根据热动力学的基本理论方法,研究了苯胺-盐酸反应体系,实验结果验证了本方法的正确性.在为苯胺聚合反应的动力学参数测定提供了一种新的实验手段的同时,也为苯胺聚合反应的速率控制、机理研究提供了理论依据.The purpose of this paper is to derive several dynamics of the equations suit to common non-reversible reaction and to establish new method to resolve first order reaction and second order reaction according to thermokinetic basic theory.The polymerization of aniline using the method was studied.The results confirmed the accuracy of the method.国家基础科学人才培养基金(J0630429)资
