Nanoseismic monitoring for detection of rockfalls. Experiments in quarry areas

Le frane per crollo da ammassi rocciosi fratturati sono tra i processi di instabilità gravitativa che più frequentemente interessano opere antropiche quali tagli su versanti naturali o artificiali, pareti di cava, trincee stradali, autostradali o ferroviarie, sia per ciò che attiene le aree di distacco che per quelle di accumulo. Nell’ambito dell’applicazione di sistemi di early warning per la gestione del rischio geologico legato a queste tipologie di frana, una sperimentazione della tecnica del monitoraggio nanosismometrico è stata effettuata presso due siti estrattivi non più in attività: le “Pirrere” della Baia di Cala Rossa sull’isola di Favignana (Trapani), in Sicilia, e la cava dismessa di Acuto (Frosinone), in Italia Centrale. Il monitoraggio nanosismometrico è una tecnica di indagine che consente di individuare e localizzare deboli eventi sismici, fino a magnitudo locale (ML) nell’ordine di -3, attraverso l’impiego di quattro sensori sismometrici disposti secondo una specifica geometria di array detta SNS (Seismic Navigation System). Nel presente lavoro, mediante il software NanoseismicSuite sono stati analizzati 73 eventi di crollo indotti artificialmente attraverso la caduta controllata di blocchi di roccia nei due siti estrattivi abbandonati; sono stati lanciati, simulando fenomeni di rockfalls, rispettivamente 47 blocchi di roccia nella cava di Acuto e 26 eventi in quattro diverse cave a cielo aperto presenti nel settore occidentale di Cala Rossa. Tali eventi, avendo punto epicentrale noto, hanno permesso di determinare il miglior modello di sottosuolo in termini di valori di velocità delle onde P ed S attraverso un’operazione di back analysis. L’analisi è stata, infatti, effettuata variando i valori di velocità e scegliendo quelli relativi all’epicentro teorico ottenuto dall’analisi dell’evento che fosse il più vicino possibile al punto reale di impatto del blocco di roccia. Al fine di valutare la sensibilità della geometria dell’array SNS e l’influenza del sito di installazione sulla capacità di individuare e localizzare gli eventi, le sperimentazioni sono state condotte sia variando il raggio di apertura che la zona di installazione degli array: presso Acuto le acquisizioni di segnale sono state condotte prima con un array SNS con apertura di 20 m e successivamente con un array di apertura 10 m, mentre presso Cala Rossa l’array è stato installato alternativamente all’aperto in un’area di plateau roccioso ed in una galleria facente parte dell’area di cava abbandonata. Analizzando i dati si è ottenuta una precisione dell’ubicazione epicentrale compresa tra il 10 ed il 22% della distanza che intercorre tra la sorgente e l’array nanosismometrico. Il miglior modello di sottosuolo ottenuto per entrambi i casi di studio è risultato avere una velocità delle onde P pari a 900 m/s ed un rapporto VP/VS pari a 1.73, valori in accordo con le condizioni di intenso stato di fratturazione delle rocce carbonatiche affioranti nelle due zone di cava. Per gli eventi di crollo indotti la magnitudo ML è risultata essere compresa tra -2.8 e -1.3; considerando l’energia sviluppata dall’impatto, legata alla massa del blocco ed all’altezza e alla velocità di caduta, non è stato possibile definire una relazione tra magnitudo ed energia, probabilmente a causa delle differenti caratteristiche del punto di impatto dei diversi blocchi. In generale, si è osservato che la precisione di ubicazione degli eventi, in termini di azimuth e distanza dal reale epicentro, è risultata paragonabile sia variando l’apertura dell’array che variando il sito di installazione. Per il sito sperimentale di Acuto, il processo di picking manuale del tempo di primo arrivo delle onde P è risultato essere più affidabile nel caso di array con apertura pari a 10 m. La sperimentazione effettuata a Cala Rossa ha permesso, invece, di osservare una migliore capacità di individuazione degli eventi nelle tracce relative all’array posizionato in galleria a causa della minore rumorosità di base del sito di installazione. Tra le registrazioni sismometriche sono state identificate varie tipologie di segnali, oltre a quelli generati dal lancio dei blocchi, alcune riconducibili ad eventi naturali di crollo altre a deboli terremoti. L’analisi dei segnali riferibili alla prima tipologia di eventi naturali, effettuata tenendo in considerazione i modelli di sottosuolo precedentemente calibrati, ha portato all’identificazione in ambedue i siti di aree aventi maggiore suscettibilità a frane per crollo. In definitiva, si può ritenere che i risultati ottenuti in questo studio siano incoraggianti rispetto all’efficacia della tecnica di monitoraggio nanosismometrico nell’individuazione e nell’ubicazione di fenomeni di crollo in roccia e portano a ritenere questa tecnica potenzialmente applicabile in aree in cui tali eventi possono interferire con infrastrutture antropiche.In the frame of early warning and risk mitigation studies for landslide processes involving rock masses, two quarry areas (Cala Rossa Bay in Sicily and Acuto in Central Italy) were monitored with SNS (Seismic Navigation System) arrays. In this study, 73 rockfalls were simulated by launches of rock blocks. This allowed to perform a back analysis for defining the best seismic velocity model of the subsoil half-space; the records related to each impact caused by the rock block launch were managed by the nanoseismic monitoring approach, varying the velocity model to obtain a theoretical epicentre as close as possible to the actual location of the impact point. In order to evaluate the sensibility of the SNS array, the results obtained by different array apertures and positions were compared in terms of azimuth and distance error with respect to the real epicentres. On the other hand, several natural rockfalls were detected; their analysis allowed to identify areas having higher susceptibility to rockfalls by using the previously calibrated subsoil half-space model. Further studies are required to better define the areas prone to rockfall generation in the considered test sites; nevertheless, the here obtained results show an encouraging perspective about the application of the nanoseismic monitoring with respect to vulnerable infrastructures in rockfall prone areas

