisting of nickel oxide-yttria-stabilized zirconia (NiO-YSZ) anode/YSZ elec�trolyte was fabricated via a single-step phase inversion-based co-extrusion/co�sintering technique in order to investigate the effect of different electrolyte
extrusion rates (1-5 mL min−1
) at different sintering temperature (1350�C,
1400�C, and 1450�C) under methane (CH4) condition. The DLHF co-sintered
at 1450�C was chosen as optimum temperature due to the good mechanical
strength and gas-tight property. Meanwhile, 18 to 34 μm of electrolyte thick�ness was achieved when electrolyte extrusion rate increase from 1 to
5 mL min−1
. Power density as high as 0.32 W cm−2 was obtained on the cell
with the electrolyte layer of 18 μm in thickness (DLHF1) which is 20% higher
than the cell with an electrolyte layer of 34 μm (DLHF5) which was only
0.12 W cm−2 when operated at 850�C. However, DLHF1 had suffered cracking
formation that originated from anode site which shortened the stability test
duration to only 8 hours of survival under 750�C. While DLHF5 can operate
up to 15 hours but an increase in electrolyte thickness had resulted in higher
ohmic area-specific resistance that lowering the power density. Fifty-seven per�cent reduction in cell performance was observed under methane condition
when compared to the cell that performs using hydrogen gas due to the carbon
deposition as proven by Raman spectroscopy and carbon, hydrogen, nitrogen,
and sulfur analyzer
Modular structure of web-based decision support systems for integrated pest management. A review
Poly(vinyl chloride) Ionic Liquid Polymer Electrolyte Based on Bis(fluorosulfonyl)Amide for Sodium Secondary Batteries
Poly(vinyl chloride) Ionic Liquid Polymer Electrolyte Based on Bis(fluorosulfonyl)Amide for Sodium Secondary Batteries
Cobalt supported alumina catalyst for oxidation of glucose to gluconic acid under mild reaction conditions
Glucose is one of the most essential carbohydrate feedstock for the production of industrial chemicals [1]. One of the important and valuable chemical as a starting feedstock to produce gluconic acid [2, 3]. On the rise of industries and new applications of gluconic acid, further increase in demand is expected to continue rising in future [4]. As the commercialize biochemical route is not recyclable, possesses negative impacts to environment and other drawbacks, many researchers have put much attention towards catalytic oxidation of glucose to gluconic acid with the use of selective heterogeneous catalyst. However, the selective oxidation of glucose is quite challenging as to the activity of catalyst and low conversion. These pose difficulties in designing process, operation and production at industrial scale [5]
Efficient and Reusable Iron-Zinc Oxide Catalyst for Oxidative Desulfurization of Model Fuel
In this study, Fe-ZnO catalyst synthesized via modified sol–gel technique with different Fe doping ratio (2, 3, and 5) wt% was explored for oxidative desulfurization (ODS) of model fuel. The sol-gel technique was adopted without the use of surfactants. The catalysts were characterized by several means of characterization techniques (TGA, XRD, FTIR, N2- physisorption, XPS, FESEM-EDX and NH3-TPD). The characterization results clearly showed that sol-gel technique is a suitable method to synthesize highly crystalline metal oxide materials with smaller particle size, higher surface area and tunable acidic properties. The ODS reaction conditions and Fe metal loading were found to influence the dibenzothiophene (DBT) removal efficiency. The catalytic ODS data showed that Fe-ZnO with 5 wt% of Fe catalyst is capable in total removal of DBT within shorter reaction time under mild reaction conditions in the presence of H2O2 as an oxidant. The catalyst is reusable for six consecutive cycles of reaction without regeneration steps and the characteristic of spent catalyst was confirmed with XRD and FTIR analysis. The close catalytic cycle involving H2O2 as an oxidant was shown through proposed mechanistic pathway