4,242 research outputs found
University Library Development in Indiana, 1910 to 1966
published or submitted for publicatio
Two-electron bond-orbital model, 2
The two-electron bond-orbital model of tetrahedrally-coordinated solids is generalized and its application extended. All intrabond matrix elements entering the formalism are explicitly retained, including the direct overlap S between the anion and cation sp3 hybrid wavefunctions. Complete analytic results are obtained for the six two-electron eigenvalues and eigenstates of the anion-cation bond in terms of S, one-electron parameters V2 and V3, and two-electron correlation parameters V4, V5 and V6. Refined formulas for the dielectric constant and the nuclear exchange and pseudodipolar coefficients, as well as new expressions for the valence electron density, polarity of the bond and the cohesive energy, are then derived. The theory gives a good account of the experimentally observed trends in all properties considered and approximate quantitative agreement is achieved for the pseudodipolar coefficient
Margins within margins?: voices Speaking through a study of the provision of an educational program for the children of one Australian show circuit
This paper examines the tactics used by the Showmen's Guild of Australasia in successfully lobbying for the development of a distance education program for their children. The Guild is considered to be a 'marginalized' group, meaning members have less access to wealth, power, and status. Since 1930, members of the Showmen's Guild and their families have traveled from town to town providing agricultural and equestrian shows. Despite the diversity of backgrounds and experiences among people connected with the show circuit, the Guild is highly organized and has been politically active. Informal sanctions have been effective in enforcing group discipline and in presenting the image of a single body of opinion. In addition, investment in sophisticated machinery and technology has resulted in show people having the financial resources to buy homes and have a political voice via more 'normalized channels'. Although members learn early that they are a marginalized group and are perceived as different from the mainstream, the group maintains close ties and often celebrates its difference. Implications for educational program development center on the goals of educational programs designed for disadvantaged groups, and the status of other marginalized groups and their efforts to contest their marginalized status. (LP
Transition-metal interactions in aluminum-rich intermetallics
The extension of the first-principles generalized pseudopotential theory
(GPT) to transition-metal (TM) aluminides produces pair and many-body
interactions that allow efficient calculations of total energies. In
aluminum-rich systems treated at the pair-potential level, one practical
limitation is a transition-metal over-binding that creates an unrealistic TM-TM
attraction at short separations in the absence of balancing many-body
contributions. Even with this limitation, the GPT pair potentials have been
used effectively in total-energy calculations for Al-TM systems with TM atoms
at separations greater than 4 AA. An additional potential term may be added for
systems with shorter TM atom separations, formally folding repulsive
contributions of the three- and higher-body interactions into the pair
potentials, resulting in structure-dependent TM-TM potentials. Towards this
end, we have performed numerical ab-initio total-energy calculations using VASP
(Vienna Ab Initio Simulation Package) for an Al-Co-Ni compound in a particular
quasicrystalline approximant structure. The results allow us to fit a
short-ranged, many-body correction of the form a(r_0/r)^{b} to the GPT pair
potentials for Co-Co, Co-Ni, and Ni-Ni interactions.Comment: 18 pages, 5 figures, submitted to PR
Evolutionary Algorithms for Reinforcement Learning
There are two distinct approaches to solving reinforcement learning problems,
namely, searching in value function space and searching in policy space.
Temporal difference methods and evolutionary algorithms are well-known examples
of these approaches. Kaelbling, Littman and Moore recently provided an
informative survey of temporal difference methods. This article focuses on the
application of evolutionary algorithms to the reinforcement learning problem,
emphasizing alternative policy representations, credit assignment methods, and
problem-specific genetic operators. Strengths and weaknesses of the
evolutionary approach to reinforcement learning are presented, along with a
survey of representative applications
Two-electron bond-orbital model, 1
Harrison's one-electron bond-orbital model of tetrahedrally coordinated solids was generalized to a two-electron model, using an extension of the method of Falicov and Harris for treating the hydrogen molecule. The six eigenvalues and eigenstates of the two-electron anion-cation Hamiltonian entering this theory can be found exactly general. The two-electron formalism is shown to provide a useful basis for calculating both non-magnetic and magnetic properties of semiconductors in perturbation theory. As an example of the former, expressions for the electric susceptibility and the dielectric constant were calculated. As an example of the latter, new expressions for the nuclear exchanges and pseudo-dipolar coefficients were calculated. A simple theoretical relationship between the dielectric constant and the exchange coefficient was also found in the limit of no correlation. These expressions were quantitatively evaluated in the limit of no correlation for twenty semiconductors
Local Volume Effects in the Generalized Pseudopotential Theory
The generalized pseudopotential theory (GPT) is a powerful method for
deriving real-space transferable interatomic potentials. Using a coarse-grained
electronic structure, one can explicitly calculate the pair ion-ion and
multi-ion interactions in simple and transition metals. Whilst successful in
determining bulk properties, in central force metals the GPT fails to describe
crystal defects for which there is a significant local volume change. A
previous paper [PhysRevLett.66.3036 (1991)] found that by allowing the GPT
total energy to depend upon some spatially-averaged local electron density, the
energetics of vacancies and surfaces could be calculated within experimental
ranges. In this paper, we develop the formalism further by explicitly
calculating the forces and stress tensor associated with this total energy. We
call this scheme the adaptive GPT (aGPT) and it is capable of both molecular
dynamics and molecular statics. We apply the aGPT to vacancy formation and
divacancy binding in hcp Mg and also calculate the local electron density
corrections to the bulk elastic constants and phonon dispersion for which there
is refinement over the baseline GPT treatment.Comment: 11 pages, 6 figure
Recommended from our members
Inclusive pedagogy for diverse learners : science instruction, disability, and the community college.
