The Effect of Antimony and Cobalt on the Current Efficiency and the Grain Orientation of Deposits during the Electrolysis of a Zinc Sulfate Solution

Preparation of solutions and apparatus and experimental procedure was described. The effect of antimony and cobalt in a zinc sulfate electrolyte upon current efficiency with increasing time was determined by the hydrogen evolution method. The degree of preferred orientation of grains in the electrodeposits was determined by the reflection method of X-ray diffraction

Some mechanical consideration of transmission systems

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Formation of Hydrated Calcium Oxalates in the Presence of Poly-L-Aspartic Acid

The effect of poly-L-aspartic acid (PA) on the crystal structure of calcium oxalate crystals grown after spontaneous nucleation was evaluated as a function of relative supersaturation and calcium:oxalate ratio in a buffered salt solution, with pH and ionic strength in the range of normal human urine. PA was used as a model for naturally occurring acidic urine proteins that have been shown to inhibit nucleation and growth of calcium oxalate crystals. The crystals grown were characterized by optical microscopy and X-ray powder diffraction. It was observed that calcium oxalate monohydrate was the preferred crystalline form in the absence of added PA, and it was the only crystalline form obtained at most conditions tested without PA. However, the presence of PA favored the formation of calcium oxalate dihydrate crystals, when present in adequate quantities. The quantity of PA required to affect this change in preferred crystal structure was increased at higher supersaturations and at lower calcium:oxalate ratios, exhibiting a non-linear dependence on both variables. PA was also shown to be a kinetic inhibitor of calcium oxalate dihydrate crystallization. Aspartic acid monomer was found to cause no change in the preferred structure of calcium oxalate monohydrate at mass concentrations well beyond those required with PA to obtain 100 % calcium oxalate dihydrate, indicating the critical importance of the polymeric nature of PA for this effect on crystal structure

Randall's plaque: Pathogenesis and role in calcium oxalate nephrolithiasis

The purpose of these studies was to test the hypothesis that Randall's plaque develops in unique anatomical sites of the kidney and their formation is conditioned by specific stone-forming pathophysiologies. We performed intraoperative papillary biopsies from kidneys of idiopathic-calcium oxalate (CaOx), intestinal bypass for obesity, brushite (BR) and cystine stone formers (SF) during percutaneous nephrolithotomy. Tissues were examined by infrared analysis and light and electron microscopy. Our analysis revealed a distinct pattern of mineral deposition and papillary pathology for each type of SF. CaOx SF had interstitial apatite crystals beginning at thin loops of Henle. These deposits termed Randall's plaque are thought to serve as sites for stone attachment. No tubular injury was noted. Intestinal bypass patients possessed intraluminal apatite deposits in inner medullary collecting ducts (IMCD) with associated cell injury. BR SF showed the most severe form of cortical and medullary changes with sites of Randall's plaque, and yellowish intraluminal deposits of apatite in IMCD. Cystine SF had plugging of ducts of Bellini with cystine crystals and apatite deposits in IMCD and loops of Henle. Intratubular sites of crystalline deposits were always associated to adjacent regions of interstitial fibrosis. The metabolic, anatomic, and surgical pathologic findings in four distinct groups of SF clearly show that ‘the histology of the renal papilla from a stone former, is particular to the clinical setting’. We believe our approach to studying stone disease will provide insights into the pathogenesis of stone formation for each type of SF that will lead to improved clinical treatment

Soil resources and potential for agricultural development in Bahr El Jebel in southern Sudan, Jonglei Canal project area

The author has identified the following significant results. Fourteen LANDSAT scenes were used to produce mosaics of the 167, 474 sq km study area. These were black and white MSS 7 images and false color composite images. Five major soil-landscape units were delineated on the mosaics, and these were subdivided into a total of 40 soil mapping units. Aerial reconnaissance was useful in defining boundaries between mapping units and in estimating the proportion of the various soils which composed each mapping unit. Ground surveying permitted first-hand observation of major soils and sampling for quantitative laboratory analysis. Soil interpretations were made, including properties, potentials, and limitations

Three-dimensional bottom diffraction in the North Pacific

Author Posting. © Acoustical Society of America, 2019. This article is posted here by permission of Acoustical Society of America for personal use, not for redistribution. The definitive version was published in Journal of the Acoustical Society of America 146(3), (2019): 1913-1922, doi:10.1121/1.5125427.A significant aspect of bottom-interaction in deep water acoustic propagation, from point sources to point receivers, is the diffraction (or scattering) of energy from discrete seafloor locations along repeatable, deterministic paths in three-dimensions. These bottom-diffracted surface-reflected (BDSR) paths were first identified on the North Pacific acoustic laboratory experiment in 2004 (NPAL04) for a diffractor located on the side of a small seamount. On the adjacent deep seafloor, ambient noise and propagation in the ocean sound channel were sufficiently quiet that the BDSRs were the dominant arrival. The ocean bottom seismometer augmentation in the North Pacific (OBSANP) experiment in June–July 2013 studied BDSRs at the NPAL04 site in more detail. BDSRs are most readily identified by the arrival time of pulses as a function of range to the receiver for a line of transmissions. The diffraction points for BDSRs occur on the relatively featureless deep seafloor as well as on the sides of small seamounts. Although the NPAL04 and OBSANP experiments had very different geometries the same diffractor location is consistent with observed arrivals in both experiments within the resolution of the analysis. On OBSANP the same location excites BDSRs for 77.5, 155, and 310 Hz transmissions.We greatly appreciate the support from Captain Curl, the officers, and crew of the R/V Melville (MV1308). The OBS data used in this research was acquired on instruments from the ocean bottom seismograph instrument pool (OBSIP) at Scripps Institution of Oceanography. Ernie Aaron (SIO) was responsible for shipboard OBS operations. The multi-beam data was processed using the MB-System (Caress and Chayes, 1996). Figure 1 was prepared using the generic mapping tool (Wessel and Smith, 1998). Feedback and reviews from an anonymous reviewer and the editorial staff of JASA are also greatly appreciated. The OBSANP experiment was funded by the ONR Ocean Acoustics Program (Code 322 OA) under Grant Nos. N00014-10-1-0987 and N00014-10-1-0510. Analysis was carried out under ONR Grant Nos. N00014-14-1-0324, N00014-16-1-2337, and N00014-17-C-7043.2020-03-3

