Flexible Energy Supply for Distributed Electronics Powered by Organic Solar Cell and Printed Supercapacitor

In this work we report a flexible energy supply unit made by printing flexible disposable aqueous supercapacitor modules onto a light harvester. In order to demonstrate simpler and more scalable manufacturing processes, we printed the supercapacitors monolithically instead of laminating electrodes face-to-face and integrated the series connections into the fabrication process. The supercapacitor modules were printed onto the backside of the Organic Photovoltaic (OPV) modules to combine energy harvesting and storage module for harvesting light under normal indoor conditions, storing it in a supercapacitor module, and thus offering power for low power IoT devices.acceptedVersionPeer reviewe

High spatial resolution aerosol retrievals used for daily particulate matter monitoring over Po valley, northern Italy

The Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 5.1 Aerosol Optical Depth (AOD) data retrieved at 0.55 μm with spatial resolution of 10 km (MYD04) and the new 1 km Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm from MODIS is investigated in this work. We focus on evaluating the ability of these two products to characterize the spatial distribution of aerosols within urban areas. This is done through the comparison with PM10 measurements from 126 of the Italian Regional Agency for Environmental Protection (ARPA) ground monitoring stations during 2012. The Po Valley area (northern Italy) was chosen as the study domain since urban air pollution is one of the most important concerns in this region. Population and industrial activities are located within a large number of urban areas within the valley. We find that the annual correlations between PM10 and AOD are R2 = 0.90 and R2 = 0.62 for MYD04 and for MAIAC respectively. When the depth of the planetary boundary layer (PBL) is used to normalize the AOD, we find a significant improvement in the PM–AOD correlation. The introduction of the PBL information is needed for AOD to capture the seasonal cycle of the observed PM10 over the Po valley and significantly improves the PM vs. AOD relationship, leading to a correlation of R2 = 0.98 for both retrievals when they are normalized by the PBL depth. The results show that the normalized MAIAC retrieval provides a higher resolution depiction of the AOD within the Po Valley and performs as well in a statistical sense as the normalized standard MODIS retrieval for the same days and locations

Photoinduced hole transfer in QD–phthalocyanine hybrids

A series of CdSe quantum dot (QD)–phthalocyanine (Pc) hybrids were synthesized and their photophysics was studied using steady state and time-resolved spectroscopic methods. Emission of QDs was progressively quenched upon increasing the concentration of Pc in the hybrids. A detailed transient absorption study of the hybrids revealed that the mechanism of quenching is charge separation, resulting in the formation of hybrids with negatively charged QDs and the Pc cation. Direct photo-excitation of Pc did not show any detectable interaction between the excited state of Pc and the QD to which it is attached. An explanation is proposed, based on the suggestion that the energy of the lowest unoccupied molecular orbital (LUMO) of Pc is lower than the lower edge of the QD conduction band, while the energy of the highest occupied molecular orbital (HOMO) of Pc is sufficiently higher than the high energy edge of the QD valence band (VB), thus permitting hole transfer from the QD VB to the Pc HOMO after photo-excitation of QDs.acceptedVersionPeer reviewe

Application of MAIAC high spatial resolution aerosol retrievals over Po Valley (Italy)

The Moderate Resolution Imaging Spectroradiometer (MODIS) Aerosol Optical Depth (AOD) data retrieved at 0:55 μm with spatial resolutions of 10 km and 1 km AOD have been considered in this work. The 10 km resolution of MODIS AOD product is from the MODIS Collection 5:1 dark target retrieval and the 1 km resolution retrieval is from the new Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm. We evaluate ability of these two products to characterize the spatial distribution of aerosols in urban areas through comparison with surface PM10 measurements. The Po Valley area (northern Italy) is considered in this study since urban air pollution is an important concern. Population and industrial activities are located in a large number of urban areas distributed within the valley. The 10 km spatial resolution of MODIS AOD product is considered too large for air quality studies at the urban scale. Using MAIAC data at 1 km, we examine the relationship between PM10 concentrations, AOD, and AOD normalized by Planetary Boundary Layer (PBL) depths obtained from NCEP global analysis, for year 2012 over the Po Valley. Results show that the MAIAC retrieval provides a high resolution depiction of the AOD within the Po Valley and performs nearly as well in a statistical sense as the standard MODIS retrieval during the time period considered. Results also show that normalization by the analyzed PBL depth to obtain an estimate of the mean boundary layer extinction is needed to capture the seasonal cycle of the observed PM10 over the Po Valley