Towards storage-stable high-content recycled tyre rubber modified bitumen

The addition of crumb rubber particles as bitumen modifier can be currently considered as a well-established alternative to conventional polymers for bitumen modification. However, Recycle Tyre Rubber (RTR) modified binders still present drawbacks such as poor mix workability and hot storage stability. Within this study the authors try unlocking the full potential of devulcanised tyre rubber-heavy oils blend, named Liquid Rubber (LR), by exploring the possibility of tailoring recycled polymer modified bitumen with unconventional high-content of RTR and designed to overcome the above mentioned technological problems of RTR modified bitumen while keeping its advantages. Results show that LR-bitumen blends incorporating up to 30% RTR in weight of total binder clearly improves useful temperature interval of base bitumen by maintaining solubility values allowing them to be considered stable at hot-storage temperature. Furthermore, the LR modifier allows reducing usual manufacture temperatures up to 30 °C by providing superior low and intermediate temperature rheology, however high service temperature properties are improved only at low strain

Evaluation of bio-materials’ rejuvenating effect on binders for high-reclaimed asphalt content mixtures

The interest in using bio-materials in pavement engineering has grown significantly over the last decades due to environmental concerns about the use of non-recoverable natural resources. In this paper, bio-materials are used together with Reclaimed Asphalt (RA) to restore some of the properties of the aged bitumen present in mixtures with high RA content. For this purpose, two bio-materials are studied and compared to conventional and polymer modified bitumens. Blends of these materials with RA bitumen were produced and studied to simulate a 50% RA mixture. The rejuvenating effect of the two bio-materials on RA has been assessed and compared with the effect of the conventional binders. Apparent Molecular Weight Distribution of the samples (obtained by the ?-method) and different rheological parameters were used for this purpose. Results revealed the power of bio-materials to rejuvenate RA bitumen, showing their capability to be used as fresh binders in high-RA content mixtures

Evaluación del comportamiento mecánico de mezclas asfálticas templadas con 100 % de material reciclado

The use of Half Warm Mixes with high Reclaimed Asphalt content (HWMRA) has the potential to generate significant environmental advantages such as the reduction in consumption of natural resources and the emission of gases into the atmosphere. This paper therefore focuses on demonstrating the viability of using these types of mixes in wearing courses. For this purpose, an HWMRA with 70 % and 100 % Reclaimed Asphalt Pavement (RAP) and emulsion were designed in the laboratory. The performance of the mixes was then assessed and compared with that of conventional Hot Mix Asphalt. In a second stage, the mixes were manufactured in-plant, and laid and compacted in an Accelerated Pavement Test track. The cores were then extracted and tested for stiffness modulus and resistance to fatigue. The results from the tests conducted with both the laboratory specimens and the cores showed that the performance of HWMRA is comparable to that of HMA. These findings encourage greater confidence in promoting the use of these types of sustainable asphalt mixes.La utilización de mezclas asfálticas templadas con alto contenido de asfalto reciclado (HWMRA) conlleva ventajas medioambientales como la reducción del consumo de recursos naturales y la emisión de gases a la atmósfera. Este artículo se centra en mostrar la viabilidad de este tipo de mezclas para capas de rodadura. Para ello, se diseñaron mezclas HWMRA con 70 % y 100 % de asfalto reciclado en el laboratorio y se evaluó y comparó su comportamiento con una mezcla caliente convencional. En una segunda etapa, las mezclas fueron fabricadas en planta, extendidas y compactadas en una pista de ensayo acelerado de pavimentos. A continuación, se extrajeron testigos y se ensayaron para conocer su módulo de rigidez y resistencia a fatiga. Tanto los resultados de laboratorio como tras la fabricación en planta y puesta en obra mostraron que el comportamiento de mezclas HWMRA es comparable al de mezclas calientes convencionales. Dicha conclusión puede aportar confianza a este tipo de mezclas sostenibles promoviendo su mayor utilización

Comparación del efecto de la concentración de polvo de neumático reciclado y polímeros en el comportamiento de ligantes para mezclas bituminosas

Crumb rubber modified binders are environmental-friendly alternatives to polymer modified bitumens in asphalt mixtures. This paper compares the performance of both types of binders with different modifier contents. Six binders were characterised by conventional tests and analysed using the UCL method. This method evaluates different properties of binders regarding their role in asphalt mixtures (cohesion, water and thermal sensitivity and resistance to ageing). Results showed that i) crumb rubber concentration has to be higher than that of SBS-polymers in order to obtain a similar performance to that of SBS-polymer modified bitumen; ii) crumb rubber modified binders are more stable than SBS-polymer modified binders in terms of modifier concentration; iii) crumb rubber modified binders exhibited less water sensitivity and similar thermal and ageing susceptibility to SBS-polymer modified binders; iv) linear relationships have been found between modifier concentration and the properties studied for both kind of binders.Los betunes modificados con polvo de neumático (PN) son alternativas ambientalmente sostenibles a los betunes modificados con polímeros. Este artículo compara el comportamiento de ambos tipos de betunes con varios contenidos de modificador. Para ello, se caracterizaron seis betunes mediante ensayos convencionales y método UCL. Este método evalúa propiedades de ligantes para su uso en mezclas bituminosas (cohesión, sensibilidad al agua, térmica y al envejecimiento). Los resultados muestran que i) la concentración de PN ha de ser más elevada que la de polímeros para obtener comportamiento semejante; ii) los betunes con PN son más estables ante cambios en la concentración de modificador que los betunes con polímeros; iii) los betunes con PN presentan menor sensibilidad al agua y equivalente susceptibilidad térmica y al envejecimiento que los betunes con polímeros; iv) se encontraron buenos ajustes lineales entre la concentración de modificadores y la evolución de las propiedades estudiadas

