Advances for the Ruthenium Complexes-Based Homogeneous Catalytic Hydrogenation of Oxalates to Ethylene Glycol

草酸酯加氢是重要的有机化学反应,在工业制乙二醇生产中有着重要的应用.对钌金属配合物均相催化反应的研究进行了综述.以催化反应体系为焦点,探讨了多种; 因素如温度、氢气压力、催化剂浓度、反应时间、添加剂等对底物转化率以及产物选择性的影响,并讨论了催化反应机理,其中金属-配体协同促进的H_2分子异; 裂,进而完成对底物分子中酯基依次加氢的反应机理是探讨的重点,这为新型催化剂的设计和应用提供参考.Hydrogenation of oxalates is one of the important organic reactions, which has an ultimate use for the industrial production of ethylene glycol. The studies on the ruthenium complexes-based homogeneous catalytic reaction systems are herein summarized. With the focus on the catalytic reaction systems, the important factors with significant influences on the oxalate transformation efficiency as well as the product selectivity are discussed, including temperature, H-2 pressure, catalyst concentration, reaction duration, additives, and so on. The catalytic reaction mechanisms are also discussed in detail, where the mechanism for the H-2-heterolysis promoted under the metal-ligand cooperation for the oxalate hydrogenation to ethylene glycol is enhanced. This study would be useful for designing the new catalyst applicable in industry.National Natural Science Foundation of China [21473142, 91545115,; 21473145]; Innovative Research Team of China [IRT_14R31, J1310024

人肝细胞内戊型肝炎病毒结合蛋白的酵母双杂交筛选

为进一步深入研究戊型肝炎病毒(HEV)感染机制以及致病机理,用酵母双杂交系统从人肝细胞cDNA文库中筛选与戊型肝炎病毒衣壳蛋白E2相互作用的蛋白,核酸序列分析及同源性检索表明,4个克隆与E2相互作用,其中一个克隆与P38IP高度同源,细胞免疫共沉淀实验结果显示:在哺乳动物细胞水平仍能够检测到E2与P38IP片段的特异的相互作用

扬州跳水游泳馆钢屋盖双向索桁架设计

扬州跳水游泳馆下部为3层钢筋混凝土框架结构,上部为钢结构屋面,钢结构屋面东西向长135.5m,南北向长71.7m,为大跨度承重杂交空间结构体系,主要包含正交平面桁架,单层网壳,正交双向索桁架3种空间结构形式。本文重点介绍了该工程中正交双向索桁架的结构布置方案及受力特点,详细给出了双向索桁架的找形分析,各种组合工况下非线性荷载态分析的过程及计算结果,并对两种软件的计算结果进行了分析。文章最后介绍了本工程中采用的大型索结构施工模拟分析方法,详细给出了桁架及网壳安装完成并拆撑、双向索桁架从高空引线就位到膜材安装完成每个施工步骤中结构的内力和位移状态,得到一些有价值的结论,供类似的工程设计参考

大功率LED热管散热器的模块化设计与研究

针对当前大功率LED散热器多采用肋片式散热器,散热效果不是很理想,同时当前灯具都采用一体化的集成结构,在维护和检修的过程中,只能整体返厂,给大功率LED灯具的使用带来不便等问题,提出了大功率LED热管散热器模块化思路。通过模块化设计,大功率LED的散热效果得到了提高,且能够进行及时的维护,多数部件可以循环利用,延长了灯具的生命周期,降低了维修成本。对大功率LED热管散热器模块进行了设计优化,并且通过ICEPAK散热软件进行了模拟,结果表明此热管散热器模块大大提高了大功率LED的散热性能

氦喷嘴激光离子源离线系统的实验结果

简要介绍了建立在清华大学的氦喷嘴激光离子源离线系统．并给出了在氦喷嘴出口处激光直接共振电离喷束中的钠原子的实验结果．此结果表明，在氦喷嘴出口处，用激光在束电离钠原子是可行的．由此出发可设计具有Ｚ选择性、效率高、可测同位素寿命下限低又能适用于高温难熔元素的激光离子源

Yield analysis of large-area high-power single-chip GaN-based light- emitting diodes with network design

<span font-size:="" lang="EN-US" mso-ansi-language:="" mso-ascii-theme-font:="" mso-bidi-font-family:="" mso-bidi-font-size:="" mso-bidi-language:="" mso-bidi-theme-font:="" mso-fareast-font-family:="" mso-fareast-language:="" mso-fareast-theme-font:="" mso-hansi-theme-font:="" new="" style="font-family: " times=""><font color="#000000">: In this Letter, a GaN-based high-power (HP) single-chip (SC) large-area LED with parallel and series network structure is fabricated. The optical characteristics of the HP-SC LED is investigated. Driven at 600 mA, the optical output power of the HP-SC LED chip is measured to be 9.7 W, corresponding to an EQE of 26.4%, which is 19.6% lower than that of the standard small LED cell due to both the lateral light-extraction efficiency degradation and the self-heating effect. A statistical analysis was carried out to investigate the yield of the fabricated HP-SC LEDs, the experimental results agree with the theoretical calculations very well, validating the feasibility of this design on the production yield for the large-area LEDs.</font></span