Application of various types of alumina and nano-γ-alumina sulfuric acid in the synthesis of α-aminonitriles derivatives: comparative study

An efficient and green protocol for the synthesis of α-aminonitrile derivatives by one-pot reaction of different aldehydes with amines and trimethylsilyl cyanide has been developed using natural alumina, alumina sulfuric acid (ASA), nano-g-alumina, nano-g-alumina sulfuric acid (nano-g-ASA) under microwave irradiation and solvent-free conditions. The advantages of methods are short reaction times, high yields, milder conditions and easy work up. The catalysts can be recovered for the subsequent reactions and reused without any appreciable loss of efficiency. KEY WORDS: Nano-g-alumina, Nano-g-alumina sulfuric acid, Green synthesis, Microwave irradiation, α-aminonitriles derivatives Bull. Chem. Soc. Ethiop. 2014, 28(3), 441-450.DOI: http://dx.doi.org/10.4314/bcse.v28i3.1

Investigation of Breakthrough Curves of Citric Acid Adsorption

In this paper, experimental breakthrough curves for citric acid adsorption from aqueous solution onto ion-exchange resin at 20, 35, 55 °C have been obtained by some weak and strong basic anionic resins, such as IRA-92, IRA-93, IRA-420 and IRA-458. The results show that amberlite IRA-93 has good performance and is one of the best resins in the process of citric acid recovery from aqueous solution. Also, the temperature effect study shows that an increase in temperature causes an increase in diffusion coefficient of particles, but the saturation capacity of resin decreases. To achieve an appropriate model, three mathematical models were analyzed to predict system properties based on statistical tests, and finally, the appropriate model was determined. To examine model capability, mathematical equations have been implemented in various breakthrough curve data obtained by other investigators, and the results show appropriate conformity

A Systematic Review and Meta-analysis to Investigate the Correlation Vegetable Irrigation with Wastewater and Concentration of Potentially Toxic Elements (PTES): a Case Study of Spinach (Spinacia oleracea) and Radish (Raphanus raphanistrum subsp. sativus)

Water shortage and stress around the world lead to the reuse of wastewater in many sectors while the recycling of water in agriculture as one of the most consumed sectors can boost the contamination of crops by potentially toxic elements (PTEs). Therefore, this study was aimed to investigate the correlation between the accumulation of PTEs (Fe, Zn, Cr, Ni, Cu, Pb, As, Cd, and Se) in edible parts of spinach and radish plants and sewage irrigation by the aid of a meta-analysis. Moreover, the non-carcinogenic risk (N-CR) and carcinogenic risk (CR) for health risk assessment of consumers were assessed through actual total target hazard quotient (TTHQact) and carcinogenic risk (CRact). After the screening process, 51 articles with 75 studies were included. According to findings, the rank order of PTEs in spinach and radish were Fe > Zn > Cr > Cu > Ni > Pb > Cd > As > Se and Fe > Zn > Cr > Ni > Cu > Pb > As > Cd > Se, respectively. PTE adsorption by edible parts of spinach (leafy vegetable) was higher than radish. The health risk assessment shows that residents in Iran, India, and China are at N-CR while the population of Iran, India, and Pakistan are facing CR. © 2020, Springer Science+Business Media, LLC, part of Springer Nature

