High Temperature Superconductivity: the explanation

Soon after the discovery of the first high temperature superconductor by Georg Bednorz and Alex Mueller in 1986 the late Sir Nevill Mott answering his own question "Is there an explanation?" [Nature v 327 (1987) 185] expressed a view that the Bose-Einstein condensation (BEC) of small bipolarons, predicted by us in 1981, could be the one. Several authors then contemplated BEC of real space tightly bound pairs, but with a purely electronic mechanism of pairing rather than with the electron-phonon interaction (EPI). However, a number of other researchers criticized the bipolaron (or any real-space pairing) scenario as incompatible with some angle-resolved photoemission spectra (ARPES), with experimentally determined effective masses of carriers and unconventional symmetry of the superconducting order parameter in cuprates. Since then the controversial issue of whether the electron-phonon interaction (EPI) is crucial for high-temperature superconductivity or weak and inessential has been one of the most challenging problems of contemporary condensed matter physics. Here I outline some developments in the bipolaron theory suggesting that the true origin of high-temperature superconductivity is found in a proper combination of strong electron-electron correlations with a significant finite-range (Froehlich) EPI, and that the theory is fully compatible with the key experiments.Comment: 8 pages, 2 figures, invited comment to Physica Script

Unconventional superconducting pairing by conventional phonons

The common wisdom that the phonon mechanism of electron pairing in the weak-coupling Bardeen-Cooper-Schrieffer (BCS) superconductors leads to conventional s-wave Cooper pairs is revised. An inevitable anisotropy of sound velocity in crystals makes the phonon-mediated attraction of electrons non-local in space providing unconventional Cooper pairs with a nonzero orbital momentum in a wide range of electron densities. As a result of this anisotropy quasi-two dimensional charge carriers undergo a quantum phase transition from an unconventional d-wave superconducting state to a conventional s-wave superconductor with more carriers per unit cell. In the opposite strong-coupling regime rotational symmetry breaking appears as a result of a reduced Coulomb repulsion between unconventional bipolarons dismissing thereby some constraints on unconventional pairing in the Bose-Einstein condensation (BEC) limit. The conventional phonons, and not superexchange, are shown to be responsible for the d-wave symmetry of cuprate superconductors, where the on-site Coulomb repulsion is large.Comment: 4 pages, 4 figures, more references adde

Vortex matter in the charged Bose liquid at absolute zero

The Gross-Pitaevskii-type equation is solved for the charge Bose liquid in the external magnetic field at zero temperature. There is a vortex lattice with locally broken charge neutrality. The boson density is modulated in real space and each vortex is charged. Remarkably, there is no upper critical field at zero temperature, so the density of single flux-quantum vortices monotonously increases with the magnetic field up to B=infinity and no indication of a phase transition. The size of each vortex core decreases as about 1/sqrt(B) keeping the system globally charge neutral. If bosons are composed of two fermions, a phase transition to a spin-polarized Fermi liquid at some magnetic field larger than the pair-breaking field is predicted.Comment: 4 pages, 4 figures, references update

Parameter-free expression for superconducting Tc in cuprates

A parameter-free expression for the superconducting critical temperature of layered cuprates is derived which allows us to express Tc in terms of experimentally measured parameters. It yields Tc values observed in about 30 lanthanum, yttrium and mercury-based samples for different levels of doping. This remarkable agreement with the experiment as well as the unusual critical behaviour and the normal-state gap indicate that many cuprates are close to the Bose-Einstein condensation regime.Comment: 5 pages, 2 figures. Will be published in Physical Review

Superlight small bipolarons from realistic long-range Coulomb and Fr\"ohlich interactions

We report analytical and numerical results on the two-particle states of the polaronic t-Jp model derived recently with realistic Coulomb and electron-phonon (Frohlich) interactions in doped polar insulators. Eigenstates and eigenvalues are calculated for two different geometries. Our results show that the ground state is a bipolaronic singlet, made up of two polarons. The bipolaron size increases with increasing ratio of the polaron hopping integral t to the exchange interaction Jp but remains small compared to the system size in the whole range 0<t/Jp<1. Furthermore, the model exhibits a phase transition to a superconducting state with a critical temperature well in excess of 100K. In the range t/Jp<1, there are distinct charge and spin gaps opening in the density of states, specific heat, and magnetic susceptibility well above Tc.Comment: Calculation section and discussion of gap have been updated. Revised calculations now enhance the predicted T_c in our model to over 200 K at large hoppin

Coherent `ab' and `c' transport theory of high-TcT_{c} cuprates

We propose a microscopic theory of the `$c$'-axis and in-plane transport of copper oxides based on the bipolaron theory and the Boltzmann kinetics. The fundamental relationship between the anisotropy and the spin susceptibility is derived, $\rho_{c}(T,x)/\rho_{ab}(T,x)\sim x/\sqrt{T}\chi_{s}(T,x)$. The temperature $(T)$ and doping $(x)$ dependence of the in-plane, $\rho_{ab}$ and out-of-plane, $\rho_{c}$ resistivity and the spin susceptibility, $\chi_{s}$ are found in a remarkable agreement with the experimental data in underdoped, optimally and overdoped $La_{2-x}Sr_{x}CuO_{4}$ for the entire temperature regime from $T_{c}$ up to $800K$. The normal state gap is explained and its doping and temperature dependence is clarified.Comment: 12 pages, Latex, 3 figures available upon reques

Towards Bose-Einstein Condensation of Electron Pairs: Role of Schwinger Bosons

It can be shown that the bosonic degree of freedom of the tightly bound on-site electron pairs could be separated as Schwinger bosons. This is implemented by projecting the whole Hilbert space into the Hilbert subspace spanned by states of two kinds of Schwinger bosons (to be called binon and vacanon) subject to a constraint that these two kinds of bosonic quasiparticles cannot occupy the same site. We argue that a binon is actually a kind of quantum fluctuations of electron pairs, and a vacanon corresponds to a vacant state. These two bosonic quasiparticles may be responsible for the Bose-Einstein condensation (BEC) of the system associated with electron pairs. These concepts are also applied to the attractive Hubbard model with strong coupling, showing that it is quite useful. The relevance of the present arguments to the existing theories associated with the BEC of electron pairs is briefly commented.Comment: Revtex, one figur

A Case of Fatal Bleeding from Acute Varicose Leg Ulcer: Clinico-pathological Characteristics

AbstractVaricosity of the superficial leg veins is a common human pathology leading to a number of serious complications. Acute severe bleeding is one of the rarest occurrences; however, it could cause death within minutes. This article describes a case of a small (4 mm) acute varicose ulcer in the right medial calf region of a 55-year-old woman that caused fatal exsanguination. The specific clinico-pathological features and possible pathogenesis of this condition are briefly reviewed. The present case along with several others described in the literature suggests that even the small, ‘cosmetic’ leg varicosities are indeed dangerous and require proper and timely management