509 research outputs found
Azimuthal instability of the radial thermocapillary flow around a hot bead trapped at the water-air interface
We investigate the radial thermocapillary flow driven by a laser-heated
microbead in partial wetting at the water-air interface. Particular attention
is paid to the evolution of the convective flow patterns surrounding the hot
sphere as the latter is increasingly heated. The flow morphology is nearly
axisymmetric at low laser power P. Increasing P leads to symmetry breaking with
the onset of counter-rotating vortex pairs. The boundary condition at the
interface, close to no-slip in the low-P regime, turns about stress-free
between the vortex pairs in the high-P regime. These observations strongly
support the view that surface-active impurities are inevitably adsorbed on the
water surface where they form an elastic layer. The onset of vortex pairs is
the signature of a hydrodynamic instability in the layer response to the
centrifugal forced flow. Interestingly, our study paves the way for the design
of active colloids able to achieve high-speed self-propulsion via vortex pair
generation at a liquid interface
Free energy of colloidal particles at the surface of sessile drops
The influence of finite system size on the free energy of a spherical
particle floating at the surface of a sessile droplet is studied both
analytically and numerically. In the special case that the contact angle at the
substrate equals a capillary analogue of the method of images is
applied in order to calculate small deformations of the droplet shape if an
external force is applied to the particle. The type of boundary conditions for
the droplet shape at the substrate determines the sign of the capillary
monopole associated with the image particle. Therefore, the free energy of the
particle, which is proportional to the interaction energy of the original
particle with its image, can be of either sign, too. The analytic solutions,
given by the Green's function of the capillary equation, are constructed such
that the condition of the forces acting on the droplet being balanced and of
the volume constraint are fulfilled. Besides the known phenomena of attraction
of a particle to a free contact line and repulsion from a pinned one, we
observe a local free energy minimum for the particle being located at the drop
apex or at an intermediate angle, respectively. This peculiarity can be traced
back to a non-monotonic behavior of the Green's function, which reflects the
interplay between the deformations of the droplet shape and the volume
constraint.Comment: 24 pages, 19 figure
Defect structures in nematic liquid crystals around charged particles
We numerically study the orientation deformations in nematic liquid crystals
around charged particles. We set up a Ginzburg-Landau theory with inhomogeneous
electric field. If the dielectric anisotropy varepsilon_1 is positive, Saturn
ring defects are formed around the particles. For varepsilon_1<0, novel "ansa"
defects appear, which are disclination lines with their ends on the particle
surface. We find unique defect structures around two charged particles. To
lower the free energy, oppositely charged particle pairs tend to be aligned in
the parallel direction for varepsilon_1>0 and in the perpendicular plane for
varepsilon_1<0 with respect to the background director . For identically
charged pairs the preferred directions for varepsilon_1>0 and varepsilon_1<0
are exchanged. We also examie competition between the charge-induced anchoring
and the short-range anchoring. If the short-range anchoring is sufficiently
strong, it can be effective in the vicinity of the surface, while the director
orientation is governed by the long-range electrostatic interaction far from
the surface.Comment: 10 papes, 12 figures, to appear in European Physical Journal
Identification of QTLs controlling gene expression networks defined a priori
BACKGROUND: Gene expression microarrays allow the quantification of transcript accumulation for many or all genes in a genome. This technology has been utilized for a range of investigations, from assessments of gene regulation in response to genetic or environmental fluctuation to global expression QTL (eQTL) analyses of natural variation. Current analysis techniques facilitate the statistical querying of individual genes to evaluate the significance of a change in response, also known as differential expression. Since genes are also known to respond as groups due to their membership in networks, effective approaches are needed to investigate transcriptome variation as related to gene network responses. RESULTS: We describe a statistical approach that is capable of assessing higher-order a priori defined gene network response, as measured by microarrays. This analysis detected significant network variation between two Arabidopsis thaliana accessions, Bay-0 and Shahdara. By extending this approach, we were able to identify eQTLs controlling network responses for 18 out of 20 a priori-defined gene networks in a recombinant inbred line population derived from accessions Bay-0 and Shahdara. CONCLUSION: This approach has the potential to be expanded to facilitate direct tests of the relationship between phenotypic trait and transcript genetic architecture. The use of a priori definitions for network eQTL identification has enormous potential for providing direction toward future eQTL analyses
Collective dynamics of colloids at fluid interfaces
The evolution of an initially prepared distribution of micron sized colloidal
particles, trapped at a fluid interface and under the action of their mutual
capillary attraction, is analyzed by using Brownian dynamics simulations. At a
separation \lambda\ given by the capillary length of typically 1 mm, the
distance dependence of this attraction exhibits a crossover from a logarithmic
decay, formally analogous to two-dimensional gravity, to an exponential decay.
