Thermal properties of MgB2: the effect of disorder on gap amplitudes and relaxation times of p and s bands

We present thermal conductivity and specific heat measurements on MgB2 and Mg-AlB2 samples. Thermal properties have been analysed by using a two-gap model in order to estimate the gap amplitudes, D(0)p and D(0)s and the intra-band scattering rates, Gss and Gpp. As a function of Al doping and disorder D(0)s rapidly decreases, while D(0)p is rather constant. Gss and Gpp are increased by the disorder, being Gpp more affected than Gss.Comment: 2 pages, 3 figures, presented to the conference M2S-HTSC, 25-30 May 2003, Rio de Janeir

Tetragonal to orthorhombic phase transition in SmFeAsO: a synchrotron powder diffraction investigation

The crystal structure of SmFeAsO has been investigated by means of Rietveld refinement of high resolution synchrotron powder diffraction data collected at 300 K and 100 K. The compound crystallizes in the tetragonal P4/nmm space group at 300 K and in the orthorhombic Cmma space group at 100 K; attempts to refine the low temperature data in the monoclinic P112/n space group diverged. On the basis of both resistive and magnetic analyses the tetragonal to orthorhombic phase transition can be located at T about 140 K.Comment: Submitted to: Superconductor Science and Technology PACS: 61.05.cp, 61.66.Fn, 74.10.+v, 74.62.Dh, 74.70.D

Role of heat and mechanical treatments in the fabrication of superconducting Ba0.6K0.4Fe2As2 ex-situ Powder-In-Tube tapes

Among the recently discovered Fe-based superconducting compounds, the (K,Ba)Fe2As2 phase is attracting large interest within the scientific community interested in conductor developments. In fact, after some years of development, critical current densities Jc of about 105 A/cm2 at fields up to more than 10 T have been obtained in powder in tube (PIT) processed wires and tapes. Here we explore the crucial points in the wire/tape fabrication by means of the ex-situ PIT method. We focus on scaling up processes which are crucial for the industrial fabrication. We analyzed the effects on the microstructure of the different heat and mechanical treatments. By an extensive microstructural analysis correlated with the transport properties we addressed the issues concerning the phase purity, the internal porosity and crack formation in the superconducting core region. Our best conductors with a filling factor of about 30 heat treated at 800 C exhibited Tc = 38 K the highest value measured in such kind of superconducting tape. The microstructure analysis shows clean and well connected grain boundaries but rather poor density: The measured Jc of about 3 x 10^4 A/cm2 in self-field is suppressed by less than a factor 7 at 7 T. Such not yet optimized Jc values can be accounted for by the reduced density while the moderate in-field suppression and a rather high n-factor confirm the high homogeneity and uniformity of these tapes

Coupling between 4f and itinerant electrons in SmFeAsO1-xFx (0.15 < x < 0.2) superconductors: an NMR study

$^{19}$F NMR measurements in SmFeAsO$_{1-x}$F$_x$, for $0.15\leq x\leq 0.2$, are presented. The nuclear spin-lattice relaxation rate $1/T_1$ increases upon cooling with a trend analogous to the one already observed in CeCu$_{5.2}$Au$_{0.8}$, a quasi two-dimensional heavy-fermion intermetallic compound with an antiferromagnetic ground-state. In particular, the behaviour of the relaxation rate either in SmFeAsO$_{1-x}$F$_x$ or in CeCu$_{5.2}$Au$_{0.8}$ can be described in the framework of the self-consistent renormalization theory for weakly itinerant electron systems. Remarkably, no effect of the superconducting transition on $^{19}$F $1/T_1$ is detected, a phenomenon which can hardly be explained within a single band model.Comment: 4 figure

Role of Dirac cones in magnetotransport properties of REFeAsO (RE=rare earth) oxypnictides

In this work we study the effect of the rare earth element in iron oxypnictides of composition REFeAsO (RE=rare earth). On one hand we carry out Density Functional Theory calculations of the band structure, which evidence the multiband character of these compounds and the presence of Dirac cones along the Y-{\Gamma} and Z-R directions of the reciprocal space. On the other hand, we explore transport behavior by means of resistivity, Hall resistance and magnetoresistance measurements, which confirm the dominant role of Dirac cones. By combining our theoretical and experimental approaches, we extract information on effective masses, scattering rates and Fermi velocities for different rare earth elements.Comment: 13 pages, 5 figures accepted for publication on European Journal of Physics

Superconducting phase fluctuations in SmFeAsO0.8_{0.8}F0.2_{0.2} from diamagnetism at low magnetic field above TcT_{c}

Superconducting fluctuations (SF) in SmFeAsO$_{0.8}$F$_{0.2}$ (characterized by superconducting transition temperature $T_{c} \simeq 52.3$ K) are investigated by means of isothermal high-resolution dc magnetization measurements. The diamagnetic response to magnetic fields up to 1 T above $T_{c}$ is similar to what previously reported for underdoped cuprate superconductors and it can be justified in terms of metastable superconducting islands at non-zero order parameter lacking of long-range coherence because of strong phase fluctuations. In the high-field regime ($H \gtrsim 1.5$ T) scaling arguments predicted on the basis of the Ginzburg-Landau theory of conventional SF are found to be applicable, at variance with what observed in the low-field regime. This fact enlightens that two different phenomena are simultaneously present in the fluctuating diamagnetism, namely the phase SF of novel character and the conventional SF. High magnetic fields (1.5 T $\lesssim H \ll H_{c2}$) are found to suppress the former while leaving unaltered the latter one.Comment: 7 pages, 5 figure

Effect of Ru susbstitution on atomic displacements in the layered SmFe_{1-x}Ru_xAsO_{0.85}F_{0.15} superconductor

The effect of Ru substitution on the local structure of layered SmFe$_{1-x}$Ru$_x$AsO$_{0.85}$F$_{0.15}$ superconductor has been studied by As $K$- and Sm $L_3$ - edges x-ray-absorption spectroscopy. The extended x-ray-absorption fine-structure measurements reveal distinct Fe-As and Ru-As bondlengths in the Ru substituted samples with the latter being $\sim$0.03 \AA\ longer. Local disorder induced by the Ru substitution is mainly confined to the FeAs layer while the SmO spacer layer sustains a relative order, consistent with the x-ray-absorption near-edge structure spectra. The results suggest that, in addition to the order/disorder in the active active iron-arsenide layer, its coupling to the rare-earth\textminus oxygen spacer layer needs to be considered for describing the electronic properties of these layered superconductors

Tuning topological disorder in MgB2_{2}

We carried out Raman measurements on neutron-irradiated and Al-doped MgB$_2$ samples. The irradiation-induced topological disorder causes an unexpected appearance of high frequency spectral structures, similar to those observed in lightly Al-doped samples. Our results show that disorder-induced violations of the selection rules are responsible for the modification of the Raman spectrum in both irradiated and Al-doped samples. Theoretical calculations of the phonon density of states support this hypothesis, and demonstrate that the high frequency structures arise mostly from contributions at ${\bf q}\not=0$ of the E$_{2g}$ phonon mode.Comment: 4 pages, 4 figure