Structural And Magnetic Study Of Labacocu O5+δ

The structure and magnetic properties of the compound LaBaCuCo O5+δ have been studied for the non-stoichiometric oxygen concentration δ≈0.6. The structure is pseudo-cubic with a tripled perovskite unit cell. The crystal structure was determined by a combined Rietveld fit to neutron and synchrotron x-ray powder diffraction data in the orthorhombic Pmmm space group, with cell parameters a=3.9223 (3) Å, b=3.9360 (3) Å, c=11.7073 (8) Å, and V=180.74 (2) Å3 (room temperature). Antiferromagnetic ordering of Cu and Co magnetic moments is observed below 205 (4) K. The magnetic structure with cell aM =2a, bM =2b, and cM =2c, could be described with the Shubnikov space group Fmm m′. The magnetic moments of both equivalent Cu/Co sites were determined at 50 and 170 K to be 0.83 (3) μB and 0.58 (3) μB, respectively, consistent with one unpaired electron per atom. The fit of the intensities to a simple mean field magnetic model appeared to be insufficient to account for the variation of moments at temperatures close to TN while a three dimensional Heisenberg model could improve the fit. Susceptibility measurements between 4 and 350 K also show irreversibility below 150 K. The local environments of Cu and Co were studied by extended x-ray absorption fine structure spectroscopy at both absorption edges. Cu atoms adopt an elongated octahedral or square-based pyramidal oxygen environment which suggests mainly the presence of Cu(II) in the structure. Co adopts different local environments, depending on the electronic and spin states. © 2005 The American Physical Society.7114Er-Rakho, L., Michel, C., Lacorre, P., Raveau, B., (1988) J. 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Elastic properties of polycrystalline YBa_2Cu_3O_7: Evidence for granularity induced martensitic behavior

In this work we present the study of the elastic properties of polycrystalline samples of superconducting YBa_2Cu_3O_7 prepared by the sol-gel method. The quality of all samples was checked by x-ray diffraction and scanning electronic microscopy while their physical properties were verified by transport and magnetic measurements. The elastic study was performed using the standard pulse-echo technique through measuring the phase velocity and the attenuation of ultrasonic waves (in the range of a few MHz) as a function of temperature. We have focused this study on the low temperatures interval (T < 200K). The obtained results show a strong hysteretic behavior in the ultrasonic attenuation (in addition to usually observed hysteretic behavior for the velocity) which strongly supports the existence of a martensitic-like phase above the superconducting critical temperature T_C. We argue that this peculiar behavior can be attributed to the granularity present in the samples.Comment: Physica C (in press