Species sensitivity of zeolite minerals for uptake of mercury solutes

The uptake of inorganic Hg2+ and organometallic CH3Hg+ from aqueous solutions by 11 different natural zeolites has been investigated using a batch distribution coefficient (Kd) method and supported by a preliminary voltammetric study. The effect of mercury concentration on theKd response is shown over an environmentally appropriate concentration range of 0.1-5 ppm inorganic and organometallic Hg using a batch factor of 100 ml g−1 and 20 h equilibration. Analcime and a Na-chabazite displayed the greatest methylmercury uptakes (Kd values at 1.5 ppm of 4023 and 3456, respectively), with mordenite as the smallest at 578. All uptake responses were greater for methylmercury than for the inorganic mercuric nitrate solutions, suggesting a distinctive sensitivity of zeolites to reaction with different types of solute species. It is likely that this sensitivity is attributable to the precise nature of the resultant Hg-zeolite bonds. Additionally, both the Si-Al ratio and the Na content of the initial natural zeolite samples are shown to influence the Kd responses, with positive correlations between Kd and Na content for all zeolites excluding mordenite

The bispectrum of matter perturbations from cosmic strings

We present the first calculation of the bispectrum of the matter perturbations induced by cosmic strings. The calculation is performed in two different ways: the first uses the unequal time correlators (UETCs) of the string network - computed using a Gaussian model previously employed for cosmic string power spectra. The second approach uses the wake model, where string density perturbations are concentrated in sheet-like structures whose surface density grows with time. The qualitative and quantitative agreement of the two gives confidence to the results. An essential ingredient in the UETC approach is the inclusion of compensation factors in the integration with the Green's function of the matter and radiation fluids, and we show that these compensation factors must be included in the wake model also. We also present a comparison of the UETCs computed in the Gaussian model, and those computed in the unconnected segment model (USM) used by the standard cosmic string perturbation package CMBACT. We compare numerical estimates for the bispectrum of cosmic strings to those produced by perturbations from an inflationary era, and discover that, despite the intrinsically non-Gaussian nature of string-induced perturbations, the matter bispectrum is unlikely to produce competitive constraints on a population of cosmic strings

CMB lensing and primordial squeezed non-Gaussianity

Squeezed primordial non-Gaussianity can strongly constrain early-universe physics, but it can only be observed on the CMB after it has been gravitationally lensed. We give a new simple non-perturbative prescription for accurately calculating the effect of lensing on any squeezed primordial bispectrum shape, and test it with simulations. We give the generalization to polarization bispectra, and discuss the effect of lensing on the trispectrum. We explain why neglecting the lensing smoothing effect does not significantly bias estimators of local primordial non-Gaussianity, even though the change in shape can be >~10%. We also show how tau_NL trispectrum estimators can be well approximated by much simpler CMB temperature modulation estimators, and hence that there is potentially a ~10-30% bias due to very large-scale lensing modes, depending on the range of modulation scales included. Including dipole sky modulations can halve the tau_NL error bar if kinematic effects can be subtracted using known properties of the CMB temperature dipole. Lensing effects on the g_NL trispectrum are small compared to the error bar. In appendices we give the general result for lensing of any primordial bispectrum, and show how any full-sky squeezed bispectrum can be decomposed into orthogonal modes of distinct angular dependence.Comment: 22 pages, 6 figures; minor edits to match published versio

Thermophysiological comfort analysis of aerogel nanoparticle incorporated fabric for fire fighter's protective clothing

The paper discusses the thermophysiological comfort of a newly developed fabric potentially for firefighter's protective clothing. The fabrics were developed by incorporating super hydrophobic silica aerogel nanoparticles in 65/35 wool-Aramid blended fabric. Then the theromophysiological comfort was analyzed by determining air, moisture and heat transfer performance. It has been found that only 2% coating of aerogel nanoparticle increases thermal resistance by up to 68.64% and can reduce air permeability by up to 45.46% whereas 4% aerogel coating can reduce 61.76% air permeability. Moisture management properties of the aerogel coated fabric have also been investigated and discussed in details. In brief, it can be said that the thickener that was used for the coating, has a positive impact on moisture transportation and overall moisture management property of the fabric. Again aerogel coated next-to-skin layer and aerogel coated outer layer acted differently on the same fabric. It was observed that, the coated fabric acts as more likely as a moisture management fabric when the coating was applied on next-to-skin surface

Oscillations in the bispectrum

There exist several models of inflation that produce primordial bispectra that contain a large number of oscillations. In this paper we discuss these models, and aim at finding a method of detecting such bispectra in the data. We explain how the recently proposed method of mode expansion of bispectra might be able to reconstruct these spectra from separable basis functions. Extracting these basis functions from the data might then lead to observational constraints on these models.Comment: 6 pages, 2 figures, submitted to JOP: Conference Series, PASCOS 201

