熵函数的一种引入法

从数学上证明δQ_R/T可由全微分入手;结合几个常见的可逆循环过程,较为简明地介绍一种熵函数的引入法。该方法既省去了经典方法的烦琐推理,也避免了单刀直入式定义的困惑;不失热力学的严谨性,同时也有益于第一定律和第二定律的衔接

An Assembly Route to Inorganic Catalytic Nanoreactors Containing Sub-10-nm Gold Nanoparticles with Anti-Aggregation Properties

通讯作者地址: Zheng, NF (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China 3. Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA 电子邮件地址: [email protected], [email protected] Ministry of Education,108077 NNSFC,20871100 20721001 20423002 MSTC,2007CB815303 2009CB930703 NFFTBS,J063042

The Study of Polymerization of Aniline by Thermokinetic Method

根据热动力学的基本理论方法,研究了苯胺-盐酸反应体系,实验结果验证了本方法的正确性.在为苯胺聚合反应的动力学参数测定提供了一种新的实验手段的同时,也为苯胺聚合反应的速率控制、机理研究提供了理论依据.The purpose of this paper is to derive several dynamics of the equations suit to common non-reversible reaction and to establish new method to resolve first order reaction and second order reaction according to thermokinetic basic theory.The polymerization of aniline using the method was studied.The results confirmed the accuracy of the method.国家基础科学人才培养基金(J0630429)资