What does the “Elephant-Equus” event mean today? Reflections on mammal dispersal events around the Pliocene-Pleistocene boundary and the flexible ambiguity of biochronology

The dispersal of primitive elephantines and monodactyl equids in Eurasia has long been regarded as representative of a substantial turnover in mammal faunas, denoting the spread of open environments linked to the onset of cold and dry conditions in the Northern Hemisphere. During the 1980s, this event was named the “Elephant-Equus event” and it was correlated with the Gauss-Matuyama reversal, today corresponding to the Pliocene-Pleistocene transition and the beginning of the Quaternary, dated at ~2.6 Ma. Therefore, the Elephant-Equus event became a concept of prominent biochronological and paleoecological significance, especially in western Europe. Yet, uncertainties surrounding the taxonomy and chronology of early “elephant” and “Equus”, as well as conceptual differences in adopting (or understanding) the Elephant-Equus event as an intercontinental dispersal event or as a stratigraphic datum, engendered ambiguity and debate. Here, we provide a succinct review of the Elephant-Equus event, considering separately the available evidence on the “elephant” and the “Equus”. Elephantines dispersed out of Africa during the Pliocene (Piacenzian). Their earliest calibrated occurrences from eastern Europe date at ~3.2 Ma and they are usually referred to Mammuthus rumanus, although the allocation of several samples to this species is tentative. Available dating constraints for other localities do not resolve whether the dispersal of Mammuthus was synchronous across Eurasia, but this possibility cannot be ruled out. The spread of Mammuthus was part of an intercontinental faunal exchange between Africa and Eurasia that occurred during the Piacenzian, but in this scenario, Mammuthus is quite unique in being the only genus of African origin dispersing to western Eurasia. The arrival of monodactyl equids from North America coincides with the Pliocene-Pleistocene transition, with several occurrences dated or calibrated at ~2.6 Ma and no compelling evidence prior to this age. In Europe, early monodactyl equids are often aligned to Equus livenzovensis, but the material from the type locality of this species is chronologically time-averaged and taxonomically heterogeneous, and western European samples are seldom abundant or informative. Regardless, this does not diminish the biochronological significance of the “Equus event”. Indeed, while the term “Elephant-Equus event” should no longer be used, as the appearance of elephantines in the European fossil record markedly precedes that of monodactyl equids, we endorse the use of the “Equus event” as a valid alternative to refer to the intercontinental dispersal event that characterizes the middle Villafranchian faunal turnover, epitomized by but not limited to monodactyl equids

