双金属Zn-Fe金属有机框架的制备及其丙酮气敏特性研究

采用溶剂热法制备了双金属Zn-Fe金属有机框架结构(Zn-Fe MOF),利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射仪(XRD)对其微观形貌和晶相进行表征分析。结果表明:制备的双金属Zn-Fe MOF为纳米球结构,其直径约为150 nm。同时,制备了基于双金属Zn-Fe MOF材料的气体传感器件,研究了其对丙酮的气敏特性。测试结果表明:基于双金属Zn-Fe MOF的气体传感器对丙酮的最佳工作温度为210℃。在最佳工作温度下,对浓度为1×10-6的丙酮气体响应可达到2,响应/恢复时间分别为6 s/13 s,且具有较好的重复性和长期稳定性。最后,对基于双金属Zn-Fe MOF气体传感器的气敏机理进行了讨论。国家自然科学基金项目(51205274);;山西省人才专项项目(2016[36]);;山西省自然基金项目(2016[39]);;山西省高校科技创新研究项目(2016[37]);;山西省归国留学择优项目([2014]95);;山西省归国留学基金项目(2013-035);;山西省科技重大专项项目(20121101004);;山西省高等学校特色重点学科建设项目(晋教财[2012]45号

Ocean surface wind and wave monitoring at Typhoon Fung-Wong by HFSWR OSMAR071

介绍了OSMAr071高频地波雷达系统“凤凰“台风期间海面风、浪遥测结果。文中给出高频地波雷达OS-MAr071风、浪反演算法:利用SbM模型结合多波束采样法反演风向;利用改进的bArrICk模型进行有效波高的反演;利用SMb关系式进行风速反演。将雷达定点观测结果与浮标数据进行对比,表现出很好的一致性,其中有效波高相关系数为0.72,均方根误差为0.48M,风向相关系数为0.97,均方根误差为27.7°,风速的相关系数为0.6,均方根误差为3.5M/S。文中还对影响探测精度的因素进行了分析。This paper provides wind and wave observation results detected by high frequency surface wave radar OSMAR071 during Typhoon Fung-Wong.Methods for extracting ocean surface parameters from HFSWR sea echo are introduced.The Stewart Barnum and Maresca SBM method combined with multi-beam sampling method is used to invert wind direction.A modified Barrick's model is proposed to obtain significant wave height and the SMB formulation is used to extract wind speed information.Compared with buoy data of wind and wave,radar inversion results show good agreement with in-situ observations.The root-mean-square error RMSE of significant wave height,wind speed and wind direction between radar-derived and those from the buoy are 0.48 m,3.5 m/s,27.7°,and the coefficients of determination(R2) are 0.72,0.60 and 0.97,respectively.Factors affecting detecting accuracy are also discussed in this paper.国家高技术研究发展计划(863计划)(编号:2009AA09A301);国家自然科学基金(编号:60571065)---

The Research of Several Electrodes for SPE Water Electrolysis

研究了IrRu/Nafion117/PbAg、IrRu/Nafion117/Ni、IrRu/Nafion117/TiNi、Ag/Nafion117/Ni、C/Na-fion117/PtRu等5种三合一膜电极(MEA)的水电解性能.实验发现,上述各电极的阳极活性顺序为:IrRu>Ag>C,阴极为:Ni>PbAg>TiNi,TiNi的稳定性比Ni好很多,PbAg最为稳定.各电极的过电位均随温度的升高而下降,电流效率随电流密度的增大而提高.Performances of the IrRu/Nafion 117/PbAg,IrRu/Nafion 117/Ni,IrRu/Nafion 117/TiNi,Ag/Nafion 117/Ni and C/Nafion 117/PtRu for the SPE water electrolysis have been investigated.The order of the electrocatalysis activity for the anodic electrodes as mentioned above is IrRu>Ag>C,and that of cathodic electrode is Ni>PbAg>TiNi.While the stability of TiNi was much better than Ni,and that of PbAg is best.Moreover,the current efficiency was raised with the increase of current density.作者联系地址：表面物理与化学国家重点实验室,表面物理与化学国家重点实验室,表面物理与化学国家重点实验室,表面物理与化学国家重点实验室,表面物理与化学国家重点实验室 四川绵阳621900,四川绵阳621900,四川绵阳621900,四川绵阳621900,四川绵阳621900Author's Address: State Key Laboratory of Surface Physics and Chemistry,Mianyang 621900,Sichuan,Chin

Chlorpromazine confers neuroprotection against brain ischemia by activating BKCa channel

National Natural Science Foundation of China (NSFC) [31070741, 31270891, 81000560]Chlorpromazine (CPZ) is a well-known antipsychotic drug, still widely being used to treat symptoms of schizophrenia, psychotic depression and organic psychoses. We have previously reported that CPZ activates the BKCa (K(Ca)1.1) channel at whole cell level. In the present study, we demonstrated that CPZ increased the single channel open probability of the BKCa channels without changing its single channel amplitude. As BKCa channel is one of the molecular targets of brain ischemia, we explored a possible new use of this old drug on ischemic brain injury. In middle cerebral artery occlusion (MCAO) focal cerebral ischemia, a single intraperitoneal injection of CPZ at several dosages (5 mg/kg, 10 mg/kg and 20 mg/kg) could exert a significant neuroprotective effect on the brain damage in a dose- and time-dependent manner. Furthermore, blockade of BKCa channels abolished the neuroprotective effect of CPZ on MCAO, suggesting that the effect of CPZ is mediated by activation of the BKCa channel. These results demonstrate that CPZ could reduce focal cerebral ischemic damage through activating BKCa channels and merits exploration as a potential therapeutic agent for treating ischemic stroke. (C) 2014 Elsevier B.V. All rights reserved