Detection of nonstationarity in hydrologic time series

[[abstract]]Detection of changes in hydrologic time series due to intervention by man or natural causes is an important problem. Although intervention analysis has been used in the recent past to analyze nonstationary hydrologic time series, the necessity to specify a model of change and an initial time at which the time series has started to change are obvious disadvantages of intervention analysis. An alternative to intervention analysis is a method which is based on spectral characteristics and an exponential moving average model. The basic objective of the research discussed in the present paper is to test this alternative method. The model is tested by using synthetic uncorrelated and correlated data with step and gradual changes as well as by using real hydrologic time series. The sensitivity of the model to different parameters is also explored. The alternative model is found to be quite accurate in detecting changes in hydrologic time series

Computational analysis of viscous dissipation and joule-heating effects on non-Darcy MHD natural convection flow from a horizontal cylinder in porous media with internal heat generation

In the present paper we examine the effects of viscous dissipation, Joule heating and heat source/sink on non-Darcy MHD natural convection heat transfer flow over permeable horizontal circular cylinder in a porous medium. The boundary layer equations, which are parabolic in nature, are normalized into non-similar form and then solved numerically with the well-tested, efficient, implicit, stable Keller-box finite difference scheme. A parametric study illustrating the influence of Darcy parameter (Da), Forchheimer parameter (Λ), Grashof number(Gr), heat source/sink parameter (Ω) and viscous dissipation parameter (Ec) on the fluid velocity, temperature as well as local skin-friction and Nusselt numbers is conducted Increasing Forchheimer inertial drag parameter (Λ) retards the flow considerably but enhances temperatures. Increasing viscous dissipation parameter(Ec) is found to elevate velocities i.e. accelerate the flow and increase temperatures. Increasing heat source/sink parameter (Ω) is found to elevate velocities and increase temperatures. Increasing the Grashof number (Gr) is found to elevate the velocity and decrease the temperatures. Local skin friction number is found to be increases with increasing heat source/sink parameter (Ω) where as Local Nusselt number is found to decrease with increasing heat source/sink parameter (Ω)

Magnetostructural and magnetocaloric properties of bulk LaCrO3 system

We studied the magnetic properties of bulk LaCrO3; a GdFeO3-type distorted perovskite, with a predominant antiferromagnetic phase transition at ~ 290 K. The bulk LaCrO3 exhibits intrinsic weak ferromagnetism at room temperature, which may arise due to the tilting of CrO6 octahedra, resulting in a non-zero net magnetic moment, as confirmed from the magnetization measurements. A broad magnetically-induced entropy change (-{\Delta}S) is observed with the maximum at 290 K, close to room temperature in LaCrO3 system.Comment: 13 Pages and 3 Figures Submitted to the Journal Physics Letter A on 15 March 201

Surfactant-Assisted Synthesis of Semiconductor Nanotubes and Nanowires

Nanotubes and nanowires of CdSe and CdS have been obtained from solutions containing a surfactant such as Triton 100-X. They have been characterized by x-ray diffraction, electron microscopy, and optical spectroscopy

Magnetism and field-induced effect in a spin-orbit entangled Jeff = 1/2 honeycomb lattice

The interplay between spin-orbit coupling, frustration-induced anisotropic magnetic interaction, and spin correlations can lead to novel states with exotic excitations in rare-earth-based quantum magnets. Herein, we present the crystal structure, magnetization, electron spin resonance (ESR), specific heat, and nuclear magnetic resonance (NMR) experiments on the polycrystalline samples of Ba9Yb2Si6O24 in which Yb3+ ions form a perfect honeycomb lattice without detectable anti-site disorder. Magnetization data reveal antiferromagnetically coupled spin-orbit entangled Jeff = 1/2 degrees of freedom of Yb3+ ions in the Kramers doublet state where the Curie-Weiss temperature is - 2.97 K, as obtained from the low-temperature magnetic susceptibility data. The ESR measurements reveal that the first excited Kramers doublet is 32.3(7) meV above the ground state. The specific heat results suggest the presence of an antiferromagnetic phase transition at 2.26 K. The long-range antiferromagnetic order is completely suppressed upon the application of magnetic field and a field-induced disordered state is observed in an applied magnetic field of 2.5 T, which is also confirmed by NMR measurements. Furthermore, the NMR spin-lattice relaxation rate reveals the presence of a field-induced gap that is attributed to the Zeeman splitting of Kramers doublet state in this quantum material. Our experiments suggest the presence of a phase transition and short-range spin correlations appearing well above the antiferromagnetic phase transition temperature and a field-induced disordered state in this spin-orbit entangled Jeff =1/2 rare-earth magnet on a honeycomb lattice