We discuss in detail the adaption of a particle-mesh algorithm, as used in
cosmological simulations to study structure formation due to gravitational
collapse, to the present colloidal problem. These simulations confirm the
predictions, as far as available, of a mean-field theory developed previously
for this problem. The evolution is monitored by quantitative characteristics
which are particularly sensitive to the formation of highly inhomogeneous
structures. Upon increasing \lambda\ the dynamics show a smooth transition from
the spinodal decomposition expected for a simple fluid with short-ranged
attraction to the self-gravitational collapse scenario.Comment: 13 pages, 12 figures, revised, matches version accepted for
publication in the European Physical Journal
Natural Variation in Seed Very Long Chain Fatty Acid Content Is Controlled by a New Isoform of KCS18 in Arabidopsis thaliana
Abstract Oil from oleaginous seeds is mainly composed of triacylglycerols. Very long chain fatty acids (VLCFAs) are major constituents of triacylglycerols in many seed oils and represent valuable feedstock for industrial purposes. To identify genetic factors governing natural variability in VLCFA biosynthesis, a quantitative trait loci (QTL) analysis using a recombinant inbred line population derived from a cross between accessions Bay-0 and Shahdara was performed in Arabidopsis thaliana. Two fatty acid chain length ratio (CLR) QTL were identified, with one major locus, CLR.2, accounting for 77% of the observed phenotypic variation. A fine mapping and candidate gene approach showed that a key enzyme of the fatty acid elongation pathway, the b-ketoacyl-CoA synthase 18 (KCS18), was responsible for the CLR.2 QTL detected between Bay-0 and Shahdara. Association genetics and heterologous expression in yeast cells identified a single point mutation associated with an alteration of KCS18 activity, uncovering the molecular bases for the modulation of VLCFA content in these two natural populations of Arabidopsis. Identification of this kcs18 mutant with altered activity opens new perspectives for the modulation of oil composition in crop plants
Interaction and flocculation of spherical colloids wetted by a surface-induced corona of paranematic order
Particles dispersed in a liquid crystal above the nematic-isotropic phase
transition are wetted by a surface-induced corona of paranematic order. Such
coronas give rise to pronounced two-particle interactions. In this article, we
report details on the analytical and numerical study of these interactions
published recently [Phys. Rev. Lett. 86, 3915 (2001)]. We especially
demonstrate how for large particle separations the asymptotic form of a Yukawa
potential arises. We show that the Yukawa potential is a surprisingly good
description for the two-particle interactions down to distances of the order of
the nematic coherence length. Based on this fact, we extend earlier studies on
a temperature induced flocculation transition in electrostatically stabilized
colloidal dispersions [Phys. Rev. E 61, 2831 (2000)]. We employ the Yukawa
potential to establish a flocculation diagram for a much larger range of the
electrostatic parameters, namely the surface charge density and the Debye
screening length. As a new feature, a kinetically stabilized dispersion close
to the nematic-isotropic phase transition is found.Comment: Revtex v4.0, 16 pages, 12 Postscript figures. Accepted for
publication in Phys. Rev.
Nematic-Wetted Colloids in the Isotropic Phase: Pairwise Interaction, Biaxiality and Defects
We calculate the interaction between two spherical colloidal particles
embedded in the isotropic phase of a nematogenic liquid. The surface of the
particles induces wetting nematic coronas that mediate an elastic interaction.
In the weak wetting regime, we obtain exact results for the interaction energy
and the texture, showing that defects and biaxiality arise, although they are
not topologically required. We evidence rich behaviors, including the
possibility of reversible colloidal aggregation and dispersion. Complex
anisotropic self-assembled phases might be formed in dense suspensions.Comment: 4 pages, 6 figure
Defect structures and torque on an elongated colloidal particle immersed in a liquid crystal host
Combining molecular dynamics and Monte Carlo simulation we study defect
structures around an elongated colloidal particle embedded in a nematic liquid
crystal host. By studying nematic ordering near the particle and the
disclination core region we are able to examine the defect core structure and
the difference between two simulation techniques. In addition, we also study
the torque on a particle tilted with respect to the director, and modification
of this torque when the particle is close to the cell wall
Simulating Particle Dispersions in Nematic Liquid-Crystal Solvents
A new method is presented for mesoscopic simulations of particle dispersions
in nematic liquid crystal solvents. It allows efficient first-principle
simulations of the dispersions involving many particles with many-body
interactions mediated by the solvents. A simple demonstration is shown for the
aggregation process of a two dimentional dispersion.Comment: 5 pages, 5 figure
- …