Performance of Compression Garments for Cyclists

Base layer compression garments had been used by professional cyclists to enhance their performance. To date there is significant body of evidence relating to compression modalities in treating patients suffering from leg ulcers. However, research relating to sportswear compression garment is varied and inconclusive, a few research suggested benefit to athletes or aid recovery from exercise. This depends on a number of factors such as material (fabric/garment design, interaction), athlete (body shape, intensity of use, fitness, and perception) and type of sport or use (intensive or casual). The current research intends to establish a knowledge base by exploring the performance of garments using a combination of laboratory investigations and wearer perceptions. Four commercially available compression garments were evaluated for its performance. These include two professional brands (SKINS, RAPHA) and retail brands (Sub-dual and Sports Direct Muddyfox). The pressure profile of these garments was investigated on participants using Tekscan pressure sensors on various points (lower limb). Wearer trial investigated their perceptions for its fit, comfort, ease of wear, tactile sensation, and overall satisfaction. Various textile parameters evaluating garment durability, comfort, colourfastness and stability facilitated in determining its efficacy. In addition, wearer trials were conducted to measure physiological measurements. Overall, professional compression garments performed better compared to standard products. Suitable inferences drawn from these preliminary findings enabled to ascertain the performance of compression garments and aid in further development

The characteristics of sexual abuse in sport: A multidimensional scaling analysis of events described in media reports

Most research on sexual abuse has been conducted within family settings (Fergusson & Mullen, 1999). In recent years, following several high profile convictions and scandals, research into sexual abuse has also encompassed institutional and community settings such as sport and the church (Gallagher, 2000; Wolfe et al., 2003). Research into sexual abuse in sport, for example, began with both prevalence studies (Kirby & Greaves, 1996; Leahy, Pretty & Tenenbaum, 2002) and qualitative analyses of the processes and experiences of athlete sexual abuse (Brackenridge, 1997; Cense & Brackenridge, 2001, Toftegaard Nielsen, 2001). From such work, descriptions of the modus operandi of abusers in sport, and the experiences and consequences for athlete victims, have been provided, informing both abuse prevention work and coach education. To date, however, no study has provided empirical support for multiple associations or identified patterns of sex offending in sport in ways that might allow comparisons with research-generated models of offending outside sport. This paper reports on an analysis of 159 cases of criminally defined sexual abuse, reported in the print media over a period of 15 years. The main aim of the study was to identify the nature of sex offending in sport focusing on the methods and locations of offences. The data were analysed using multidimensional scaling (MDS), as a data reduction method, in order to identify the underlying themes within the abuse and explore the inter-relationships of behaviour, victim and context variables. The findings indicate that there are specific themes that can be identified within the perpetrator strategies that include ‘intimate’, ‘aggressive’, and ‘’dominant’ modes of interaction. The same patterns that are described here within the specific context of sport are consistent with themes that emerge from similar behavioural analyses of rapists (Canter & Heritage, 1990; Bishopp, 2003) and child molester groups (Canter, Hughes & Kirby, 1998). These patterns show a correspondence to a broader behavioural model – the interpersonal circumplex (e.g., Leary 1957). Implications for accreditation and continuing professional education of sport psychologists are noted

Non-Gaussianity in the Cosmic Microwave Background Anisotropies at Recombination in the Squeezed limit

We estimate analytically the second-order cosmic microwave background temperature anisotropies at the recombination epoch in the squeezed limit and we deduce the contamination to the primordial local non-Gaussianity. We find that the level of contamination corresponds to f_NL^{con}=O(1) which is below the sensitivity of present experiments and smaller than the value O(5) recently claimed in the literature.Comment: LaTeX file; 15 pages. Slightly revised version. Main result unchange

Effects and Detectability of Quasi-Single Field Inflation in the Large-Scale Structure and Cosmic Microwave Background

Quasi-single field inflation predicts a peculiar momentum dependence in the squeezed limit of the primordial bispectrum which smoothly interpolates between the local and equilateral models. This dependence is directly related to the mass of the isocurvatons in the theory which is determined by the supersymmetry. Therefore, in the event of detection of a non-zero primordial bispectrum, additional constraints on the parameter controlling the momentum-dependence in the squeezed limit becomes an important question. We explore the effects of these non-Gaussian initial conditions on large-scale structure and the cosmic microwave background, with particular attention to the galaxy power spectrum at large scales and scale-dependence corrections to galaxy bias. We determine the simultaneous constraints on the two parameters describing the QSF bispectrum that we can expect from upcoming large-scale structure and cosmic microwave background observations. We find that for relatively large values of the non-Gaussian amplitude parameters, but still well within current uncertainties, galaxy power spectrum measurements will be able to distinguish the QSF scenario from the predictions of the local model. A CMB likelihood analysis, as well as Fisher matrix analysis, shows that there is also a range of parameter values for which Planck data may be able distinguish between QSF models and the related local and equilateral shapes. Given the different observational weightings of the CMB and LSS results, degeneracies can be significantly reduced in a joint analysis.Comment: 27 pages, 14 figure

Optimal bispectrum constraints on single-field models of inflation

We use WMAP 9-year bispectrum data to constrain the free parameters of an 'effective field theory' describing fluctuations in single-field inflation. The Lagrangian of the theory contains a finite number of operators associated with unknown mass scales. Each operator produces a fixed bispectrum shape, which we decompose into partial waves in order to construct a likelihood function. Based on this likelihood we are able to constrain four linearly independent combinations of the mass scales. As an example of our framework we specialize our results to the case of 'Dirac-Born-Infeld' and 'ghost' inflation and obtain the posterior probability for each model, which in Bayesian schemes is a useful tool for model comparison. Our results suggest that DBI-like models with two or more free parameters are disfavoured by the data by comparison with single parameter models in the same class