1,694 research outputs found
Elastic response of filamentous networks with compliant crosslinks
Experiments have shown that elasticity of disordered filamentous networks
with compliant crosslinks is very different from networks with rigid
crosslinks. Here, we model and analyze filamentous networks as a collection of
randomly oriented rigid filaments connected to each other by flexible
crosslinks that are modeled as worm-like chains. For relatively large
extensions we allow for enthalpic stretching of crosslinks' backbones. We show
that for sufficiently high crosslink density, the network linear elastic
response is affine on the scale of the filaments' length. The nonlinear regime
can become highly nonaffine and is characterized by a divergence of the elastic
modulus at finite strain. In contrast to the prior predictions, we do not find
an asymptotic regime in which the differential elastic modulus scales linearly
with the stress, although an approximate linear dependence can be seen in a
transition from entropic to enthalpic regimes. We discuss our results in light
of the recent experiments.Comment: 10 pages, 11 figure
Electronic structure and magnetism in the frustrated antiferromagnet LiCrO2
LiCrO2 is a 2D triangular antiferromagnet, isostructural with the common
battery material LiCoO2 and a well-known Jahn-Teller antiferromagnet NaNiO2. As
opposed to the latter, LiCrO2 exibits antiferromagnetic exchange in Cr planes,
which has been ascribed to direct Cr-Cr d-d overlap. Using LDA and LDA+U first
principles calculations I confirm this conjecture and show that (a) direct d-d
overlap is indeed enhanced compared to isostructural Ni and Cr compounds, (b)
p-d charge transfer gap is also enhanced, thus suppressing the ferromagnetic
superexchange, (c) the calculated magnetic Hamiltonian maps well onto the
nearest neighbors Heisenberg exchange model and (d) interplanar inteaction is
antiferromagnetic.Comment: 5 pages, 4 figure
Multi-scale strain-stiffening of semiflexible bundle networks
Bundles of polymer filaments are responsible for the rich and unique
mechanical behaviors of many biomaterials, including cells and extracellular
matrices. In fibrin biopolymers, whose nonlinear elastic properties are crucial
for normal blood clotting, protofibrils self-assemble and bundle to form
networks of semiflexible fibers. Here we show that the extraordinary
strain-stiffening response of fibrin networks is a direct reflection of the
hierarchical architecture of the fibrin fibers. We measure the rheology of
networks of unbundled protofibrils and find excellent agreement with an affine
model of extensible wormlike polymers. By direct comparison with these data, we
show that physiological fibrin networks composed of thick fibers can be modeled
as networks of tight protofibril bundles. We demonstrate that the tightness of
coupling between protofibrils in the fibers can be tuned by the degree of
enzymatic intermolecular crosslinking by the coagulation Factor XIII.
Furthermore, at high stress, the protofibrils contribute independently to the
network elasticity, which may reflect a decoupling of the tight bundle
structure. The hierarchical architecture of fibrin fibers can thus account for
the nonlinearity and enormous elastic resilience characteristic of blood clots.Comment: 27 pages including 8 figures and Supplementary Dat
Influence of single-neutron stripping on near-barrier <sup>6</sup>He+<sup>208</sup>Pb and <sup>8</sup>He+<sup>208</sup>Pb elastic scattering
The influence of single-neutron stripping on the near-barrier elastic scattering angular distributions for the 6,8He+208Pb systems is investigated through coupled reaction channels (CRC) calculations fitting recently published data to explore the differences in the absorptive potential found in the scattering of these two neutron-rich nuclei. The inclusion of the coupling reduces the elastic cross section in the Coulomb-nuclear interference region for 8He scattering, whereas for 6He its major impact is on the large-angle elastic scattering. The real and imaginary dynamic polarization potentials are obtained by inverting the CRC elastic scattering S-matrix elements. These show that the main absorptive features occur between 11 and 12 fm for both projectiles, while the attractive features are separated by about 1 fm, with their main structures occurring at 10.5 fm for 6He and 11.5 fm for 8He
Raw and Count Data Comparability of Hip-Worn ActiGraph GT3X+ and Link Accelerometers
To enable inter- and intrastudy comparisons it is important to ascertain comparability among accelerometer models.
Purpose: The purpose of this study was to compare raw and count data between hip-worn ActiGraph GT3X+ and GT9X Link accelerometers.
Methods: Adults (n = 26 (n = 15 women); age, 49.1 T 20.0 yr) wore GT3X+ and Link accelerometers over the right hip for an 80-min protocol involving 12–21 sedentary, household, and ambulatory/exercise activities lasting 2–15 min each. For each accelerometer, mean and variance of the raw (60 Hz) data for each axis and vector magnitude (VM) were extracted in 30-s epochs. A machine learning model (Montoye 2015) was used to predict energy expenditure in METs from the raw data. Raw data were also processed into activity counts in 30-s epochs for each axis and VM, with Freedson 1998 and 2011 count-based regression models used to predictMETs. Time spent in sedentary, light, moderate, and vigorous intensities was derived from predicted METs from each model. Correlations were calculated to compare raw and count data between accelerometers, and percent agreement was used to compare epoch-by-epoch activity intensity.
Results: For raw data, correlations for mean acceleration were 0.96 T 0.05, 0.89 T 0.16, 0.71 T 0.33, and 0.80 T 0.28, and those for variance were 0.98 T 0.02, 0.98 T 0.03, 0.91 T 0.06, and 1.00 T 0.00 in the X, Y, and Z axes and VM, respectively. For count data, corresponding correlations were 1.00 T 0.01, 0.98 T 0.02, 0.96 T 0.04, and 1.00 T 0.00, respectively. Freedson 1998 and 2011 count-based models had significantly higher percent agreement for activity intensity (95.1% T 5.6% and 95.5% T 4.0%) compared with theMontoye 2015 raw data model (61.5% T 27.6%; P G 0.001).