Observations of sound-speed fluctuations in the Beaufort Sea from summer 2016 to summer 2017

© The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kucukosmanoglu, M., Colosi, J. A., Worcester, P. F., Dzieciuch, M. A., & Torres, D. J. Observations of sound-speed fluctuations in the Beaufort Sea from summer 2016 to summer 2017. Journal of the Acoustical Society of America, 149(3), (2021): 1536-1548, https://doi.org/10.1121/10.0003601.Due to seasonal ice cover, acoustics can provide a unique means for Arctic undersea communication, navigation, and remote sensing. This study seeks to quantify the annual cycle of the thermohaline structure in the Beaufort Sea and characterize acoustically relevant oceanographic processes such as eddies, internal waves, near-inertial waves (NIWs), and spice. The observations are from a seven-mooring, 150-km radius acoustic transceiver array equipped with oceanographic sensors that collected data in the Beaufort Sea from 2016 to 2017. Depth and time variations of the sound speed are analyzed using isopycnal displacements, allowing a separation of baroclinic processes and spice. Compared to lower latitudes, the overall sound speed variability is small with a maximum root mean square of 0.6 m/s. The largest source of variability is spice, most significant in the upper 100 m, followed by eddies and internal waves. The displacement spectrum in the internal wave band is time dependent and different from the Garret-Munk (GM) spectrum. The internal wave energy varied with time averaging 5% of the GM spectrum. The spice sound-speed frequency spectrum has a form very different from the displacement spectrum, a result not seen at lower latitudes. Because sound speed variations are weak, observations of episodic energetic NIWs with horizontal currents up to 20 cm/s have potential acoustical consequences.This research was supported by the Office of Naval Research (ONR) and M.K. was supported by an ONR Ocean Acoustics Graduate Student Fellowship under Award No. N00014-19-1-2203. The 600 kHz ADCP and IPS ice draft data were supported by the ONR Arctic and Global Prediction Program (ONR 322AG) under Award No. N00014-15-1-2782. This material is based on work supported by the ONR under Award No. N00014-15-2068

A deep ocean acoustic noise floor, 1–800 Hz

Author Posting. © Acoustical Society of America, 2018. This article is posted here by permission of Acoustical Society of America for personal use, not for redistribution. The definitive version was published in Journal of the Acoustical Society of America 143 (2018): 1223, doi:10.1121/1.5025042.The ocean acoustic noise floor (observed when the overhead wind is low, ships are distant, and marine life silent) has been measured on an array extending up 987 m from 5048 m depth in the eastern North Pacific, in what is one of only a few recent measurements of the vertical noise distribution near the seafloor in the deep ocean. The floor is roughly independent of depth for 1–6 Hz, and the slope (∼ f−7) is consistent with Longuet-Higgins radiation from oppositely-directed surface waves. Above 6 Hz, the acoustic floor increases with frequency due to distant shipping before falling as ∼ f−2 from 40 to 800 Hz. The noise floor just above the seafloor is only about 5 dB greater than during the 1975 CHURCH OPAL experiment (50–200 Hz), even though these measurements are not subject to the same bathymetric blockage. The floor increases up the array by roughly 15 dB for 40–500 Hz. Immediately above the seafloor, the acoustic energy is concentrated in a narrow, horizontal beam that narrows as f−1 and has a beam width at 75 Hz that is less than the array resolution. The power in the beam falls more steeply with frequency than the omnidirectional spectrum.The OBSANP cruise was funded by the Office of Naval Research under Grant Nos. N00014-10-1-0987, N00014-14- 1-0324, N00014-10-1-0510, and N00014-10-1-0990

Polls and the political process: the use of opinion polls by political parties and mass media organizations in European post‐communist societies (1990–95)

Opinion polling occupies a significant role within the political process of most liberal-capitalist societies, where it is used by governments, parties and the mass media alike. This paper examines the extent to which polls are used for the same purposes in the post-communist countries of Central and Eastern Europe, and in particular, for bringing political elites and citizens together. It argues that these political elites are more concerned with using opinion polls for gaining competitive advantage over their rivals and for reaffirming their political power, than for devolving political power to citizens and improving the general processes of democratization