52 research outputs found

    A Dystopic or Utopic Future?

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    de Castro Neto, M., & de Melo Cartaxo, T. (2021). Algorithmic Cities: A Dystopic or Utopic Future? In M. I. A. Ferreira (Ed.), How Smart Is Your City?: Technological Innovation, Ethics and Inclusiveness (Vol. 98, pp. 59-73). (Intelligent Systems, Control and Automation: Science and Engineering; Vol. 98). Springer Science and Business Media B.V.. https://doi.org/10.1007/978-3-030-56926-6_6Cities of today face a digital transformation process, leading to a new reality where urban space is taking advantage of information and communication technologies and data science to answer present and future challenges, namely to become more efficient in services and infrastructures management in order to deliver increased quality of life to the people who live, work or visit the city, and addressing at the same time the problems of climate change. This new reality is leveraged by big data produced by the cities Internet of everything (as interconnected systems, sensors and people), information management and data science capabilities, which allow us to measure and describe what happens, predict what can happen, and prescribe what could be the course of actions bringing policy making to a fact-based environment, which had never been possible before. In this work, we will address the opportunities and challenges of this paradigm shift that is leading to the city as a platform reality that supports what we can call the algorithmic city where it is up to us to decide if this will be a dystopic or utopic future for the citizen.authorsversionpublishe

    What is being done to deter ambush marketing? Are these attempts working?

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    This paper examines industry responses in Australasia and Europe to the growing practice of ambush marketing, to establish whether the measures that have been put in place to deter the practice have indeed prevented the ‘ambush’ effect, whereby audiences associate non-sponsoring organisations with particular sporting events. Although some of these measures may be more effective than others in blocking ambush attempts, they also come with potentially negative consequences for event sponsors

    Residue curve maps for reactive distillation systems with liquid-phase splitting

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    A model has been developed to study the effects of chemical kinetics on the residue curve maps (RCM) for reactive distillation systems with liquid phase splitting. In the model, chemical reaction can occur in both or only one of the two liquid phases. The heating policy V/V-0 = H/H-0 is applied so that the kinetic effect can be described by a single parameter, the Damkohler number Da. The effects of reaction kinetics on pseudohomogeneous and heterogeneous mixtures have been compared. The properties of their RCMs are the same outside, but are fully different inside the liquid-liquid (L-L) region if they have different chemical equilibrium curves. Inside the L-L region, the chemical equilibrium curve coincides to a unique reactive liquid-liquid tie line in case that the pseudohomogeneous chemical equilibrium curve intersects with the L-L envelope. When the reaction occurs in only one of the two liquid phases, the residue curves inside the L-L region are strongly affected by the L-L. envelope, especially at high Da. In the present paper, first an illustrative arbitrary reaction system, and then the reaction of cyclohexene with water to cyclohexanol are analysed with respect to their RCMs. (C) 2002 Elsevier Science Ltd. All rights reserved

    Reaktive Destillationssysteme

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    Catalytic Distillation Technology Applied to Ether Production

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    Reactive distillation is an integrated multifunctional reactor where a chemical reaction and distillation occur simultaneously in a single unit operation apparatus. The reaction can be either homogeneously or heterogeneously catalysed. The subset of heterogeneously catalysed reactive distillation processes are commonly referred to as catalytic distillation processes. The motives, limitations and disadvantages are discussed in the chapter. The kinetic and thermodynamic aspects of ether production with reactive distillation are discussed as well. The various catalytic packings as random packings, catalytic distillation trays and catalytic bales are presented. Finally the simulation, design and commercial processes are discussed

    Residue curve maps for reactive distillation systems with liquid-phase splitting

    No full text
    A model has been developed to study the effects of chemical kinetics on the residue curve maps (RCM) for reactive distillation systems with liquid phase splitting. In the model, chemical reaction can occur in both or only one of the two liquid phases. The heating policy V/V-0 = H/H-0 is applied so that the kinetic effect can be described by a single parameter, the Damkohler number Da. The effects of reaction kinetics on pseudohomogeneous and heterogeneous mixtures have been compared. The properties of their RCMs are the same outside, but are fully different inside the liquid-liquid (L-L) region if they have different chemical equilibrium curves. Inside the L-L region, the chemical equilibrium curve coincides to a unique reactive liquid-liquid tie line in case that the pseudohomogeneous chemical equilibrium curve intersects with the L-L envelope. When the reaction occurs in only one of the two liquid phases, the residue curves inside the L-L region are strongly affected by the L-L. envelope, especially at high Da. In the present paper, first an illustrative arbitrary reaction system, and then the reaction of cyclohexene with water to cyclohexanol are analysed with respect to their RCMs. (C) 2002 Elsevier Science Ltd. All rights reserved
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