1,976 research outputs found
The role of hydrogen in room-temperature ferromagnetism at graphite surfaces
We present a x-ray dichroism study of graphite surfaces that addresses the
origin and magnitude of ferromagnetism in metal-free carbon. We find that, in
addition to carbon states, also hydrogen-mediated electronic states
exhibit a net spin polarization with significant magnetic remanence at room
temperature. The observed magnetism is restricted to the top 10 nm of
the irradiated sample where the actual magnetization reaches emu/g
at room temperature. We prove that the ferromagnetism found in metal-free
untreated graphite is intrinsic and has a similar origin as the one found in
proton bombarded graphite.Comment: 10 pages, 5 figures, 1 table, submitted to New Journal of Physic
X-ray edge singularity of bilayer graphene
The X-ray edge singularity of bilayer graphene is studied by generalizing the
path integral approach based on local action which was employed for monolayer
graphene. In sharp contrast to the case of monolayer graphene, the bilayer
graphene is found to exhibit the edge singularity even at half-filling and its
characteristics are determined by interlayer coupling. At finite bias the
singular behaviors sensitively depend on the relative magnitude of fermi energy
and applied bias, which is due to the peculiar shape of energy band at finite
bias.Comment: RevTeX 4.1, 4 pages. No figur
Intercalation of graphene on SiC(0001) via ion-implantation
Electronic devices based on graphene technology are catching on rapidly and
the ability to engineer graphene properties at the nanoscale is becoming, more
than ever, indispensable. Here, we present a new procedure of graphene
functionalization on SiC(0001) that paves the way towards the fabrication of
complex graphene electronic chips. The procedure resides on the well-known
ion-implantation technique. The efficiency of the working principle is
demonstrated by the intercalation of the epitaxial graphene layer on SiC(0001)
with Bi atoms, which was not possible following standard procedures. Our
results put forward the ion-beam lithography to nanostructure and functionalize
desired graphene chips
Magnetic phase diagram of the Hubbard model with next-nearest-neighbour hopping
We calculate the magnetic phase diagram of the Hubbard model for a Bethe
lattice with nearest neighbour (NN) hopping and next nearest neighbour
(NNN) hopping in the limit of infinite coordination. We use the amplitude
of the NNN hopping to tune the density of states (DOS) of the
non-interacting system from a situation with particle-hole symmetry to an
asymmetric one with van-Hove singularities at the lower ()
respectively upper () band edge for large enough . For
this strongly asymmetric situation we find rather extended parameter regions
with ferromagnetic states and regions with antiferromagnetic states.Comment: 13 pages, 7 figure
Visualization of gas-liquid mass transfer and wake structure of rising bubbles using pH-sensitive PLIF
A planar laser-induced fluorescence (PLIF) technique for visualizing gas–liquid mass transfer and wake structure of rising gas bubbles is described. The method uses an aqueous solution of the pH-sensitive dye Naphthofluorescein and CO2 as a tracer gas. It features a high spatial resolution and frame rates of up to 500 Hz, providing the ability to capture cinematographic image sequences. By steering the laser beam with a set of two programmable scanning mirrors, sequences of three-dimensional LIF images can be recorded. The technique is applied to freely rising bubbles with diameters between 0.5 and 5 mm, which perform rectilinear, oscillatory or irregular motions. The resulting PLIF image sequences reveal the evolution of characteristic patterns in the near and far wake of the bubbles and prove the potential of the technique to provide new and detailed insights into the spatio-temporal dynamics of mass transfer of rising gas bubbles. The image sequences further allow the estimation of bubble size and rise velocity. The analysis of bubble rise velocities in the Naphthofluorescein solution indicates that surfactant-contaminated conditions are encountered
The structure of the Au(111)/methylthiolate interface : new insights from near-edge X-ray absorption spectroscopy and X-ray standing waves
The local structure of the Au(111)([square root of]3×[square root of]3)R30°-methylthiolate surface phase has been investigated by S K-edge near-edge s-ray absorption fine structure (NEXAFS) both experimentally and theoretically and by experimental normal-incidence x-ray standing waves (NIXSW) at both the C and S atomic sites. NEXAFS shows not only excitation into the intramolecular sigma* S–C resonance but also into a sigma* S–Au orbital perpendicular to the surface, clearly identifying the local S headgroup site as atop a Au atom. Simulations show that it is not possible, however, to distinguish between the two possible adatom reconstruction models; a single thiolate species atop a hollow-site Au adatom or a dithiolate moiety comprising two thiolate species bonded to a bridge-bonded Au adatom. Within this dithiolate moiety a second sigma* S–Au orbital that lies near parallel to the surface has a higher energy that overlaps that of the sigma* S–C resonance. The new NIXSW data show the S–C bond to be tilted by 61° relative to the surface normal, with a preferred azimuthal orientation in , corresponding to the intermolecular nearest-neighbor directions. This azimuthal orientation is consistent with the thiolate being atop a hollow-site Au adatom, but not consistent with the originally proposed Au-adatom-dithiolate moiety. However, internal conformational changes within this species could, perhaps, render this model also consistent with the experimental data
Via-Less Microstrip to Rectangular Waveguide Transition on InP
Indium-Phosphide (InP) is one of the most common materials used for realizing active devices working in the millimeter frequency range. The isotropic etching profile of InP substrates limits the realization of passive devices, thus requiring an expensive and lossy hybrid platform. This paper presents a via-less, cost-effective and efficient solution for InP substrate. By using the proposed planar solution, it is demonstrated that rectangular waveguides can be realized on InP by fabricating a bed of nails structure which acts as a reflecting boundary for an impinging millimeter wave. As a proof of concept, a transition from microstrip to rectangular waveguide structure is realized within H-band (220-320 GHz) with a return loss of -18dB over a bandwidth of 30 GHz
Spatially resolved observation of uniform precession modes in spin-valve systems
Using time-resolved photoemission electron microscopy the excitation of
uniform precession modes in individual domains of a weakly coupled spin-valve
system has been studied. A coupling dependence of the precession frequencies
has been found that can be reasonably well understood on the basis of a
macrospin model. By tuning the frequency of the excitation source the uniform
precession modes are excited in a resonant way.Comment: This article has been accepted by Journal of Applied Physics. After
it is published, it will be found at http://jap.aip.or
Self-assembly and two-dimensional spontaneous resolution of cyano-functionalized [7]helicenes on Cu111
Birds of a feather flock together: STM and DFT studies provide the first example of spontaneous chiral resolution of a helicene on a surface. Racemic 6,13-dicyano[7]helicene forms fully segregated domains of pure enantiomers (2D conglomerate) on Cu(111). The propensity of the system to optimize intermolecular CNâ‹…â‹…â‹…HC(Ar) hydrogen bonding and CNâ‹…â‹…â‹…CN dipolar interactions translates into chiral recognition with preferential assembly of homochiral molecules
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