IDENTIFYING SUITABLE LOCATIONS FOR MANGROVE PLANTATION USING GEOSPATIAL INFORMATION SYSTEM AND REMOTE SENSING

Mangroves provide numerous environmental benefits, such as carbon sequestration, water purification, climate change mitigation, and flood and Tsunami impact reduction. Despite these unique advantages, mangroves are threatened by the combined adverse impacts of human activities and climate change. Therefore, it is essential to implement reasonable practices to avoid further degradation of mangroves and provide efficient workflows to increase their extent. Accordingly, better plantation policies are principally required for their conservation and rehabilitation. In this study, we desired to detect suitable locations for mangrove plantation in coastal areas of Hormozgan Province, Iran. We considered a relatively new Multi Criteria Decision Making (MCDM) technique to combine ten criteria derived from remote sensing in a GIS environment. The Best Worst Method (BWM), as an MDCM technique, was implemented to determine the relative importance of each criterion. Afterward, all criteria were aggregated using the Weighted Linear Combination (WLC) method to produce a mangrove plantation suitability map. Statistical measures, including Overall Accuracy (OA = 95%), Kappa Coefficient (KC = 87.9%), and Area Under Curve (AUC = 98.79%), indicated the high applicability of the implemented method for mangrove plantation site allocation. The produced map could give managers a profound insight into finding optimal spots to plant mangroves

LYVE1 Marks the Divergence of Yolk Sac Definitive Hemogenic Endothelium from the Primitive Erythroid Lineage.

The contribution of the different waves and sites of developmental hematopoiesis to fetal and adult blood production remains unclear. Here, we identify lymphatic vessel endothelial hyaluronan receptor-1 (LYVE1) as a marker of yolk sac (YS) endothelium and definitive hematopoietic stem and progenitor cells (HSPCs). Endothelium in mid-gestation YS and vitelline vessels, but not the dorsal aorta and placenta, were labeled by Lyve1-Cre. Most YS HSPCs and erythro-myeloid progenitors were Lyve1-Cre lineage traced, but primitive erythroid cells were not, suggesting that they represent distinct lineages. Fetal liver (FL) and adult HSPCs showed 35%-40% Lyve1-Cre marking. Analysis of circulation-deficient Ncx1-/- concepti identified the YS as a major source of Lyve1-Cre labeled HSPCs. FL proerythroblast marking was extensive at embryonic day (E) 11.5-13.5, but decreased to hematopoietic stem cell (HSC) levels by E16.5, suggesting that HSCs from multiple sources became responsible for erythropoiesis. Lyve1-Cre thus marks the divergence between YS primitive and definitive hematopoiesis and provides a tool for targeting YS definitive hematopoiesis and FL colonization

IDENTIFYING SUITABLE LOCATIONS FOR MANGROVE PLANTATION USING GEOSPATIAL INFORMATION SYSTEM AND REMOTE SENSING

Mangroves provide numerous environmental benefits, such as carbon sequestration, water purification, climate change mitigation, and flood and Tsunami impact reduction. Despite these unique advantages, mangroves are threatened by the combined adverse impacts of human activities and climate change. Therefore, it is essential to implement reasonable practices to avoid further degradation of mangroves and provide efficient workflows to increase their extent. Accordingly, better plantation policies are principally required for their conservation and rehabilitation. In this study, we desired to detect suitable locations for mangrove plantation in coastal areas of Hormozgan Province, Iran. We considered a relatively new Multi Criteria Decision Making (MCDM) technique to combine ten criteria derived from remote sensing in a GIS environment. The Best Worst Method (BWM), as an MDCM technique, was implemented to determine the relative importance of each criterion. Afterward, all criteria were aggregated using the Weighted Linear Combination (WLC) method to produce a mangrove plantation suitability map. Statistical measures, including Overall Accuracy (OA = 95%), Kappa Coefficient (KC = 87.9%), and Area Under Curve (AUC = 98.79%), indicated the high applicability of the implemented method for mangrove plantation site allocation. The produced map could give managers a profound insight into finding optimal spots to plant mangroves

Position and Velocity Control for Telemanipulation with Interoperability Protocol

International audienceIn this paper we describe how a generic interoperability teler-obotics protocol can be applied for master-slave robotic systems operating in position-position, position-speed and hybrid control modes. The interoperability protocol allows robust and efficient data exchange for teleoperation systems, however it was not shown how it can fit switching position and rate control modes. Here we propose the general framework of hybrid position and rate control modes with interoperability protocol. Furthermore, we demonstrate experimentally that the framework is suitable for robotics teleoperation systems in which a human-operator can switch between position-position and position-speed master and slave robots' workspace mapping