642 research outputs found
Mg-Al Sapphirine- and Ca-Al Hibonite-bearing Granulite Xenoliths from the Chyulu Hills Volcanic Field, Kenya
Basanites of the Chyulu Hills (Kenya Rift) contain mafic Mg-Al and Ca-Al granulite xenoliths. Their protoliths are interpreted as troctolitic cumulates; however, the original mineral assemblages were almost completely transformed by subsolidus reactions. Mg-Al granulites contain the minerals spinel, sapphirine, sillimanite, plagioclase, corundum, clinopyroxene, orthopyroxene and garnet, whereas Ca-Al granulites are characterized by hibonite, spinel, sapphirine, mullite, sillimanite, plagioclase, quartz, clinopyroxene, corundum, and garnet. In the Mg-Al granulites, the first generation of orthopyroxene and some spinel may be of igneous origin. In the Ca-Al granulites, hibonite (and possibly some spinel) are the earliest, possibly igneous, minerals in the crystallization sequence. Most pyroxene, spinel and corundum in Mg-Al and Ca-Al granulites formed by subsolidus reactions. The qualitative P-T path derived from metamorphic reactions corresponds to subsolidus cooling, probably accompanied, or followed by, compression. Final equilibration was achieved at T ≈ 600-740°C and P <8 kbar, in the stability field of sillimanite. The early coexistence of corundum and pyroxenes (± spinel), as well as the association of sillimanite and sapphirine with clinopyroxene and the presence of hibonite, makes both types of granulite rare. The Ca-Al hibonite-bearing granulites are unique. Both types enlarge the spectrum of known Ca-Al-Mg-rich granulites worldwid
Contribution à l'étude de l'effet de charge sur échantillon isolant en spectroscopie de photoélectrons (XPS)
Li, B and Be Contents of Harzburgites from the Dramala Complex (Pindos Ophiolite, Greece): Evidence for a MOR-type Mantle in a Supra-subduction Zone Environment
The Pindos ophiolite represents oceanic lithosphere obducted during the Jurassic. The Dramala mantle section mainly consists of highly depleted spinel harzburgite and minor plagioclase-bearing harzburgite. Textural observations and major element compositions of minerals indicate that the harzburgites experienced impregnation by a mafic, depleted melt and subsequent high-temperature (high-T) hydration and cooling (>750°C) forming pargasite and edenitic hornblende. During further cooling (from ≥ 350-400°C to < 100°C), talc + tremolite ± serpentine ± olivine, serpentine + magnetite, and finally plagioclase alteration phases formed. To test the hypothesis of a supra-subduction zone origin for the Dramala mantle, we measured Li, B and Be contents of minerals by secondary ion mass spectrometry. Whole-rock contents were measured using inductively coupled plasma-mass spectrometry and prompt gamma neutron activation analysis. We observe low Li and B contents of primary minerals (olivine, orthopyroxene, clinopyroxene) consistent with values for unmetasomatized mantle minerals; only Li contents of clinopyroxene (up to 3·7 μg/g) are slightly elevated. The bulk Li contents (0·5-1·1 μg/g) are in the upper range of values for unmetasomatized mantle, whereas B contents (<0·04-1·1 μg/g) are variable and slightly elevated compared with the unmetasomatized mantle as a result of serpentinization. Beryllium abundances in all minerals are very low (<0·005 μg/g), except for pargasite, where a maximum Be content of 0·012 μg/g was measured. The selective addition of Li to clinopyroxene can be related to the interaction with a depleted melt, and/or to partitioning of Li into clinopyroxene upon cooling. During high-T hydration and cooling, the fluid calculated to be in equilibrium with the pargasite or edenitic hornblende (based on Li, Be and B) could have been reaction-modified seawater. Low-T hydration may have led to a very minor increase in bulk B content of most samples and to the formation of serpentine with highly variable B contents (0·1-28 μg/g). Low-T hydration decreased the Li content of orthopyroxene, and Li was probably leached from some samples. The lack of correlation between degree of serpentinization and bulk B contents as well as the presence of high- and low-B serpentine can be explained by low fluid-rock ratios, decreasing T during serpentinization and lack of equilibrium as a result of fast obduction-exhumation. The low light-element contents of primary minerals and whole-rock samples clearly argue against a supra-subduction zone (SSZ) origin of the Dramala mantle section, and against the previous hypothesis of hydrous melting of the Pindos mantle above a subduction zone. We therefore conclude that the Dramala harzburgites represent a mid-ocean ridge (MOR)-type mantle, and not an SSZ-type mantle, juxtaposed with MOR-type and SSZ-type oceanic crust, either in a back-arc or in an intra-oceanic subduction zone settin
Seizing the Future: Why Some Native Nations Do and Others Don't
This study examines the question of why is it that some Native nations seize upon the nation building strategy and take effective control of their futures while others do not. We find that foundational change in a community arises when the external and internal conditions a people face interact with their interpretations of their situation, producing a new, shared "story" of what is possible, and how it can be achieved. The keys to changing a community's "story" are found in proactive decisions to alter internal and external situations, acquire concrete knowledge of the feasible, build on the community's cultural assets, and exercise leadership—especially in educating the people in a new vision.