The following study examined the use of inclusive pedagogy by science, technology, engineering, and mathematics (STEM) faculty at three community colleges. The study was developed in response to a gap in existing knowledge about inclusive instruction in two-year colleges. The purpose was to identify barriers to the adoption of inclusive teaching methods for diverse learners and students with disabilities, and to propose ways to break down these barriers. Three research questions designed for the study asked about (a) the current teaching styles and methods of curriculum delivery used by community college STEM faculty, (b) the levels of awareness and knowledge of community college STEM faculty about inclusive teaching practices, and (c) the personal, attitudinal, and environmental factors that inhibit community college STEM faculty from using inclusive pedagogical practices to better serve students with disabilities and other diverse students. A sequential method was used to obtain both quantitative and qualitative data regarding instructional practices, pedagogical knowledge, and beliefs about teaching and learning. Two hundred and eleven STEM faculty members responded to a questionnaire that was administered electronically and 11 faculty members were interviewed, 9 of whom were observed in the classroom. Findings revealed that a significant number of these community college faculty members have an inclusive mindset and believe in adapting their instruction in order to accommodate learner differences. These faculty members also appear more knowledgeable about pedagogical practices than what has been reported in previous literature about four-year faculty. Many of the faculty members are using multimodal instructional methods. However, a significant gap still exists between what they believe and know and what is actually put into instructional practice. A number of barriers that prohibit the use and development of inclusive practices were identified in this study. The most significant among the barriers reported were the lack of an inclusive mindset, lack of knowledge about pedagogy, high teaching loads, and lack of time for instructional development. Implications for practice, policy, and research are discussed
The influence of authentic scientific research experiences on teachers' conceptions of the nature of science (NOS) and their NOS teaching practices
Thesis (Ed.D.)--Boston UniversityThis study explored the influence of teachers' authentic scientific research experiences (ASREs) on teachers' conceptions of the nature ofscience (NOS) and teachers' NOS instruction. Twelve high school biology teachers participated in this study. Six of the participants had authentic scientific research experience (ASRE) and six had not participated in authentic scientific research. Data included background surveys, modified Views of the Nature of Science (VNOS) questionnaires, interviews, and teaching observations. Data was coded based on the eight NOS understandings outlined in 2013 in the Next Generation Science Standards (NGSS). Evidence from this study indicates participating in authentic scientific research as a member of a scientific community has dual benefits of enabling high school science teachers with informed understandings of the NOS and positioning them to teach with the NOS. However, these benefits do not always result from an ASRE. If the nature of the ASRE is limited, then it may limit teachers' NOS understandings and their NOS teaching practices. The results of this study suggest that participation in ASREs may be one way to improve teachers' NOS understandings and teaching practices if the experiences themselves offer a comprehensive view of the NOS. Because ASREs and other science learning experiences do not always offer such experiences, pre-service teacher education and professional development opportunities may engage science teachers in two ways: (1) becoming part of a scientific community may enable them to teach with NOS and (2) being reflective about what being a scientist means may improve teachers' NOS understandings and better position them to teach about NOS
Silicon superlattices: Theory and application to semiconductor devices
Silicon superlattices and their applicability to improved semiconductor devices were studied. The device application potential of the atomic like dimension of III-V semiconductor superlattices fabricated in the form of ultrathin periodically layered heterostructures was examined. Whether this leads to quantum size effects and creates the possibility to alter familiar transport and optical properties over broad physical ranges was studied. Applications to improved semiconductor lasers and electrondevices were achieved. Possible application of silicon sperlattices to faster high speed computing devices was examined. It was found that the silicon lattices show features of smaller fundamental energyband gaps and reduced effective masses. The effects correlate strongly with both the chemical and geometrical nature of the superlattice
- …