Developing fast laboratory screening platform for sulfate dioxide in food by surface-enhanced Raman spectroscopy

基于表面增强拉曼光谱(SERS)的指纹图谱的高能量分辨率,以位于~630; cm~(-1)亚硫酸根的特征峰为定性和定量依据,本文开展了食品中滥用和非法添加二氧化硫的直接检测研究:一种检测流程实现了不同食品基质中二氧化硫的; 高灵敏检测,最低检出浓度达1 mg; kg~(-1)的水平.针对实际样本的传统蒸馏法前处理流程的一些不足以及SERS检测的指纹图谱优势,本文进行了三方面显著改进:; (1)碳酸钙和沸石取代氮气以提高二氧化硫的挥发提取效率; (2)草酸取代盐酸酸化蒸馏溶液,以有效避免挥发性强酸对操作环境的危害;; (3)氢氧化钠溶液代替乙酸铅溶液作为吸收液,以防止二次污染.环境友好、灵敏度高和不受基质干扰等特点使得本方法有望取代经典蒸馏法和比色法,用于食品; 中非法添加二氧化硫类添加剂的快速高效筛查.The direct detection of sulphur dioxide has been realized in various; food matrixes with high sensitivity and high selectivity, on the basis; of the integration of the high energy resolution of the finger-print; spectrum of surface-enhanced Raman spectroscopy and the universal but; easy-on-going pretreatment procedure. The characteristic peak of sulphur; dioxide at ~630 cm~(-1) was applied as the qualitative and quantitative; standard, which displayed a lowest detectable concentration at the 1 mg; kg~(-1) level for the spiked food samples. The key point of the high; sensitivity and selectivity is the effective pretreatment born out of; the standard distillation one, which has been improved in the three; parts. (1) Using CaCO_3 and Zeolite instead of N_2 gas as the bubbling; reagent. (2) Using oxalic acid as the acidic distillation solution to; eliminate the hazards from acid volatilization, such as hydrochloric; acid. (3) Using diluted sodium hydroxide solution as the absorption; reagent instead of lead acetate solution to avoid the secondary; pollution. With the three distinguished advantages of environment; friendly, high sensitivity and free of matrix interference, the proposed; method has great potential to replace the traditional ones for the fast; screening of the illegal or abused sulphur dioxide in food.国家自然科学基金; 福建省高校产学合作项目; 中央高校基本科研业务费专项资

裁判員裁判における評議パターンの提案 : 質的・量的分析の統合から

departmental bulletin pape

Zooplanktonic diversity in the western Pacific

西太平洋区是全球海洋生物种源中心,许多类群的最高物种多样性都出现于该区域,因此,在该区开展种类多样性的研究不仅重要和必要,而且具有在跨国尺度上进行综合管理和相互合作的迫切性。本文在西太平洋的浮游动物样品鉴定分类、编目、文献资料整理和分析的基础上,记录和编入西太平洋10个浮游动物类群2,658种(含亚种),隶属于206科675属,其中水螅水母类99科251属697种,栉水母类12科22属59种,浮游软体动物14科35属86种,介形类8科89属416种,桡足类51科156属908种,糠虾类4科58属202种,磷虾类2科8属56种,十足类8科22属105种,毛颚类5科8属48种,被囊类5科26属81种。The western Pacific region has been operating as a centre for the origin of marine biodiversity: the richest diversity of many marine taxa was found in these waters.Therefore,biodiversity research and con-servation efforts in this area are necessary in order to promote the integrative and international management of this resource.The present work is a compilation of numbers of all the families,genera and species of ma-jor taxa of zooplankton known in the western Pacific Ocean(106°–150°E,0°–44°N).In all,2,658 zooplank-tonic species(including subspecies) belonging to 206 families and 675 genera have been recorded from taxonomic identifications and literature,99 families,251 genera and 697 species belong to the Medusozoa,12 families,22 genera and 59 species to the Ctenophora,14 families,35 genera and 86 species to the pelagic Molluscs(Pteropoda and Heteropoda),8 families,89 genera and 416 species to the Ostracoda,51 families,156 genera and 908 species to the Copepoda,4 families,58 genera and 202 species to the Mysidcea,2 fami-lies,8 genera and 56 species to the Euphausiacea,8 families,22 genera and 105 species to the Decapoda,5 families,8 genera and 48 species to the Chaetognatha,5 families,26 genera and 81 species to the Tunicata.908专项“中国海洋生物种类名录和图谱”(908-ZC-II-02)和908专项海洋生物样品库;科技部基础工作专项“我国和邻近西北太平洋海洋生物物种编目和分布图集编制”(2006FY220700

Diurnal vertical migration of planktonic Ostracoda in IONESS system

根据IONESS系统对浮游动物的分层采样结果,研究浮游介形动物的昼夜垂直移动.浮游介形类存在着整个类群的昼夜垂直移动,白天其丰度最大值记录于200～300m层,并往上层水域递减,而夜间则明显往上层密集,丰度最大值提升至50～100m层;就物种多样性而言,由于工作水层(0～1000m)以深水层的众多种类于夜间上升至1000m以浅水层,导致工作水层内总种数由白天的49种剧增至夜间的78种,增幅达60%,各分层的种类数都有较明显的增加,750～1000m层的增幅最大,达150%,其次为50～100m层(增幅达125%);各种浮游介形类有不同的昼夜垂直移动模式,但绝大多数种类属于夜间上升型,少数种类属于不敏感类型,极少数种类却具夜间下降的移动特点.浮游介形类虽具明显的昼夜垂直移动,但这一变动往往局限于一定水深范围,从而反映出介形类的层状分布特点,可划分为广深分布型、上层分布型、中层分布型和下层分布型.The diurnal vertical migration of planktonic Ostracoda is studied based on the analysis of stratified samples of zooplanktons in the IONESS system. The whole taxa of planktonic Ostracoda migrates vertically and diurnally, its greatest abundance by day occurs at 200～300 m layer and decreases upward and at night occurs at 50～100 m layer but increases upward. Numerous species at the layers lower than the working layer (0～1 000 m) migrate upward at night to the layers shallower than 1 000 m. As a result, the total number of species in the working layer increases sharply from 49 species by day to 78 species at night, with an increase amplitude of 60%. The number of species increases rather distinctly at various layers, firstly at the layer of 750～1 000 m with an amplitude of 150% and secondly at the layer of 50～100 m with an amplitude of 125%. Different planktonic Ostracoda takes different mode of diurnal vertical migration, a great majority of species take the mode of upward migration at night, less number of species take insensitive mode and a fewer number of species take the mode of downward migration at night. The diurnal vertical migration of planktonic Ostracoda, which is distinct in this regard, is restricted in a certain water depth, demonstrating its features of stratified distribution. Ostracoda may be classified into four modes of distribution, namely, eurybathy distribution mode, upper-layer distribution mode, mid-layer distribution mode and lower-layer distribution mode

Response of some zooplankton to the El Nio in the sea the east of Taiwan Island

国家自然科学基金资助项目(5997604759979025);; 国家"十五""863"计划资助项目(2001AA516010);; 国家杰出青年基金资助项目(50125924)