2,944 research outputs found
Modelling of thermo-chemical properties over the sub-solidus MgO–FeO binary, as a function of iron spin configuration, composition and temperature
Thermo-chemical properties and T–X phase relations diagram of the (Mg,Fe)O solid solution are modelled using mixing Helmholtz energy, ΔF(T,x)mixing, calculated by quantum mechanical and semi-empirical techniques. The sub-solidus MgO–FeO binary has been explored as a function of composition, with iron either in high-spin (HS) or low-spin (LS) configuration. Only the HS model provides physically sound results at room pressure, yielding a correct trend of cell edge versus composition, whereas LS’s issues are at variance with observations. Mixing Helmholtz energy has been parametrized by the following relationship: ΔF(T,x)mixing = x × y × [U0(T) + U1(T) × (x – y) + U2(T) × (x − y)2]−T × S(x,y)config, where y = 1−x and Uj(T) are polynomials in T of the second order. ΔF(T,x)mixing exhibits a quasi-symmetric behaviour and allows one to build the T–X phase relations diagram over the MgO–FeO join. The HS model including vibrational contribution to the Helmholtz energy predicts a solid solution’s critical temperature of some 950 K, remarkably larger than olivine’s and Mg–Fe garnet’s. All this points to a more difficult Mg–Fe mixing in periclase-like structure than olivine and garnet, which, in turn, provide more structure degrees of freedom for atomic relaxation. From ΔF(T,x)mixing, we have then derived ΔH(T,x)excess and ΔS(T,x)excess. The former, characterized by a quasi-regular behaviour, has been parametrized through W × x × (1−x), obtaining WH,Mg–Fe of 17.7(5) kJ/mol. ΔS(T,x)excess, in turn, increases as a function of temperature, showing absolute figures confined within 0.1 J/mol/K. Mixing Gibbs energy, calculated combining the present issues with earlier theoretical determinations of the magnesio-wüstite’s elastic properties, has shown that the HS configuration is stable and promote Mg–Fe solid solution up to ≈15 GPa
Electromagnetic dipole moments of charged baryons with bent crystals at the LHC
We propose a unique program of measurements of electric and magnetic dipole
moments of charm, beauty and strange charged baryons at the LHC, based on the
phenomenon of spin precession of channeled particles in bent crystals. Studies
of crystal channeling and spin precession of positively- and negatively-charged
particles are presented, along with feasibility studies and expected
sensitivities for the proposed experiment using a layout based on the LHCb
detector.Comment: 19 pages, 13 figure
Efficient Passive ICS Device Discovery and Identification by MAC Address Correlation
Owing to a growing number of attacks, the assessment of Industrial Control
Systems (ICSs) has gained in importance. An integral part of an assessment is
the creation of a detailed inventory of all connected devices, enabling
vulnerability evaluations. For this purpose, scans of networks are crucial.
Active scanning, which generates irregular traffic, is a method to get an
overview of connected and active devices. Since such additional traffic may
lead to an unexpected behavior of devices, active scanning methods should be
avoided in critical infrastructure networks. In such cases, passive network
monitoring offers an alternative, which is often used in conjunction with
complex deep-packet inspection techniques. There are very few publications on
lightweight passive scanning methodologies for industrial networks. In this
paper, we propose a lightweight passive network monitoring technique using an
efficient Media Access Control (MAC) address-based identification of industrial
devices. Based on an incomplete set of known MAC address to device
associations, the presented method can guess correct device and vendor
information. Proving the feasibility of the method, an implementation is also
introduced and evaluated regarding its efficiency. The feasibility of
predicting a specific device/vendor combination is demonstrated by having
similar devices in the database. In our ICS testbed, we reached a host
discovery rate of 100% at an identification rate of more than 66%,
outperforming the results of existing tools.Comment: http://dx.doi.org/10.14236/ewic/ICS2018.
Search for new physics via baryon EDM at LHC
Permanent electric dipole moments (EDMs) of fundamental particles provide
powerful probes for physics beyond the Standard Model. We propose to search for
the EDM of strange and charm baryons at LHC, extending the ongoing experimental
program on the neutron, muon, atoms, molecules and light nuclei. The EDM of
strange baryons, selected from weak decays of charm baryons produced
in pp collisions at LHC, can be determined by studying the spin precession in
the magnetic field of the detector tracking system. A test of CPT symmetry can
be performed by measuring the magnetic dipole moment of and
baryons. For short-lived and
baryons, to be produced in a fixed-target experiment using the 7 TeV LHC beam
and channeled in a bent crystal, the spin precession is induced by the intense
electromagnetic field between crystal atomic planes. The experimental layout
based on the LHCb detector and the expected sensitivities in the coming years
are discussed.Comment: Proceeding of Lepton Photon Interactions at High Energies (2017
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