Sol gel synthesis of multiphase lanthanum oxicarbonate and langasite thin films

Precursors of lanthanum oxide and of (3La2O3, 5Ga2O3, SiO2) system were first elaborated then thermally decomposed into polycrystalline lanthanum oxide and langasite La3Ga5SiO14. The as prepared lanthanum oxide powder was then hydrated and carbonated to give hydroxicarbonates: thermal decomposition of these complex system La2O3-X(OH)y(CO3)z was studied by Fourier Transform infrared spectroscopy. Spin coating process applied to these precursors was optimized to elaborate thin films of lanthanum oxicarbonate La2O2CO3, lanthanum oxide La2O3 and langasite, on silicium substrates (Si-(001)). Thin films are partly textured. Making use of same spin coating process, multiphase thin films of langasite covered with La2O3 particles were obtained.Precursors of lanthanum oxide and of (3La2O3, 5Ga2O3, SiO2) system were first elaborated then thermally decomposed into polycrystalline lanthanum oxide and langasite La3Ga5SiO14. The as prepared lanthanum oxide powder was then hydrated and carbonated to give hydroxicarbonates: thermal decomposition of these complex system La2O3-X(OH)y(CO3)z was studied by Fourier Transform infrared spectroscopy. Spin coating process applied to these precursors was optimized to elaborate thin films of lanthanum oxicarbonate La2O2CO3, lanthanum oxide La2O3 and langasite, on silicium substrates (Si-(001)). Thin films are partly textured. Making use of same spin coating process, multiphase thin films of langasite covered with La2O3 particles were obtained

New ionic conducting ceramics of NASICON type: synthesis and characterizations

In this work, we present a study of two NaSICON families of general formula Na2.800M1.775Si0.900P2.100O12 with M=Zr or Hf. The synthesis was carried out using sol-gel process and the synthesized precursors were characterized using coupled DTA-TG. The obtained oxides after pyrolysis of precursors were identified by X-ray diffraction. The electric properties of the sintered oxides were carried out by impedance spectroscopy (SIC). The obtained results at this conditions highlight a good improvement of electrical conductivity (σtot around 10-4S.cm-1). This value is comparable to total electrical conductivity at 300K given in the literature.In this work, we present a study of two NaSICON families of general formula Na2.800M1.775Si0.900P2.100O12 with M=Zr or Hf. The synthesis was carried out using sol-gel process and the synthesized precursors were characterized using coupled DTA-TG. The obtained oxides after pyrolysis of precursors were identified by X-ray diffraction. The electric properties of the sintered oxides were carried out by impedance spectroscopy (SIC). The obtained results at this conditions highlight a good improvement of electrical conductivity (σtot around 10-4S.cm-1). This value is comparable to total electrical conductivity at 300K given in the literature

Solid-state synthesis of NASICON (Na3Zr2Si2PO12) using nanoparticle precursors for optimisation of ionic conductivity

In this work, the effect of varying the size of the precursor raw materials SiO2 and ZrO2 in the solid-state synthesis of NASICON in the form Na3Zr2Si2PO12 was studied. Nanoscale and macro-scale precursor materials were selected for comparison purposes, and a range of sintering times were examined (10, 24 and 40 h) at a temperature of 1230 °C. Na3Zr2Si2PO12 pellets produced from nanopowder precursors were found to produce substantially higher ionic conductivities, with improved morphology and higher density than those produced from larger micron-scaled precursors. The nanoparticle precursors were shown to give a maximum ionic conductivity of 1.16 × 10−3 S cm−1 when sintered at 1230 °C for 40 h, in the higher range of published solid-state Na3Zr2Si2PO12 conductivities. The macro-precursors gave lower ionic conductivity of 0.62 × 10−3 S cm−1 under the same processing conditions. Most current authors do not quote or consider the precursor particle size for solid-state synthesis of Na3Zr2Si2PO12. This study shows the importance of precursor powder particle size in the microstructure and performance of Na3Zr2Si2PO12 during solid-state synthesis and offers a route to improved predictability and consistency of the manufacturing process

Substitutional effect of Mg2+ on structural and magnetic properties of cobalt nanoferrite

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Structural, magnetic and magnetocaloric study of Ni0.5Zn0.5Fe2O4 spinel

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Structural, magnetic and magnetocaloric study of Ni0.5Zn0.5Fe2O4 spinel

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Substitutional effect of Mg2+ on structural and magnetic properties of cobalt nanoferrite

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Structural, magnetic, magnetocaloric properties and critical behavior of La0.62Nd0.05Ba0.33MnO3 elaborated by co-precipitation process

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Structural, morphological, and magnetic studies of spinel ferrites derived from layered double hydroxides

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