Conclusions: Count data were more highly comparable than raw data between accelerometers. Data filtering and/or more robust raw data models are needed to improve raw data comparability between ActiGraph GT3X+ and Link accelerometers
Actively Contracting Bundles of Polar Filaments
We introduce a phenomenological model to study the properties of bundles of
polar filaments which interact via active elements. The stability of the
homogeneous state, the attractors of the dynamics in the unstable regime and
the tensile stress generated in the bundle are discussed. We find that the
interaction of parallel filaments can induce unstable behavior and is
responsible for active contraction and tension in the bundle. Interaction
between antiparallel filaments leads to filament sorting. Our model could apply
to simple contractile structures in cells such as stress fibers.Comment: 4 pages, 4 figures, RevTex, to appear in Phys. Rev. Let
The effects of the CHANGE! intervention on children's physical activity and health
Low childhood physical activity levels, and high paediatric overweight and obesity levels, carry a considerable burden to health including cardiometabolic disease, low fitness, and reduced psychosocial well-being. Numerous school- based physical activity interventions have been conducted with varied success. This thesis therefore aimed to develop and investigate the effectiveness of the Children's Health, Activity and Nutrition: Get Educated! (CHANGE!) project, which was a school-based curriculum intervention to promote healthy lifestyles using an educational focus on physical activity and healthy eating. The purpose of the formative study (Study 1) was to elicit subjective views of children, their parents, and teachers about physical activity to inform the design of the CHANGE! intervention programme. Analyses revealed that families have a powerful and important role in promoting health-enhancing behaviours. Involvement of parents and the whole family is a strategy that could be significant to ~ncrease children's physical activity levels. There is large variation in the cut-points used to define moderate physical activity (MPA), vigorous physical activity (VPA) and sedentary time, which impacts on accurate estimation of physical activity levels. The purpose of Study 2 was to test a field-based protocol using intermittent activities representative of children's physical activity behaviours, to generate behaviourally valid, population-specific cut-points for sedentary behaviour, MPA and VPA. These cut-points were subsequently applied to CHANGE! to investigate changes in physical activity (Study 3). The CHANGE! intervention resulted in positive changes to body size and VPA outcomes after follow-up. The effects were strongest among those sociodemographic groups at greatest risk of poor health status. Further work is required to test the sustained effectiveness of this approach in the medium and long-term. Further, the development of an inexpensive and replicable field- based protocol to generate behaviourally valid and population-specific accelerometer cut-points may improve classification of physical activity levels in children, which could enhance subsequent intervention and observational studies
Effect of sampling rate on acceleration and counts of hip- and wrist-worn ActiGraph accelerometers in children
Sampling rate (Hz) of ActiGraph accelerometers may affect processing of acceleration to activity counts when using a hip-worn monitor, but research is needed to quantify if sampling rate affects actual acceleration (mg's), when using wrist-worn accelerometers and during non-locomotive activities. Objective: To assess the effect of ActiGraph sampling rate on total counts/15-sec and mean acceleration and to compare differences due to sampling rate between accelerometer wear locations and across different types of activities. Approach: Children (n=29) wore a hip- and wrist-worn accelerometer (sampled at 100 Hz, downsampled in MATLAB to 30 Hz) during rest/transition periods, active video games, and a treadmill test to volitional exhaustion. Mean acceleration and counts/15-sec were computed for each axis and as vector magnitude. Main Results: There were mostly no significant differences in mean acceleration. However, 100 Hz data resulted in significantly more total counts/15-sec (mean bias 4-43 counts/15-sec across axes) for both the hip- and wrist-worn monitor when compared to 30 Hz data. Absolute differences increased with activity intensity (hip: r=0.46-0.63; wrist: r=0.26-0.55) and were greater for hip- versus wrist-worn monitors. Percent agreement between 100 and 30 Hz data was high (97.4-99.7%) when cut-points or machine learning algorithms were used to classify activity intensity. Significance: Our findings support that sampling rate affects the generation of counts but adds that differences increase with intensity and when using hip-worn monitors. We recommend researchers be consistent and vigilantly report the sampling rate used, but note that classifying data into activity intensities resulted in agreement despite differences in sampling rate
Magnetic and electric properties of double-perovskites and estimation of their Curie temperatures by ab initio calculations
First principles electronic structure calculations have been carried out on
ordered double perovskites Sr_2B'B"O_6 (for B' = Cr or Fe and B" 4d and 5d
transition metal elements) with increasing number of valence electrons at the
B-sites, and on Ba_2MnReO_6 as well as Ba_2FeMoO_6. The Curie temperatures are
estimated ab initio from the electronic structures obtained with the local
spin-density functional approximation, full-potential generalized gradient
approximation and/or the LDA+U method (U - Hubbard parameter). Frozen
spin-spirals are used to model the excited states needed to evaluate the
spherical approximation for the Curie temperatures. In cases, where the induced
moments on the oxygen was found to be large, the determination of the Curie
temperature is improved by additional exchange functions between the oxygen
atoms and between oxygen and B' and B" atoms.
A pronounced systematics can be found among the experimental and/or
calculated Curie temperatures and the total valence electrons of the transition
metal elements.Comment: 8 pages, 11 figures. Submitted to the Physical Review
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