92 research outputs found
3D Dirac semimetal Cd3As2: A review of material properties
Cadmium arsenide (Cd3As2) - a time-honored and widely explored material in
solid-state physics - has recently attracted considerable attention. This was
triggered by a theoretical prediction concerning the presence of 3D
symmetry-protected massless Dirac electrons, which could turn Cd3As2 into a 3D
analogue of graphene. Subsequent extended experimental studies have provided us
with compelling experimental evidence of conical bands in this system, and
revealed a number of interesting properties and phenomena. At the same time,
some of the material properties remain the subject of vast discussions despite
recent intensive experimental and theoretical efforts, which may hinder the
progress in understanding and applications of this appealing material. In this
review, we focus on the basic material parameters and properties of Cd3As2, in
particular those which are directly related to the conical features in the
electronic band structure of this material. The outcome of experimental
investigations, performed on Cd3As2 using various spectroscopic and transport
techniques within the past sixty years, is compared with theoretical studies.
These theoretical works gave us not only simplified effective models, but more
recently, also the electronic band structure calculated numerically using ab
initio methods.Comment: 16 pages, 16 figure
Resistive switching in β-SrV6O15
Abstract.: We investigate the pressure and temperature behavior of current-dependent resistivity of β-SrV6O15. We observe a switching between states of different resistivities in the insulating state of β-SrV6O15. In the low pressure phase, the resistive switching appears at temperatures below the semiconductor-insulator transition. In the high pressure phase, under ~1.6GPa, the switching appears in the temperature range of the phase transition. The existence of switching may imply an important role of strontium off-stoichiometry for the electrical transport in β-SrV6O15. No electric-field-induced enhancement of the conductivity is observed. However, the conduction is significantly nonlinear under ~1.6GPa, indicating that the charge order pattern in the high pressure phase is considerably different from that of the low pressure phas
Optical properties of BiTeBr and BiTeCl
We present a comparative study of the optical properties - reflectance,
transmission and optical conductivity - and Raman spectra of two layered
bismuth-tellurohalides BiTeBr and BiTeCl at 300 K and 5 K, for light polarized
in the a-b planes. Despite different space groups, the optical properties of
the two compounds are very similar. Both materials are doped semiconductors,
with the absorption edge above the optical gap which is lower in BiTeBr (0.62
eV) than in BiTeCl (0.77 eV). The same Rashba splitting is observed in the two
materials. A non-Drude free carrier contribution in the optical conductivity,
as well as three Raman and two infrared phonon modes, are observed in each
compound. There is a dramatic difference in the highest infrared phonon
intensity for the two compounds, and a difference in the doping levels. Aspects
of the strong electron-phonon interaction are identified. Several interband
transitions are assigned, among them the low-lying absorption which has
the same value 0.25 eV in both compounds, and is caused by the Rashba spin
splitting of the conduction band. An additional weak transition is found in
BiTeCl, caused by the lower crystal symmetry.Comment: Accepted in PR
Optical conductivity of nodal metals
Fermi liquid theory is remarkably successful in describing the transport and
optical properties of metals; at frequencies higher than the scattering rate,
the optical conductivity adopts the well-known power law behavior
. We have observed an unusual non-Fermi
liquid response in the ground
states of several cuprate and iron-based materials which undergo electronic or
magnetic phase transitions resulting in dramatically reduced or nodal Fermi
surfaces. The identification of an inverse (or fractional) power-law behavior
in the residual optical conductivity now permits the removal of this
contribution, revealing the direct transitions across the gap and allowing the
nature of the electron-boson coupling to be probed. The non-Fermi liquid
behavior in these systems may be the result of a common Fermi surface topology
of Dirac cone-like features in the electronic dispersion.Comment: 8 pages including supplemental informatio
Phonon anomaly in BaFe2As2
The detailed optical properties of BaFe2As2 have been determined over a wide
frequency range above and below the structural and magnetic transition at T_N =
138 K. A prominent in-plane infrared-active mode is observed at 253 cm^{-1}
(31.4 meV) at 295 K. The frequency of this vibration shifts discontinuously at
T_N; for T < T_N the frequency of this mode displays almost no temperature
dependence, yet it nearly doubles in intensity. This anomalous behavior appears
to be a consequence of orbital ordering in the Fe-As layers.Comment: 4 pages, 3 figures and one table (minor revisions
Collective Charge Excitations below the Metal-to-Insulator Transition in BaVS3
The charge response in the barium vanadium sulfide (BaVS3) single crystals is
characterized by dc resistivity and low frequency dielectric spectroscopy. A
broad relaxation mode in MHz range with huge dielectric constant ~= 10^6
emerges at the metal-to-insulator phase transition TMI ~= 67 K, weakens with
lowering temperature and eventually levels off below the magnetic transition
Tchi ~= 30 K. The mean relaxation time is thermally activated in a manner
similar to the dc resistivity. These features are interpreted as signatures of
the collective charge excitations characteristic for the orbital ordering that
gradually develops below TMI and stabilizes at long-range scale below Tchi.Comment: 6 pages, 3 figures, submitted to PR
Electronic correlations and unusual superconducting response in the optical properties of the iron-chalcogenide FeTe0.55Se0.45
The in-plane complex optical properties of the iron-chalcogenide
superconductor FeTe0.55Se0.45 have been determined above and below the critical
temperature Tc = 14 K. At room temperature the conductivity is described by a
weakly-interacting Fermi liquid; however, below 100 K the scattering rate
develops a frequency dependence in the terahertz region, signaling the
increasingly correlated nature of this material. We estimate the dc
conductivity just above Tc to be sigma_dc ~ 3500 Ohm-1cm-1 and the superfluid
density rho_s0 ~ 9 x 10^6 cm-2, which places this material close to the scaling
line rho_s0/8 ~ 8.1 sigma_dc Tc for a BCS dirty-limit superconductor. Below Tc
the optical conductivity reveals two gap features at Delta_1,2 ~ 2.5 and ~ 5.1
meV.Comment: Minor revisions, 5 pages, 4 figure
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