Similarity and contrasts between thermodynamic properties at the critical point of liquid alkali metals and of electron-hole droplets
The recent experimental study by means of time-resolved luminescence
measurements of an electron-hole liquid (EHL) in diamond by Shimano et al.
[Phys. Rev. Lett. 88 (2002) 057404] prompts us to compare and contrast critical
temperature T_c and critical density n_c relations in liquid alkali metals with
those in electron-hole liquids. The conclusion drawn is that these systems have
similarities with regard to critical properties. In both cases the critical
temperature is related to the cube root of the critical density. The existence
of this relation is traced to Coulomb interactions and to systematic trends in
the dielectric constant of the electron-hole systems. Finally a brief
comparison between the alkalis and EHLs of the critical values for the
compressibility ratio Z_c is also given
A solar disinfection water treatment system for remote communities
Abstract not availablePeter Kalt, Cristian Birzer, Harrison Evans, Anthony Liew, Mark Padovan, Michael Watchma
Ab initio and nuclear inelastic scattering studies of FeSi/GaAs heterostructures
The structure and dynamical properties of the FeSi/GaAs(001) interface
are investigated by density functional theory and nuclear inelastic scattering
measurements. The stability of four different atomic configurations of the
FeSi/GaAs multilayers is analyzed by calculating the formation energies and
phonon dispersion curves. The differences in charge density, magnetization, and
electronic density of states between the configurations are examined. Our
calculations unveil that magnetic moments of the Fe atoms tend to align in a
plane parallel to the interface, along the [110] direction of the FeSi
crystallographic unit cell. In some configurations, the spin polarization of
interface layers is larger than that of bulk FeSi. The effect of the
interface on element-specific and layer-resolved phonon density of states is
discussed. The Fe-partial phonon density of states measured for the FeSi
layer thickness of three monolayers is compared with theoretical results
obtained for each interface atomic configuration. The best agreement is found
for one of the configurations with a mixed Fe-Si interface layer, which
reproduces the anomalous enhancement of the phonon density of states below 10
meVComment: 14 pages, 9 figures, 4 table
Optical properties of (AlxGa1-x)(0.52)In0.48P at the crossover from a direct-gap to an indirect-gap semiconductor
The optical properties and the dynamics of excitons and the electron-hole plasma have been studied in disordered (AlxGa1−x)0.52In0.48P near to the direct-to-indirect band gap crossover. In particular we have investigated three epitaxial layers grown by solid-source molecular beam epitaxy with varying Al content x. Two of them have compositions in the immediate vicinity of the crossover point, the other is assigned to the indirect-gap regime. Both direct and indirect recombination processes contribute to the photon emission from the material. Since the relative importance of the different recombination processes depends strongly on temperature, excitation intensity, and excitation pulse duration, the processes can be identified by changing these parameters. As a result, we can determine the relative alignment of the conduction band minima and the distribution of the electrons among them. At high excitation levels the two crossover samples show stimulated emission at a photon energy of ∼2.29 eV, i.e., in the green spectral range. Using the variable stripe length method, we find an optical gain of up to ∼600 cm−1 at excitation levels of ∼350 kW/cm2.Stimulated emission involves direct recombination. This conclusion is reached from the experiments and from line-shape modeling, including a self-consistent treatment of populations and renormalization of the conduction band minima
Palladium-catalysed synthesis of arylnaphthoquinones as antiprotozoal and antimycobacterial agents
Malaria and tuberculosis are still among the leading causes of death in low-income countries. The 1,4-naphthoquinone (NQ) scaffold can be found in a variety of anti-infective agents. Herein, we report an optimised, high yield process for the preparation of various 2-arylnaphthoquinones by a palladium-catalysed Suzuki reaction. All synthesised compounds were evaluated for their in-vitro antiprotozoal and antimycobacterial activity. Antiprotozoal activity was assessed against Plasmodium falciparum (P.f.) NF54 and Trypanosoma brucei rhodesiense (T.b.r.) STIB900, and antimycobacterial activity against Mycobacterium smegmatis (M.s.) mc(2) 155. Substitution with pyridine and pyrimidine rings significantly increased antiplasmodial potency of our compounds. The 2-aryl-NQs exhibited trypanocidal activity in the nM range with a very favourable selectivity profile. (Pseudo)halogenated aryl-NQs were found to have a pronounced effect indicating inhibition of mycobacterial efflux pumps. Cytotoxicity of all compounds towards L6 cells was evaluated and the respective selectivity indices (SI) were calculated. In addition, the physicochemical parameters of the synthesised compounds were discussed
Design, realization and test of C-band accelerating structures for the SPARC_LAB linac energy upgrade
- …