The lost hyena from Paciano (Umbria, Italy) reconsidered

We redescribe and revise the taxonomic attribution of a lost hyena hemimandible recovered from Paciano (Umbria, Italy), originally reported in the early 1900s, by comparing it with relevant samples of Pliocene, Pleistocene, and extant species. The mandible of the Paciano hyena was initially attributed to Hyaena striata (= Hyaena hyaena) and subsequently listed as a record of the giant hyena Pachycrocuta brevirostris, but is here assigned to another “bone-cracking” hyena, the Pliocene-Early Pleistocene Pliocrocuta perrieri. The Paciano hyena contributes to the discussion on the relationships and turnover between Pl. perrieri and P. brevirostris. On the one hand, the two species are very similar in craniodental morphology; their isolated remains are often separated by size; and P. brevirostris is thought to derive from a large-sized population of Pl. perrieri. On the other, a larger size is not an aspect to disregard in hyenas as it usually correlates with the acquisition or better development of “bone-cracking” features; remains attesting the co-occurrence of Pl. perrieri and P. brevirostris are known from some sites dated at around 2.0–1.8 Ma; and the observed size differences between the two species exceed those recorded between extant and (at times) sympatric species. Therefore, taken alone the competition with P. brevirostris does not explain the extinction of Pl. perrieri, but considering it together with the concurrent spread and resulting peak of carnivoran diversity in Late Villafranchian faunas might. Pliocrocuta perrieri was outcompeted by its larger descendent in scavenging carcasses, while other carnivorans limited its options to deviate to other resources or adopt a different feeding behavior (e.g., active hunting). The case of Paciano is also significant in that it offers an example of the importance and feasibility of reconsidering historical collections, even when the original material is lost entirely. In general, the seek for “novelty” that permeates current scientific literature ensues in few descriptions or reconsiderations of historical samples, especially if the new examinations confirm old results, but we emphasize the significance of such efforts in making old data truly available for the scientific community. In addition, the hyena from Paciano has a biochronological and stratigraphic value, confirming the occurrence in western Umbria of a depositional cycle older than the late Early Pleistocene one (well represented by the rich assemblages from Pietrafitta and Selvella; Farneta Faunal Unit)

Water Relations in Berseem Cultivars Under Drought Stress

Berseem clover (Trifolium alexandrinum L.) is a crop of particular interest in semi-arid regions, used for herbage and hay productions. However, its seed yield is reduced by drought stress that occurs during seed filling. In this study five cultivars (Axi, Big Bee, Lilibeo, Sacromonte and Saniros) subjected to four irrigation frequencies in controlled environment, were compared for their physiological responses to subsequent water stress period (3 days). Some parameters (leaf water potential (), osmotic potential (þ), relative water content (RWC) and gravimetric soil water content (GSWC)) related to plant water status were recorded. Plants subjected to previous periods of water stress were less sensitive to final drought stress than plants never stressed (control). Among cultivars examined, Lilibeo showed significantly higher values of , þ and RWC. Therefore, it seems to be the most tolerant cultivar for its ability to mantain high water status under water stress conditions

Should I stay or should I go? Carbon leakage and ETS in an evolutionary model

Emissions trading is gaining increasing importance around the world as a suitable instrument to address climate change. In the absence of a global carbon market, however, unilateral carbon policies may end up causing carbon leakage effects, the more so if carbon prices are to increase in the future to achieve more ambitious emissions abatement targets. This paper intends to explore the possible delocalization effects of an Emissions Trading System (ETS) by proposing an evolutionary theoretical model in which regulated firms decide whether to stay (keep their production activities in the domestic country) or leave (move production abroad where no ETS is in place) imitating what other firms do. We investigate how this decision is affected by some key ETS design features, such as the emissions cap, the number of allowances granted for free to ETS firms, the level of a floor price for allowances. Numerical simulations show that the firms' decision on whether to abate emissions or relocate abroad are more sensitive to policies that reduce the cost of green technologies than to changes in specific features of the ETS design such as the emissions cap, the floor price and the number of permits granted for free.Web of Science103art. no. 10556

