Polymer adsorption on heterogeneous surfaces

The adsorption of a single ideal polymer chain on energetically heterogeneous and rough surfaces is investigated using a variational procedure introduced by Garel and Orland (Phys. Rev. B 55 (1997), 226). The mean polymer size is calculated perpendicular and parallel to the surface and is compared to the Gaussian conformation and to the results for polymers at flat and energetically homogeneous surfaces. The disorder-induced enhancement of adsorption is confirmed and is shown to be much more significant for a heterogeneous interaction strength than for spatial roughness. This difference also applies to the localization transition, where the polymer size becomes independent of the chain length. The localization criterion can be quantified, depending on an effective interaction strength and the length of the polymer chain.Comment: accepted in EPJB (the Journal formerly known as Journal de Physique

Accurate freezing and melting equations for the Lennard-Jones system

Analyzing three approximate methods to locate liquid-solid coexistence in simple systems, an observation is made that all of them predict the same functional dependence of the temperature on density at freezing and melting of the conventional Lennard-Jones system. The emerging equations can be written as $T={\mathcal A}\rho^4+{\mathcal B}\rho^2$ in normalized units. We suggest to determine the values of the coefficients ${\mathcal A}$ at freezing and melting from the high-temperature limit, governed by the inverse twelfth power repulsive potential. The coefficients ${\mathcal B}$ can be determined from the triple point parameters of the LJ fluid. This produces freezing and melting equations which are exact in the high-temperature limit and at the triple point, and show remarkably good agreement with numerical simulation data in the intermediate region.Comment: 6 pages, 1 figur

Deformations of Gabor Frames

The quantum mechanical harmonic oscillator Hamiltonian generates a one-parameter unitary group W(\theta) in L^2(R) which rotates the time-frequency plane. In particular, W(\pi/2) is the Fourier transform. When W(\theta) is applied to any frame of Gabor wavelets, the result is another such frame with identical frame bounds. Thus each Gabor frame gives rise to a one-parameter family of frames, which we call a deformation of the original. For example, beginning with the usual tight frame F of Gabor wavelets generated by a compactly supported window g(t) and parameterized by a regular lattice in the time-frequency plane, one obtains a family of frames F_\theta generated by the non-compactly supported windows g_\theta=W(theta)g, parameterized by rotated versions of the original lattice. This gives a method for constructing tight frames of Gabor wavelets for which neither the window nor its Fourier transform have compact support. When \theta=\pi/2, we obtain the well-known Gabor frame generated by a window with compactly supported Fourier transform. The family F_\theta therefore interpolates these two familiar examples.Comment: 8 pages in Plain Te

Robust Optimal Risk Sharing and Risk Premia in Expanding Pools

We consider the problem of optimal risk sharing in a pool of cooperative agents. We analyze the asymptotic behavior of the certainty equivalents and risk premia associated with the Pareto optimal risk sharing contract as the pool expands. We first study this problem under expected utility preferences with an objectively or subjectively given probabilistic model. Next, we develop a robust approach by explicitly taking uncertainty about the probabilistic model (ambiguity) into account. The resulting robust certainty equivalents and risk premia compound risk and ambiguity aversion. We provide explicit results on their limits and rates of convergence, induced by Pareto optimal risk sharing in expanding pools

Correlations of conductance peaks and transmission phases in deformed quantum dots

We investigate the Coulomb blockade resonances and the phase of the transmission amplitude of a deformed ballistic quantum dot weakly coupled to leads. We show that preferred single--particle levels exist which stay close to the Fermi energy for a wide range of values of the gate voltage. These states give rise to sequences of Coulomb blockade resonances with correlated peak heights and transmission phases. The correlation of the peak heights becomes stronger with increasing temperature. The phase of the transmission amplitude shows lapses by $\pi$ between the resonances. Implications for recent experiments on ballistic quantum dots are discussed.Comment: 29 pages, 9 eps-figure

Diagnosing Deconfinement and Topological Order

Topological or deconfined phases are characterized by emergent, weakly fluctuating, gauge fields. In condensed matter settings they inevitably come coupled to excitations that carry the corresponding gauge charges which invalidate the standard diagnostic of deconfinement---the Wilson loop. Inspired by a mapping between symmetric sponges and the deconfined phase of the $Z_2$ gauge theory, we construct a diagnostic for deconfinement that has the interpretation of a line tension. One operator version of this diagnostic turns out to be the Fredenhagen-Marcu order parameter known to lattice gauge theorists and we show that a different version is best suited to condensed matter systems. We discuss generalizations of the diagnostic, use it to establish the existence of finite temperature topological phases in $d \ge 3$ dimensions and show that multiplets of the diagnostic are useful in settings with multiple phases such as $U(1)$ gauge theories with charge $q$ matter. [Additionally we present an exact reduction of the partition function of the toric code in general dimensions to a well studied problem.]Comment: 11 pages, several figure

An Entropy Stable Nodal Discontinuous Galerkin Method for the Two Dimensional Shallow Water Equations on Unstructured Curvilinear Meshes with Discontinuous Bathymetry

We design an arbitrary high-order accurate nodal discontinuous Galerkin spectral element approximation for the nonlinear two dimensional shallow water equations with non-constant, possibly discontinuous, bathymetry on unstructured, possibly curved, quadrilateral meshes. The scheme is derived from an equivalent flux differencing formulation of the split form of the equations. We prove that this discretisation exactly preserves the local mass and momentum. Furthermore, combined with a special numerical interface flux function, the method exactly preserves the mathematical entropy, which is the total energy for the shallow water equations. By adding a specific form of interface dissipation to the baseline entropy conserving scheme we create a provably entropy stable scheme. That is, the numerical scheme discretely satisfies the second law of thermodynamics. Finally, with a particular discretisation of the bathymetry source term we prove that the numerical approximation is well-balanced. We provide numerical examples that verify the theoretical findings and furthermore provide an application of the scheme for a partial break of a curved dam test problem

Ionization enhanced ion collection by a small floating grain in plasmas

It is demonstrated that the ionization events in the vicinity of a small floating grain can increase the ion flux to its surface. In this respect the effect of electron impact ionization is fully analogous to that of the ion-neutral resonant charge exchange collisions. Both processes create slow ion which cannot overcome grain' electrical attraction and eventually fall onto its surface. The relative importance of ionization and ion-neutral collisions is roughly given by the ratio of the corresponding frequencies. We have evaluated this ratio for neon and argon plasmas to demonstrate that ionization enhanced ion collection can indeed be an important factor affecting grain charging in realistic experimental conditions.Comment: 7 pages, 1 figure, submitted to Physics of Plasma