High-pressure behavior of superconducting boron-doped diamond

This work investigates the high-pressure structure of freestanding superconducting ($T_{c}$ = 4.3\,K) boron doped diamond (BDD) and how it affects the electronic and vibrational properties using Raman spectroscopy and x-ray diffraction in the 0-30\,GPa range. High-pressure Raman scattering experiments revealed an abrupt change in the linear pressure coefficients and the grain boundary components undergo an irreversible phase change at 14\,GPa. We show that the blue shift in the pressure-dependent vibrational modes correlates with the negative pressure coefficient of $T_{c}$ in BDD. The analysis of x-ray diffraction data determines the equation of state of the BDD film, revealing a high bulk modulus of $B_{0}$=510$\pm$28\,GPa. The comparative analysis of high-pressure data clarified that the sp$^{2}$ carbons in the grain boundaries transform into hexagonal diamond.Comment: 7 pages, 4 figure

容量スケーリング法を用いた容量制約をもつ多品種フローネットワークデザイン問題の近似解法

In this study, transmission electron microscopy (TEM) was used to evaluate the effect of controlled forging followed by cooling at various rates on microstructure of an HSLA-80 steel. The observations demonstrate that water-quenched steel has finer multiphase constituents of lath martensite, bainite and twined martensite, whereas air-cooling has resulted in a mixture of bainitic ferrite, retained austenite or MA constituents along with some Widmanstatten ferrite. When the steel is cooled in sand, the maximum volume fraction of polygonal ferrite (PF) was produced which, in turn, increased volume fraction of MA constituents. Precipitation of fine ε-Cu, Nb and Ti carbides and carbonitrides was observed and identified using energy dispersive spectrometric analysis (EDS) and electron diffraction

Single-Walled Carbon Nanotube Bundles Intercalated with Semiconductor Nanoparticles

Nanoparticles of CdSe, CdS and ZnSe have been incorporated in the inter-tubular gaps of single-walled carbon nanotube (SWNT) bundles. Electron microscope, X-ray diffraction (XRD), electronic spectroscopy and Raman studies have been employed to characterize these systems. The lengths of the intercalate inside the bundles could be varied by changing the reaction conditions. Electronic absorption and photoluminescence studies from the semiconductor intercalates show the expected blue-shift with respect to the corresponding bulk samples in CdS and ZnS samples. The SWNT lattice is expanded on incorporating CdSe as confirmed by XRD in the low-angle range. The expansion in the lattice is also corroborated by the Raman measurements which show a considerable red-shift for both the radial and the tangential modes of the SWNT signal, thus signifying an increase in the van der Waals gap between the tubes in the bundle. The red-shift of the Raman signal is due to the decrease in the inter-tube interactions as well as due to doping effects

Growth and reproductive parameters of bonnet monkey (Macaca radiata)

The present paper summarizes some of the important biological and physiological data recorded over a 30-year period on the biology of bonnet monkeys in captivity. Data on sexual maturity, menstrual cyclicity, general behaviour, endocrine profile, reproductive physiology, gestation, parturition, postpartum amenorrhoea in the female, and sexual maturity, hormone profile, and seasonal variation in sperm count of the male monkeys are presented. In addition to the biological values, weights of selected organs, vertebral and dental pattern are also presented. Menarche occurred at an age of 36±4 months and the first conception in the colony occurred at an age of 54±4 months. The average menstrual cycle length was 28±4.3 days. Majority of monkeys did not cycle regularly during March-June during which the temperature reached a peak. The pregnancy index of the colony was 80% with controlled breeding. The gestation period was 166±5 days with 6-7 months postpartum amenorrhoea. Males attained sexual maturity by the age of 6-7 years and exhibited the characteristic nocturnal surge of serum testosterone at this age and sperm concentration ranged from 116-799 millions/ejaculate

Effect of chronic administration of 7α-methyl-19-nortestosterone on serum testosterone, number of spermatozoa and fertility in adult male bonnet monkeys (Macaca radiata)

Hormonal approaches to male contraception that are based on the suppression of LH secretion require androgen replacement treatment to maintain sexual behaviour and secondary sexual characteristics. Androgen supplementation not only involves large and frequent doses of testosterone esters but also results in undesirable effects on the prostate gland. In an attempt to avoid such problems, a synthetic androgen, 7α-methyl-19-nortestosterone (MENT), which is much more potent than testosterone, has been developed. In the present study, MENT was administered at different doses (25, 50, 100, 300 and 1000 μg day−1 either alone or in combination with oestradiol via Silastic implants for a specified period to adult male bonnet monkeys (Macaca radiata). Blood and semen samples were collected at specific intervals and analysed for serum testosterone and seminal parameters, respectively. The results of the present study clearly indicate that administration of MENT at all doses tested results in suppression of the nocturnal surge of testosterone (by day 3), as well as a decrease in the number of spermatozoa (by day 45). Co-administration of oestradiol resulted in a reduction in the dose of MENT required to suppress the nocturnal surge. None of the male bonnet monkeys treated with MENT were able to impregnate females, clearly demonstrating the efficacy of MENT in blocking fertility in male bonnet monkeys