938 research outputs found

    Dynamical Hierarchies

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    Atomic Layer Deposition-Based Synthesis of Photoactive TiO2 Nanoparticle Chains by Using Carbon Nanotubes as Sacrificial Templates

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    Highly ordered and self supported anatase TiO2 nanoparticle chains were fabricated by calcining conformally TiO2 coated multi-walled carbon nanotubes (MWCNTs). During annealing, the thin tubular TiO2 coating that was deposited onto the MWCNTs by atomic layer deposition (ALD) was transformed into chains of TiO2 nanoparticles (~12 nm diameter) with an ultrahigh surface area (137 cm2 per cm2 of substrate), while at the same time the carbon from the MWCNTs was removed. Photocatalytic tests on the degradation of acetaldehyde proved that these forests of TiO2 nanoparticle chains are highly photo active under UV light because of their well crystallized anatase phase

    A new regional climate model for POLAR-CORDEX : evaluation of a 30-year hindcast with COSMO-CLM2 over Antarctica

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    Continent-wide climate information over the Antarctic Ice Sheet (AIS) is important to obtain accurate information of present climate and reduce uncertainties of the ice sheet mass balance response and resulting global sea level rise to future climate change. In this study, the COSMO-CLM2 Regional Climate Model is applied over the AIS and adapted for the specific meteorological and climatological conditions of the region. A 30-year hindcast was performed and evaluated against observational records consisting of long-term ground-based meteorological observations, automatic weather stations, radiosoundings, satellite records, stake measurements and ice cores. Reasonable agreement regarding the surface and upper-air climate is achieved by the COSMO-CLM2 model, comparable to the performance of other state-of-the-art climate models over the AIS. Meteorological variability of the surface climate is adequately simulated, and biases in the radiation and surface mass balance are small. The presented model therefore contributes as a new member to the COordinated Regional Downscaling EXperiment project over the AIS (POLAR-CORDEX) and the CORDEX-CORE initiative

    Binary properties of CH and Carbon-Enhanced Metal-Poor stars

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    The HERMES spectrograph installed on the 1.2-m Mercator telescope has been used to monitor the radial velocity of 13 low-metallicity carbon stars, among which 7 Carbon-Enhanced Metal-Poor (CEMP) stars and 6 CH stars. All stars but one show clear evidence for binarity. New orbits are obtained for 8 systems. The sample covers an extended range in orbital periods, extending from 3.4 d (for the dwarf carbon star HE 0024-2523) to about 54 yr (for the CH star HD 26, the longest known among barium, CH and extrinsic S stars). Three systems exhibit low-amplitude velocity variations with periods close to 1 yr superimposed on a long-term trend. In the absence of an accurate photometric monitoring of these systems, it is not clear yet whether these variations are the signature of a very low-mass companion, or of regular envelope pulsations. The period - eccentricity (P - e) diagram for the 40 low-metallicity carbon stars with orbits now available shows no difference between CH and CEMP-s stars (the latter corresponding to those CEMP stars enriched in s-process elements, as are CH stars). We suggest that they must be considered as one and the same family and that their different names only stem from historical reasons. Indeed, these two families have as well very similar mass-function distributions, corresponding to companions with masses in the range 0.5 - 0.7 Msun, indicative of white-dwarf companions, adopting 0.8 - 0.9 Msun for the primary component. This result confirms that CH and CEMP-s stars obey the same mass-transfer scenario as their higher-metallicity analogs, the barium stars. The P - e diagrams of barium, CH and CEMP-s stars are indeed very similar. They reveal two different groups of systems: one with short orbital periods (P < 1000 d) and mostly circular or almost circular orbits, and another with longer-period and eccentric (e > 0.1) orbits.Comment: Accepted in Astronomy & Astrophysic

    Centralized vs. Personalized Commitments and their influence on Cooperation in Group Interactions

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    Before engaging in a group venture agents may seekcommitments from other members in the group and,based on the level of participation (i.e. the numberof actually committed participants), decide whether itis worth joining the venture. Alternatively, agents candelegate this costly process to a (beneficent or non-costly) third-party, who helps seek commitments fromthe agents. Using methods from Evolutionary GameTheory, this paper shows that, in the context of PublicGoods Game, much higher levels of cooperationcan be achieved through such centralized commitmentmanagement. It provides a more efficient mechanismfor dealing with commitment free-riders, those who arenot willing to bear the cost of arranging commitmentswhilst enjoying the benefits provided by the paying commitment proposers.We show also that the participationlevel plays a crucial role in the decision of whetheran agreement should be formed; namely, it needs tobe more strict in the centralized system for the agreementto be formed; however, once it is done right, it ismuch more beneficial in terms of the level of cooperationas well as the attainable social welfare. In short, ouranalysis provides important insights for the design ofmulti-agent systems that rely on commitments to monitoragents’ cooperative behavior

    From vocational training to education: the development of a no-frontiers education policy for Europe?

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    This article focuses on developments towards an EU educational policy. Education was not included as one of the Community competencies in the Treaty of Rome. The first half of the article analyses the way that the European Court of Justice and the Commission of the European Communities between them managed to develop a series of substantial Community programmes out of Article 128 on vocational training. The second half of the article discusses educational developments in the community following the Treaty on European Union and the Treaty of Amsterdam. Whilst the legal competence of the community now includes education, the author's argument is that the inclusion of an educational competence will not result in further developments to mirror those in the years before the Treaty on Europe</p
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