Synthesis of Complex (C_(60))_2Ru_2Cl_4[Ph_2P(CH_2)_4PPh_2]

在氮气氛中采用配体取代法合成了C60以σ-π配位方式与Ru形成的稳定η2型富勒烯双核钌金属配合物(C60)2Ru2Cl4[Ph2P(CH2)4PPh2],其结构经UV,IR,XPS,XRD和元素分析表征。A fullerene double core ruthenium metal η2-complex{(C60)2Ru2Cl4[Ph2P(CH2)4PPh2]} with σ-π feedback pattern between C60 and Ru was synthesized by the method of ligand substituting in nitrogen atmosphere. The structure was characterized by UV, IR, XPS, XRD and elemental analysis.福建省自然科学基金资助项目(E04100001,E0110002

Synthesis and Characterization and Photoelectric Property of Fullerene Complex C_(60)Pt(BINAP)

本文利用配体取代法合成了C60Pt(BINAP)新型富勒烯膦金属配合物,采用质谱、元素分析、紫外-可见吸收光谱、红外吸收光谱、光电子能谱等对该产物进行了表征,并测定了其在光化学电池中的光伏效应。光伏效应测试结果表明:在BQ/H2Q与I2/I3-介质溶液中镀层厚度为1～2μm时,具有较好的光电转换性能,光生电压值最高达358mV。A fullerene-phosphine metal complex,C60Pt(BINAP) ,was synthesized by ligand substitution method.The product was characterized by MS,elemental analysis,UV-Vis,IR and XPS.The photovoltaic performances of the complex was determined in the photochemistry cell.The results showed that the fullerene-phosphine metal complex exhibited high photoelectric conversion property,especially under the conditions of BQ/H2Q and I3-/I-redox couples,and 1～2 μm of thickness of the film,the maximum value of photovoltage was 358 mV.福建省自然科学基金资助项目(No.E04100001,E0110002)

Synthesis and Characterization and Photoelectric Property of Fullerene Complex C60Pt(BINAP)

A fullerene-phosphine metal complex, Cat(BINAP), was synthesized by ligand substitution method. The product was characterized by MS, elemental analysis, UV-Vis, IR and XPS. The photovoltaic performances of the complex was determined in the photochemistry cell. The results showed that the fullerene-phosphine metal complex exhibited high photoelectric conversion property, especially under the conditions of BQ/H(2)Q and I-3(-)/I(-)redox couples, and 1 similar to 2 mu m of thickness of the film, the maximum value of photovoltage was 358 mV

Synthesis of A Novel Fullerene-phosphine Metal Complex

用配体取代法合成了新型富勒烯膦金属配合物——C60.双(二苯基膦)戊烷合钯[C60Pd(dPPPE),1],其结构经uV-VIS,Ir,XPS及元素分析表征。在1的分子结构中,C60以σ-π配位方式与Pd配位,形成新型的η2-C60双齿膦金属配合物。A novel fullerene-phosphine metal complex,C60Pd(dpppe)(1),was synthesized by ligand substitution method.The structure was characterized by UV-Vis,IR,XPS and elemental analysis.C60 and Pd formed the η2-C60 metal complex of 1 with σ-π coordination bond

Synthesis and Characterization of the Fullerene Complex C_(60)RuCl_2(phCH_2Pph_2)_2

富勒烯金属配合物具有特殊的物理和化学性质.本实验在氮气氛中采用配体取代法合成了富勒烯Ru金属配合物C60RuCl2(phCH2Pph2)2,并利用元素分析、红外光谱、紫外可见光谱、光电子能谱、X射线多晶粉末衍射对配合物的组成、结构等进行了表征.结果表明,C60以σ──π配位方式与Ru形成了稳定的η2型C60金属配合物C60RuCl2(phCH2Pph2)2.Fullerene-ruthenium metal complexe C60RuCl2(phCH2Pph2)2 was synthesized using the method of ligand substitution via the reaction of C60 with RuCl2(phCH2Pph2)4 under condition of a nitrogen atmosphere and refluxing.The title compound was characterized by using elemental analysis,infrared spectroscopy,UV-vis,XPS,XRD.The results showed that the phCH2Pph2 took up tow coordination sites of the central metal,and C60 took up another two sites in σ π feedback pattern.福建省自然科学基金项目(E04100001,E0110002)资