First-Principles Thermodynamics of Coherent Interfaces in Samarium-Doped Ceria Nanoscale Superlattices

Nanoscale superlattices of samarium-doped ceria layers with varying doping levels have been recently proposed as a novel fuel cell electrolyte. We calculate the equilibrium composition profile across the coherent {100} interfaces present in this system using lattice-gas Monte Carlo simulations with long-range interactions determined from electrostatics and short-range interactions obtained from ab initio calculations. These simulations reveal the formation of a diffuse, nonmonotonic, and surprisingly wide (11 nm at 400 K) interface composition profile, despite the absence of space charge regions

Exclusive electroproduction revisited: treating kinematical effects

Generalized parton distributions of the nucleon are accessed via exclusive leptoproduction of the real photon. While earlier analytical considerations of phenomenological observables were restricted to twist-three accuracy, i.e., taking into account only terms suppressed by a single power of the hard scale, in the present study we revisit this differential cross section within the helicity formalism and restore power-suppressed effects stemming from the process kinematics exactly. We restrict ourselves to the phenomenologically important case of lepton scattering off a longitudinally polarized nucleon, where the photon flips its helicity at most by one unit.Comment: 22 pages, 1 figur

Supernova Constraints and Systematic Uncertainties from the First Three Years of the Supernova Legacy Survey

We combine high-redshift Type Ia supernovae from the first three years of the Supernova Legacy Survey (SNLS) with other supernova (SN) samples, primarily at lower redshifts, to form a high-quality joint sample of 472 SNe (123 low-z, 93 SDSS, 242 SNLS, and 14 Hubble Space Telescope). SN data alone require cosmic acceleration at >99.999% confidence, including systematic effects. For the dark energy equation of state parameter (assumed constant out to at least z = 1.4) in a flat universe, we find w = –0.91^(+0.16)_(–0.20)(stat)^(+0.07)_(–0.14)(sys) from SNe only, consistent with a cosmological constant. Our fits include a correction for the recently discovered relationship between host-galaxy mass and SN absolute brightness. We pay particular attention to systematic uncertainties, characterizing them using a systematic covariance matrix that incorporates the redshift dependence of these effects, as well as the shape-luminosity and color-luminosity relationships. Unlike previous work, we include the effects of systematic terms on the empirical light-curve models. The total systematic uncertainty is dominated by calibration terms. We describe how the systematic uncertainties can be reduced with soon to be available improved nearby and intermediate-redshift samples, particularly those calibrated onto USNO/SDSS-like systems

A Note on Infinities in Eternal Inflation

In some well-known scenarios of open-universe eternal inflation, developed by Vilenkin and co-workers, a large number of universes nucleate and thermalize within the eternally inflating mega-universe. According to the proposal, each universe nucleates at a point, and therefore the boundary of the nucleated universe is a space-like surface nearly coincident with the future light cone emanating from the point of nucleation, all points of which have the same proper-time. This leads the authors to conclude that at the proper-time t = t_{nuc} at which any such nucleation occurs, an infinite open universe comes into existence. We point out that this is due entirely to the supposition of the nucleation occurring at a single point, which in light of quantum cosmology seems difficult to support. Even an infinitesimal space-like length at the moment of nucleation gives a rather different result -- the boundary of the nucleating universe evolves in proper-time and becomes infinite only in an infinite time. The alleged infinity is never attained at any finite time.Comment: 13 pages and 6 figure

Jet Investigations Using the Radial Moment

We define the radial moment, , for jets produced in hadron-hadron collisions. It can be used as a tool for studying, as a function of the jet transverse energy and pseudorapidity, radiation within the jet and the quality of a perturbative description of the jet shape. We also discuss how non-perturbative corrections to the jet transverse energy affect .Comment: 14 pages, LaTeX, 6 figure

Must Cosmological Perturbations Remain Non-Adiabatic After Multi-Field Inflation?

Even if non-adiabatic perturbations are generated in multi-field inflation, the perturbations will become adiabatic if the universe after inflation enters an era of local thermal equilibrium, with no non-zero conserved quantities, and will remain adiabatic as long as the wavelength is outside the horizon, even when local thermal equilibrium no longer applies. Small initial non-adiabatic perturbations associated with imperfect local thermal equilibrium remain small when baryons are created from out-of-equilibrium decay of massive particles, or when dark matter particles go out of local thermal equilibrium.Comment: 12 pages, typographical errors corrected, acknowledgment added. Article accepted for publication in Physical Review

Design and fabrication of a radiative actively cooled honeycomb sandwich structural panel for a hypersonic aircraft

The panel assembly consisted of an external thermal protection system (metallic heat shields and insulation blankets) and an aluminum honeycomb structure. The structure was cooled to temperature 442K (300 F) by circulating a 60/40 mass solution of ethylene glycol and water through dee shaped coolant tubes nested in the honeycomb and adhesively bonded to the outer skin. Rene'41 heat shields were designed to sustain 5000 cycles of a uniform pressure of + or - 6.89kPa (+ or - 1.0 psi) and aerodynamic heating conditions equivalent to 136 kW sq m (12 Btu sq ft sec) to a 422K (300 F) surface temperature. High temperature flexible insulation blankets were encased in stainless steel foil to protect them from moisture and other potential contaminates. The aluminum actively cooled honeycomb sandwich structural panel was designed to sustain 5000 cycles of cyclic in-plane loading of + or - 210 kN/m (+ or - 1200 lbf/in.) combined with a uniform panel pressure of + or - 6.89 kPa (?1.0 psi)

Quantum Decoherence in a D-Foam Background

Within the general framework of Liouville string theory, we construct a model for quantum D-brane fluctuations in the space-time background through which light closed-string states propagate. The model is based on monopole and vortex defects on the world sheet, which have been discussed previously in a treatment of 1+1-dimensional black-hole fluctuations in the space-time background, and makes use of a T-duality transformation to relate formulations with Neumann and Dirichlet boundary conditions. In accordance with previous general arguments, we derive an open quantum-mechanical description of this D-brane foam which embodies momentum and energy conservation and small mean energy fluctuations. Quantum decoherence effects appear at a rate consistent with previous estimates.Comment: 16 pages, Latex, two eps figures include

First-principles thermodynamic modeling of lanthanum chromate perovskites

Tendencies toward local atomic ordering in (A,A′)(B,B′)O_(3−δ) mixed composition perovskites are modeled to explore their influence on thermodynamic, transport, and electronic properties. In particular, dopants and defects within lanthanum chromate perovskites are studied under various simulated redox environments. (La_(1−x),Sr_x)(Cr_(1−y),Fe_y)O_(3−δ) (LSCF) and (La_(1−x),Sr_x)(Cr_(1−y),Ru_y)O_(3−δ) (LSCR) are modeled using a cluster expansion statistical thermodynamics method built upon a density functional theory database of structural energies. The cluster expansions are utilized in lattice Monte Carlo simulations to compute the ordering of Sr and Fe(Ru) dopant and oxygen vacancies (Vac). Reduction processes are modeled via the introduction of oxygen vacancies, effectively forcing excess electronic charge onto remaining atoms. LSCR shows increasingly extended Ru-Vac associates and short-range Ru-Ru and Ru-Vac interactions upon reduction; LSCF shows long-range Fe-Fe and Fe-Vac interaction ordering, inhibiting mobility. First principles density functional calculations suggest that Ru-Vac associates significantly decrease the activation energy of Ru-Cr swaps in reduced LSCR. These results are discussed in view of experimentally observed extrusion of metallic Ru from LSCR nanoparticles under reducing conditions at elevated temperature