NON-PETROLEUM-BASED BINDERS FOR PAVING APPLICATIONS: RHEOLOGICAL AND CHEMICAL INVESTIGATION ON AGEING EFFECTS

The massive exploitation of non-renewable natural resources which has taken place in the last decade has led to significant global environmental concerns. In such a context, the use of non-petroleum-based binders for the construction of bound layers of flexible pavements can represent an effective solution to limit crude oil depletion. The research work presented in this paper focused on the effects of ageing on the rheological and chemical characteristics of a non-bituminous binder, indicated in the study as a “biobinder”, and a traditional neat bitumen selected as a reference material. Binders were analyzed in four ageing conditions obtained by making use of the Rolling Thin Film Oven and of the Pressure Ageing Vessel. Rheological behaviour of binders was investigated by means of oscillatory tests carried out in a wide range of temperatures and frequencies with a dynamic shear rheometer. Chemical structure was explored via Thin Layer Chromatographic analyses and Fourier Transform Infrared Spectroscopy. The experimental work demonstrated that mechanisms of ageing which are involved in biobinders completely differ from those experienced by petroleum-based binders. Concerns were expressed with respect to the applicability to non-conventional binders of currently available ageing techniques and of chemical characterization methods

Simulating plant produced material in the laboratory to replicate rheological and fatigue properties

As part of an effort by agencies and industry to move towards performance-based design to evaluate mixtures in the laboratory at a smaller scale before moving to full scale operation, laboratory protocols exist to simulate the aging that occurs as a material is produced. However, recent research has shown that these existing protocols may not accurately represent the changes a material experiences in a plant. Moreover, due to the focus of previous studies on the ability of the current method to replicate mixture characteristics and performance in an undamaged state, there is a lack of information as it relates to the damaged state. This paper presents a concise description of a study undertaken on a particular mixture to evaluate the differences in the behaviour of a standard asphalt concrete mixture produced in the laboratory and in the plant to assess the anticipated field performance at the mixture design stage. The results, in terms of the rheological properties of binders extracted and recovered from laboratory and plant produced mixtures as well as rheological, repeated cyclic fatigue, and cracking performance evaluation of the asphalt mixtures, have shown the ability of a short-term oven aging protocol to replicate plant produced material in the laboratory

Toward Non-Petroleum-Derived Asphalt Mixes: Using Biobinders for High-Modulus Asphalt Mixes with High Reclaimed Asphalt Content

The concept of biobinders has been recently developed to refer to binders for asphalt mixtures that contain any bio-renewable materials. In this sense, there exist different types of biobinders with diverse natures and their use is still not wide spread also due to the uncertainties about their performance. Therefore, as a first step, every biobinder should be characterized to provide confidence for its use. Secondly, a way to increase the use and acceptance of biobinders is to use these biobinders in Reclaimed Asphalt (RA) mixtures replacing the need for petroleum-derived bituminous binders. In this manner, asphalt mixtures performance can benefit from the bitumen already present in RA while the use of new bitumen is avoided. Within this framework, this paper shows: (1) the characterization of two biobinders to be used as fresh binders in high-RA content mixtures; (2) their blend design with a aged RA binder to assess the feasibility of producing high- RA content mixtures; (3) biobinders and RA blends’ rheological evaluation; and (4) the rheological characterization of 50% RA mixtures manufactured with the biobinders. The results show the importance of performing a blend design before high content RA asphalt mixtures manufacturing as well as the suitability of biobinders to be used as fresh binders in recycled asphalt mixtures

A new procedure to determine the rheological properties of RAP binder and corresponding bituminous blends

In this paper, a new and simple approach to estimate the rheological properties of Reclaimed Asphalt Pavement (RAP) binder is proposed to overcome the limitations of the conventional extraction procedure. This method is based on Dynamic Shear Rheometer tests performed on mortars composed of RAP fine fraction and virgin binder, together with a new back-calculation solution. The properties of the bitumi- nous blends of virgin and RAP binders are obtained with a modified Nielsen model. The Voigt model is then successfully used to estimate complex modulus and phase angle of the RAP binder from the prop- erties of the back-calculated binder blend. This procedure would prevent the need of RAP binder extrac- tions to determine its properties, which is time-consuming and might modify the actual binder characteristics

Renewable binders from waste biomass for road construction: A review on thermochemical conversion technologies and current developments

Biobinders (binders manufactured from biomass) are becoming popular in asphalt engineering due to growing environmental concerns of greenhouse gas emissions from the use of fossil fuels and depleting petroleum bitumen reserves. Waste biomass products are sources of particular interest due to their widespread availability and impact on sustainability, however, they generally need to be thermochemically treated before being used as biobinders. Although biobinders can exhibit good performance in terms of resisting common distresses affecting road pavements, they are still relatively unknown and the uncertainty around them discourages their further use. In this context, this review aims at providing a link between biomass thermochemical conversion technologies and their respective products that may be used as biobinders in pavement engineering. For this purpose, firstly, a detailed insight of the biomass thermochemical conversion technologies available for the manufacture of biobinders is provided. Specifically, solvent liquefaction and pyrolysis are compared and the operating parameters affecting the production of biobinders from solvent liquefaction are explored. Secondly, the review focuses on providing an overview of current biobinder studies for asphalt mixtures with an emphasis on the feedstock utilised and their key engineering properties. The review shows that biobinders’ performance highly depends on the biomass source and the technology applied to produce them. Summary tables provide researchers with a quick but insightful way of identifying potential biobinder feedstocks according to certain properties