Исследование процесса синтеза гидрокарбонатных магнезиальных структур в водных условиях

Объект исследования – магнезиальное вяжущее на основе порошка каустического магнезита и водного раствора бикарбоната магния в качестве затворителя. Предмет исследования – процесс синтеза гидрокарбонатных магнезиальных структур при твердении гидравлического магнезиального вяжущего в водных условиях. Цель работы – исследование процесса синтеза гидрокарбонатных магнезиальных структур при твердении гидравлического магнезиального вяжущего в водных условиях. В результате исследования: установлено влияние водной среды и типа системы (открытой и закрытой) на процессы гидратации и твердения магнезиального вяжущего.The object of research is a magnesia binder based on caustic magnesite powder and an aqueous solution of magnesium bicarbonate as a grouting fluid. The subject of research is the process of synthesis of hydrocarbonate magnesia structures during hardening of a hydraulic magnesia binder in water conditions. The purpose of this work is to study the synthesis of hydrocarbonate magnesia structures during hardening of a hydraulic magnesia binder in water conditions. As a result of the research: the influence of the aquatic environment and the type of system (open and closed) on the processes of hydration and hardening of magnesia binder was established

Characterisation of the photolytic HONO-source in the atmosphere simulation chamber SAPHIR

HONO formation has been proposed as an important OH radical source in simulation chambers for more than two decades. Besides the heterogeneous HONO formation by the dark reaction of NO₂ and adsorbed water, a photolytic source has been proposed to explain the elevated reactivity in simulation chamber experiments. However, the mechanism of the photolytic process is not well understood so far. As expected, production of HONO and NO_x was also observed inside the new atmospheric simulation chamber SAPHIR under solar irradiation. This photolytic HONO and NO_x formation was studied with a sensitive HONO instrument under reproducible controlled conditions at atmospheric concentrations of other trace gases. It is shown that the photolytic HONO source in the SAPHIR chamber is not caused by NO₂ reactions and that it is the only direct NO_y source under illuminated conditions. In addition, the photolysis of nitrate which was recently postulated for the observed photolytic HONO formation on snow, ground, and glass surfaces, can be excluded in the chamber. A photolytic HONO source at the surface of the chamber is proposed which is strongly dependent on humidity, on light intensity, and on temperature. An empirical function describes these dependencies and reproduces the observed HONO formation rates to within 10%. It is shown that the photolysis of HONO represents the dominant radical source in the SAPHIR chamber for typical tropospheric O₃/H₂O concentrations. For these conditions, the HONO concentrations inside SAPHIR are similar to recent observations in ambient air

The Effects of Lower-Extremity Plyometric Training on Soccer-Specific Outcomes in Adult Male Soccer Players:A Systematic Review and Meta-Analysis

BACKGROUND: Plyometric training is a specific form of strength training that is used to improve the physical performance of athletes. An overview of the effects of plyometric training on soccer-specific outcomes in adult male soccer players is not available yet. PURPOSE: To systematically review and meta-analyze the effects of plyometric training on soccer-specific outcome measures in adult male soccer players and to identify which programs are most effective. METHODS: PubMed, Embase/Medline, Cochrane, PEDro, and Scopus were searched. Extensive quality and risk of bias assessments were performed using the Cochrane ROBINS 2.0 for randomized trials. A random effects meta-analysis was performed using Cochrane Review Manager 5.3. RESULTS: Seventeen randomized trials were included in the meta-analysis. The impact of plyometric training on strength, jump height, sprint speed, agility, and endurance was assessed. Only jump height, 20-m sprint speed, and endurance were significantly improved by plyometric training in soccer players. Results of the risk of bias assessment of the included studies resulted in overall scores of some concerns for risk of bias and high risk of bias. CONCLUSION: This review and meta-analysis showed that plyometric training improved jump height, 20-m sprint speed, and endurance, but not strength, sprint speed over other distances, or agility in male adult soccer players. However, the low quality of the included studies and substantial heterogeneity means that results need to be interpreted with caution. Future high-quality research should indicate whether or not plyometric training can be used to improve soccer-specific outcomes and thereby enhance performance

Organic nitrate and secondary organic aerosol yield from NO3 oxidation of ß-pinene evaluated using a gas-phase kinetics/aerosol partitioning model

The yields of organic nitrates and of secondary organic aerosol (SOA) particle formation were measured for the reaction NO3+beta-pinene under dry and humid conditions in the atmosphere simulation chamber SAPHIR at Research Center Julich. These experiments were conducted at low concentrations of NO3 (NO3+N2O5 < 10 ppb) and beta-pinene (peak similar to 15 ppb), with no seed aerosol. SOA formation was observed to be prompt and substantial (similar to 50% mass yield under both dry conditions and at 60% RH), and highly correlated with organic nitrate formation. The observed gas/aerosol partitioning of organic nitrates can be simulated using an absorptive partitioning model to derive an estimated vapor pressure of the condensing nitrate species of p(vap) similar to 5x10(-6) Torr (6.67x10(-4) Pa), which constrains speculation about the oxidation mechanism and chemical identity of the organic nitrate. Once formed the SOA in this system continues to evolve, resulting in measurable aerosol volume decrease with time. The observations of high aerosol yield from NOx-dependent oxidation of monoterpenes provide an example of a significant anthropogenic source of SOA from biogenic hydrocarbon precursors. Estimates of the NO3+beta-pinene SOA source strength for California and the globe indicate that NO3 reactions with monoterpenes are likely an important source (0.5-8% of the global total) of organic aerosol on regional and global scales

