富勒烯金属配合物具有特殊的物理和化学性质.本实验在氮气氛中采用配体取代法合成了富勒烯Ru金属配合物C60RuCl2(phCH2Pph2)2,并利用元素分析、红外光谱、紫外可见光谱、光电子能谱、X射线多晶粉末衍射对配合物的组成、结构等进行了表征.结果表明,C60以σ──π配位方式与Ru形成了稳定的η2型C60金属配合物C60RuCl2(phCH2Pph2)2.Fullerene-ruthenium metal complexe C60RuCl2(phCH2Pph2)2 was synthesized using the method of ligand substitution via the reaction of C60 with RuCl2(phCH2Pph2)4 under condition of a nitrogen atmosphere and refluxing.The title compound was characterized by using elemental analysis,infrared spectroscopy,UV-vis,XPS,XRD.The results showed that the phCH2Pph2 took up tow coordination sites of the central metal,and C60 took up another two sites in σ π feedback pattern.福建省自然科学基金项目(E04100001,E0110002)资
