418 research outputs found
evaluation of the effects of the numerical modelling choices on the simulation of a tensile test on cfrp composite
Abstract The goal of the present work is to define a method to build a FE model which is able to reproduce an experimental tensile test on CFRP specimen with different stacking sequences (UD and balanced). The defined method assesses the material numerical parameters by means of a simulation that replicates, as a virtual test, the experimental tensile one, and in the future, it will be possible to exploit the data obtained to create a reliable model for the simulation of low velocity impacts. Analyses have been performed using the non-linear solver ABAQUS Explicit. The current work further studies how to model damage and the effect of modifications of the numerical parameters on the results. Indeed, the numerical simulation of composite materials is very sensitive to the numerical choices made. Moreover, from the literature and experiments, the mechanical properties of composites are very variable and hence the evaluation of the model response to such modifications is of particular interest
Optical study of the vibrational and dielectric properties of BiMnO3
BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also
ferroelectric (FE) due to a non-centro-symmetric C2 structure, until
diffraction data indicated that its space group is the centro-symmetric C2/c.
Here we present infrared phonon spectra of BMO, taken on a mosaic of single
crystals, which are consistent with C2/c at any T > 10 K, as well as
room-temperature Raman data which strongly support this conclusion. We also
find that the infrared intensity of several phonons increases steadily for
decreasing T, causing the relative permittivity of BMO to vary from 18.5 at 300
K to 45 at 10 K. At variance with FE materials of displacive type, no
appreciable softening has been found in the infrared phonons. Both their
frequencies and intensities, moreover, appear insensitive to the FM transition
at Tc
Synthesis and characterization of multiferroic BiMnO
We report on the high pressure synthesis of BiMnO, a manganite
displaying a "quadruple perovskite" structure. Structural characterization of
single crystal samples shows a distorted and asymmetrical coordination around
the Bi atom, due to presence of the lone pair, resulting in
non-centrosymmetric space group Im, leading to a permanent electrical dipole
moment and ferroelectric properties. On the other hand, magnetic
characterization reveals antiferromagnetic transitions, in agreement with the
isostructural compounds, thus evidencing two intrinsic properties that make
BiMnO a promising multiferroic material.Comment: 4 pages, 3 figure
Commensurate structural modulation in the charge- and orbitally-ordered phase of the quadruple perovskite (NaMn)MnO
By means of synchrotron x-ray and electron diffraction, we studied the
structural changes at the charge order transition =176 K in the
mixed-valence quadruple perovskite (NaMn)MnO. Below we
find satellite peaks indicating a commensurate structural modulation with the
same propagation vector q =(1/2,0,-1/2) of the CE magnetic order that appears
at low temperature, similarly to the case of simple perovskites like
LaCaMnO. In the present case, the modulated structure
together with the observation of a large entropy change at gives
evidence of a rare case of full Mn/Mn charge and orbital order
consistent with the Goodenough-Kanamori model.Comment: Accepted for publication in Phys. Rev. B Rapid Communication
Internal-strain mediated coupling between polar Bi and magnetic Mn ions in the defect-free quadruple-perovskite BiMnMnO
By means of neutron powder diffraction, we investigated the effect of the
polar Bi ion on the magnetic ordering of the Mn ions in
BiMnMnO, the counterpart with \textit{quadruple} perovskite
structure of the \textit{simple} perovskite BiMnO. The data are consistent
with a \textit{noncentrosymmetric} spacegroup which contrasts the
\textit{centrosymmetric} one previously reported for the isovalent and
isomorphic compound LaMnMnO, which gives evidence of a
Bi-induced polarization of the lattice. At low temperature, the two
Mn sublattices of the and sites order antiferromagnetically
(AFM) in an independent manner at 25 and 55 K, similarly to the case of
LaMnMnO. However, both magnetic structures of
BiMnMnO radically differ from those of LaMnMnO.
In BiMnMnO the moments of the sites form
an anti-body AFM structure, whilst the moments \textbf{M} of the
sites result from a large and \textit{uniform} modulation along the b-axis of the moments \textbf{M} in the
-plane. The modulation is strikingly correlated with the displacements of
the Mn ions induced by the Bi ions. Our analysis unveils a strong
magnetoelastic coupling between the internal strain created by the Bi
ions and the moment of the Mn ions in the sites. This is ascribed to
the high symmetry of the oxygen sites and to the absence of oxygen defects, two
characteristics of quadruple perovskites not found in simple ones, which
prevent the release of the Bi-induced strain through distortions or
disorder. This demonstrates the possibility of a large magnetoelectric coupling
in proper ferroelectrics and suggests a novel concept of internal strain
engineering for multiferroics design.Comment: 9 pages, 7 figures, 5 table
- …