Technical Note: Formal blind intercomparison of HO₂ measurements in the atmosphere simulation chamber SAPHIR during the HOxComp campaign

Hydroperoxy radical (HO₂) concentrations were measured during the formal blind intercomparison campaign HOxComp carried out in Jülich, Germany, in 2005. Three instruments detected HO₂ via chemical conversion to hydroxyl radicals (OH) and subsequent detection of the sum of OH and HO₂ by laser induced fluorescence (LIF). All instruments were based on the same detection and calibration scheme. Because measurements by a MIESR instrument failed during the campaign, no absolute reference measurement was available, so that the accuracy of individual instruments could not be addressed. Instruments sampled ambient air for three days and were attached to the atmosphere simulation chamber SAPHIR during the second part of the campaign. Six experiments of one day each were conducted in SAPHIR, where air masses are homogeneously mixed, in order to investigate the performance of instruments and to determine potential interferences of measurements under well-controlled conditions. Linear correlation coefficients (<i>R</i>²) between measurements of the LIF instruments are generally high and range from 0.82 to 0.98. However, the agreement between measurements is variable. The regression analysis of the entire data set of measurements in SAPHIR yields slopes between 0.69 to 1.26 and intercepts are smaller than typical atmospheric daytime concentrations (less than 1 pptv). The quality of fit parameters improves significantly, when data are grouped into data subsets of similar water vapor concentrations. Because measurements of LIF instruments were corrected for a well-characterized water dependence of their sensitivities, this indicates that an unknown factor related to water vapor affected measurements in SAPHIR. Measurements in ambient air are also well-correlated, but regression parameters differ from results obtained from SAPHIR experiments. This could have been caused by differences in HO₂ concentrations in the sampled air at the slightly different locations of instruments

Ди-мюонное фоторождение в эксперименте NA64

В работе проанализированы основные процессы, вносящие мюонный вклад в статистику эксперимента NA64. Рассмотрены методы моделирования случайных величин. Разработан Монте-Карло генератор процесса ди-мюонного фоторождения, позволяющий получить энергетические и угловые распределения мюонов.The main processes involved in the muon contribution to the NA64 experiment statistics are analyzed. Methods for modeling random variables are considered. A Monte-Carlo generator was developed for the process of di-muon photoproduction, which makes it possible to obtain energy and angular distributions of muons

Missing OH source in a suburban environment near Beijing: observed and modelled OH an HO2 concentrations in summer 2006

Measurements of ambient OH and HO₂ radicals were performed by laser induced fluorescence (LIF) during CAREBeijing2006 (Campaigns of Air Quality Research in Beijing and Surrounding Region 2006) at the suburban site Yufa in the south of Beijing in summer 2006. On most days, local air chemistry was influenced by aged air pollution that was advected by a slow, almost stagnant wind from southern regions. Observed daily maxima of OH and HO₂^* were in the range of (4–17) × 10⁶ cm^&minus;3 and (2–24) × 10⁸ cm^&minus;3, respectively. During daytime, OH reactivities were generally high (10–30 s^&minus;1) and mainly contributed by VOCs and their oxidation products. The comparison of modelled and measured HO_x concentrations reveals a systematic underprediction of OH as a function of NO. A large discrepancy of a factor 2.6 is found at the lowest NO concentration encountered (0.1 ppb), whereas the discrepancy becomes insignificant above 1 ppb NO. This study extends similar observations from the Pearl-River Delta (PRD) in South China to a more urban environment. The OH discrepancy at Yufa can be resolved, if NO-independent additional OH recycling is assumed in the model. The postulated Leuven Isoprene Mechanism (LIM) has the potential to explain the gap between modelled and measured OH at Beijing taking into account conservative error estimates, but still lacks experimental confirmation. This and the hereby unresolved discrepancy at PRD suggest that other VOCs besides isoprene might be involved in the required, additional OH recycling. Fast primary production of RO_x radicals up to 7 ppb h^&minus;1 was determined at Beijing which was dominated by the photolysis of O₃, HONO, HCHO, and dicarbonyls. For a special case, 20 August, when the plume of Beijing city was encountered, a missing primary HO_x source (≈ 3 ppb h^&minus;1) was determined under high NO_x conditions similar to other urban areas like Mexico city. CAREBeijing2006 emphasizes the important role of OVOCs as a radical source and sink, and the need for further investigation of the chemical degradation of VOCs in order to better understand radical chemistry in VOC-rich air