Impact of Seed Inoculation with Trichoderma afroharzianum Strains on Plant Growth, Root Morphology, and Leaf Phenolic Content in Hemp (Cannabis sativa L.) at Early Growth Stages

Industrial hemp (Cannabis sativa L.) is receiving increasing attention for its multiple end-uses; therefore, an improvement in its production is needed to meet the increased demand. In the present study, the effect of seed inoculation with two Trichoderma afroharzianum strains, T-AA and T-22, on plant growth and root morphology of hemp plants at sixth-leaf (S6) and tenth-leaf (S10) stages was assessed for two consecutive years (2020 and 2021). In addition, the ability of the two strains to enhance the accumulation of phenolic compounds in hemp leaves was also evaluated. The results obtained revealed the ability of T-22 to improve the growth and root morphology of hemp plants both in 2020 and 2021, although with different impact, probably ascribable to the different weather conditions in the two years. In 2020, the positive effects of T-22 were detected at S10 stage with significant increases in the shoot and root length (38% and 17%, respectively) and dried biomass (35% and 30%, respectively) compared to untreated plants. The total root surface area and the number of tips, forks, and crossings also increased significantly (24–36%) at this stage. In 2021, significant increases in the shoot length and dried biomass (40% and 30%, respectively) were observed at S6 stage, whereas root length and dried biomass increased significantly at S6 (55% and 47%, respectively) and S10 stage (121% and 40%, respectively). Significant increases in the total surface area and volume, as well as in the number of tips, forks, and crossings were also observed at both S6 and S10 stage (50–63% and 105–187%, respectively). Interestingly, in both years and at both stages, the two strains induced significant increases in the leaf accumulation of phenolic compounds and the antioxidant activity, which were greater in T-22- compared to T-AA-treated plants (18–102% and 13–34%, respectively). The results are discussed in light of the potential practical applications of T-22 as a biostimulant of hemp plant growth under favorable and unfavorable environmental conditions, and of both strains as promising tools for the improvement of the leaves’ economic value as a source of health-promoting compounds

Accumulation of Dry Matter, Protein and Total Available Carbohydrate in Berseem under Different Cutting Regimes

The effect of different cutting regimes on physiology and morphology of aerial parts and roots in 6 bcrseem (Trifolium alexadrium L.) genotypes was evaluated. Observations were carried out on individual plants at 4 stages of development: fourth and eighth internode elongation, early flowering and physiological seed maturity. The results showed that the genotypes were characterised by highest values of dry matter in the aerial and root parts at the early flowering stage. Variability among genotypes was observed

Vanillin-Based Photocurable Anticorrosion Coatings Reinforced with Nanoclays

This study investigates the chemical-physical properties and anticorrosion effectiveness of UV-cured coatings produced using epoxidized vanillin (DGEVA) as biobased precursor, then reinforced by the addition of nanoclay. After optimizing the UV-curing parameters of three different formulations by Fourier transform infrared spectroscopy (FTIR), the thermo-mechanical properties of the coatings are assessed by differential scanning calorimetric analysis (DSC), dynamic thermal mechanical analysis (DTMA), and pencil hardness. The coatings are applied on mild steel substrates and then their barrier properties are investigated by electrochemical impedance spectroscopy measurements, immersing the samples in 3.5 wt% NaCl aerated solutions. The results show the good corrosion protective effectiveness of the biobased coatings. The nanoclay addition has a beneficial effect, as it hinders the diffusion of the aggressive ions from the electrolyte solution to the metal substrate. The reported findings demonstrate the possibility of using biobased precursors and UV-curing technology to reduce the environmental impact of the coating industry.A photocurable epoxy composite is realized using epoxidized vanillin (DGEVA) as a biobased precursor, and functionalized nanoclay as filler. The coating shows good thermo-mechanical properties, high chemical resistance, and satisfactory corrosion protection effectiveness in aggressive environments containing chlorides. imag