Climatically driven loss of calcium in steppe soil as a sink for atmospheric carbon

During the last several thousand years the semi‐arid, cold climate of the Russian steppe formed highly fertile soils rich in organic carbon and calcium (classified as Chernozems in the Russian system). Analysis of archived soil samples collected in Kemannaya Steppe Preserve in 1920, 1947, 1970, and fresh samples collected in 1998 indicated that the native steppe Chernozems, however, lost 17–28 kg m−2 of calcium in the form of carbonates in 1970–1998. Here we demonstrate that the loss of calcium was caused by fundamental shift in the steppe hydrologic balance. Previously unleached soils where precipitation was less than potential evapotranspiration are now being leached due to increased precipitation and, possibly, due to decreased actual evapotranspiration. Because this region receives low levels of acidic deposition, the dissolution of carbonates involves the consumption of atmospheric CO2. Our estimates indicate that this climatically driven terrestrial sink of atmospheric CO2 is ∼2.1–7.4 g C m−2 a−1. In addition to the net sink of atmospheric carbon, leaching of pedogenic carbonates significantly amplified seasonal amplitude of CO2 exchange between atmosphere and steppe soil

Color Variability of the Blazar AO 0235+16

Multicolor (UBVRIJHK) observations of the blazar AO 0235+16 are analyzed. The light curves were compiled at the Turin Observatory from literature data and the results of observations obtained in the framework of the WEBT program (http://www.to.astro/blazars/webt/). The color variability of the blazar was studied in eight time intervals with a sufficient number of multicolor optical observations; JHK data are available for only one of these. The spectral energy distribution (SED) of the variable component remained constant within each interval, but varied strongly from one interval to another. After correction for dust absorption, the SED can be represented by a power law in all cases, providing evidence for a synchrotron nature of the variable component. We show that the variability at both optical and IR wavelengths is associated with the same variable source.Comment: 11 pages, 9 figures, 4 tables, accepted for publication in Astronomy Report

The Stellar Content of the Polar Rings in the Galaxies NGC 2685 and NGC 4650A

We present the results of stellar photometry of polar-ring galaxies NGC 2685 and NGC 4650A, using the archival data obtained with the Hubble Space Telescope's Wide Field Planetary Camera 2. Polar rings of these galaxies were resolved into ~800 and ~430 stellar objects in the B, V and Ic bands, considerable part of which are blue supergiants located in the young stellar complexes. The stellar features in the CM-diagrams are best represented by isochrones with metallicity Z = 0.008. The process of star formation in the polar rings of both galaxies was continuous and the age of the youngest detected stars is about 9 Myr for NGC 2685 and 6.5 Myr for NGC 4650A.Comment: 21 pages, 9 figures, AJ 2004 February, accepte

Large Divergence of Projected High Latitude Vegetation Composition and Productivity Due To Functional Trait Uncertainty

Vegetation distribution and composition are expected to change in northern high latitudes under rapid warming, which regulates ecosystem functions but remains challenging to predict. Vegetation change arises from the interplay of chronic climate trends such as warming and transient demographic processes of recruitment, growth, competition, and mortality. Most predictive models overlooked the role of demographic dynamics controlled by plant traits. Here, we simulate vegetation dynamics at the Kougarok Hillslope site in Alaska under historical and future climates using the E3SM Land Model coupled to the Functionally Assembled Terrestrial Simulator (ELM-FATES). To evaluate the roles of plant traits, we parameterize the model with 5,265 trait configurations representing diverse physiological and demographic strategies. Results show current modeled biomass, composition, and productivity are most sensitive to traits controlling photosynthetic capacity, carbon allocation, allometry, and phenology. Among all trait configurations, ∼5% reproduce in situ biomass and plant functional type (PFT) composition measured in 2016, that are indistinguishable from these two observed ecosystem states. Notably, these same trait configurations produce diverging biomass, composition, and productivity under future climate, where the uncertainty attributable to traits is twice the change attributable to climate change. The variation of projected productivity arises from emerging PFT composition under novel climate regimes, primarily explained by traits controlling cold-induced mortality, recruitment, and allometry. Our findings highlight the importance and uncertainty of demographic dynamics and its interaction with climate change in shaping Arctic vegetation change. Improved model predictions will likely benefit from explicit consideration of vegetation demography and better constraints of critical traits

A hybrid multiagent approach for global trajectory optimization

In this paper we consider a global optimization method for space trajectory design problems. The method, which actually aims at finding not only the global minimizer but a whole set of low-lying local minimizers(corresponding to a set of different design options), is based on a domain decomposition technique where each subdomain is evaluated through a procedure based on the evolution of a population of agents. The method is applied to two space trajectory design problems and compared with existing deterministic and stochastic global optimization methods

Using boundary layer equilibrium to reduce uncertainties in transport models and CO₂ flux inversions

This paper reexamines evidence for systematic errors in atmospheric transport models, in terms of the diagnostics used to infer vertical mixing rates from models and observations. Different diagnostics support different conclusions about transport model errors that could imply either stronger or weaker northern terrestrial carbon sinks. Conventional mixing diagnostics are compared to analyzed vertical mixing rates using data from the US Southern Great Plains Atmospheric Radiation Measurement Climate Research Facility, the CarbonTracker data assimilation system based on Transport Model version 5 (TM5), and atmospheric reanalyses. The results demonstrate that diagnostics based on boundary layer depth and vertical concentration gradients do not always indicate the vertical mixing strength. Vertical mixing rates are anti-correlated with boundary layer depth at some sites, diminishing in summer when the boundary layer is deepest. Boundary layer equilibrium concepts predict an inverse proportionality between CO2 vertical gradients and vertical mixing strength, such that previously reported discrepancies between observations and models most likely reflect overestimated as opposed to underestimated vertical mixing. However, errors in seasonal concentration gradients can also result from errors in modeled surface fluxes. This study proposes using the timescale for approach to boundary layer equilibrium to diagnose vertical mixing independently of seasonal surface fluxes, with applications to observations and model simulations of CO2 or other conserved boundary layer tracers with surface sources and sinks. Results indicate that frequently cited discrepancies between observations and inverse estimates do not provide sufficient proof of systematic errors in atmospheric transport models. Some previously hypothesized transport model biases, if found and corrected, could cause inverse estimates to further diverge from carbon inventory estimates of terrestrial sinks

Folding of a donor–acceptor polyrotaxane by using noncovalent bonding interactions

Mechanically interlocked compounds, such as bistable catenanes and bistable rotaxanes, have been used to bring about actuation in nanoelectromechanical systems (NEMS) and molecular electronic devices (MEDs). The elaboration of the structural features of such rotaxanes into macromolecular materials might allow the utilization of molecular motion to impact their bulk properties. We report here the synthesis and characterization of polymers that contain π electron-donating 1,5-dioxynaphthalene (DNP) units encircled by cyclobis(paraquat-p-phenylene) (CBPQT4+), a π electron-accepting tetracationic cyclophane, synthesized by using the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC). The polyrotaxanes adopt a well defined “folded” secondary structure by virtue of the judicious design of two DNP-containing monomers with different binding affinities for CBPQT4+. This efficient approach to the preparation of polyrotaxanes, taken alongside the initial investigations of their chemical properties, sets the stage for the preparation of a previously undescribed class of macromolecular architectures