25 research outputs found
Ab initio study of magnetism at the TiO2/LaAlO3 interface
In this paper we study the possible relation between the electronic and
magnetic structure of the TiO2/LaAlO3 interface and the unexpected magnetism
found in undoped TiO2 films grown on LaAlO. We concentrate on the role
played by structural relaxation and interfacial oxygen vacancies.
LaAlO3 has a layered structure along the (001) direction with alternating LaO
and AlO2 planes, with nominal charges of +1 and -1, respectively. As a
consequence of that, an oxygen deficient TiO2 film with anatase structure will
grow preferently on the AlO2 surface layer. We have therefore performed
ab-initio calculations for superlattices with TiO2/AlO2 interfaces with
interfacial oxygen vacancies. Our main results are that vacancies lead to a
change in the valence state of neighbour Ti atoms but not necessarily to a
magnetic solution and that the appearance of magnetism depends also on
structural details, such as second neighbor positions. These results are
obtained using both the LSDA and LSDA+U approximations.Comment: Accepted for publication in Journal of Materials Scienc
A coded aperture microscope for X-ray fluorescence full-field imaging
The design and construction of an instrument for full-field imaging of the X-ray fluorescence emitted by a fully illuminated sample are presented. The aim is to produce an X-ray microscope with a few micrometers spatial resolution, which does not need to scan the sample. Since the fluorescence from a spatially inhomogeneous sample may contain many fluorescence lines, the optic which will provide the magnification of the emissions must be achromatic, i.e. its optical properties must be energy-independent. The only optics which fulfill this requirement in the X-ray regime are mirrors and pinholes. The throughput of a simple pinhole is very low, so the concept of coded apertures is an attractive extension which improves the throughput by having many pinholes, and retains the achromatic property. Modified uniformly redundant arrays (MURAs) with 10 mu m openings and 50% open area have been fabricated using gold in a lithographic technique, fabricated on a 1 mu m-thick silicon nitride membrane. The gold is 25 mu m thick, offering good contrast up to 20keV. The silicon nitride is transparent down into the soft X-ray region. MURAs with various orders, from 19 up to 73, as well as their respective negative (a mask where open and closed positions are inversed compared with the original mask), have been made. Having both signs of mask will reduce near-field artifacts and make it possible to correct for any lack of contrast
Fabrication and testing of monolithic 384 Germanium strip detector with highly integrated readout
A monolithic 64-channel germanium strip detector system with integrated circuit readout for energy dispersive X-ray diffraction
Tomography with energy dispersive diffraction
X-ray diffraction can be used as the signal for tomographic reconstruction and provides a cross-sectional map of the crystallographic phases and related quantities. Diffraction tomography has been developed over the last decade using monochromatic x-radiation and an area detector. This paper reports tomographic reconstruction with polychromatic radiation and an energy sensitive detector array. The energy dispersive diffraction (EDD) geometry, the instrumentation and the reconstruction process are described and related to the expected resolution. Results of EDD tomography are presented for two samples containing hydroxyapatite (hAp). The first is a 3D-printed sample with an elliptical crosssection and contains synthetic hAp. The second is a human second metacarpal bone from the Roman-era cemetery at Ancaster, UK and contains bio-hAp which may have been altered by diagenesis. Reconstructions with different diffraction peaks are compared. Prospects for future EDD tomography are also discussed