103 research outputs found
Effects of long-range disorder and electronic interactions on the optical properties of graphene quantum dots
We theoretically investigate the effects of long-range disorder and
electron-electron interactions on the optical properties of hexagonal armchair
graphene quantum dots consisting of up to 10806 atoms. The numerical
calculations are performed using a combination of tight-binding, mean-field
Hubbard and configuration interaction methods. Imperfections in the graphene
quantum dots are modelled as a long-range random potential landscape, giving
rise to electron-hole puddles. We show that, when the electron-hole puddles are
present, tight-binding method gives a poor description of the low-energy
absorption spectra compared to meanfield and configuration interaction
calculation results. As the size of the graphene quantum dot is increased, the
universal optical conductivity limit can be observed in the absorption
spectrum. When disorder is present, calculated absorption spectrum approaches
the experimental results for isolated monolayer of graphene sheet
Effects of random atomic disorder on the magnetic stability of graphene nanoribbons with zigzag edges
We investigate the effects of randomly distributed atomic defects on the
magnetic properties of graphene nanoribbons with zigzag edges using an extended
mean-field Hubbard model. For a balanced defect distribution among the
sublattices of the honeycomb lattice in the bulk region of the ribbon, the
ground state antiferromagnetism of the edge states remains unaffected. By
analyzing the excitation spectrum, we show that while the antiferromagnetic
ground state is susceptible to single spin flip excitations from edge states to
magnetic defect states at low defect concentrations, it's overall stability is
enhanced with respect to the ferromagnetic phase.Comment: 5 pages, 4 figure
Planar bilayer metamaterial with left-handed transmission and negative refraction at microwave frequencies
A planar composite metamaterial consisting of bilayers of metal cutwire pairs and long wire pairs which are separated by a thin dielectric layer is designed and fabricated for microwave frequencies. The simulated and experimentally measured transmission spectra of the metamaterial and its individual components (cutwire-only and wire-only) indicates that the metamaterial exhibits a transmission band within the common stop bands of its components, and thus acts as a medium with negative index of refraction. The existence of n < 0 is further supported by a refraction experiment. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA
Multi-elemental speciation analysis of barley genotypes diering in tolerance to cadmium toxicity using SEC-ICP-MS and ESI-TOF-MS
Plants respond to Cd exposure by synthesizing heavy-metal-binding oligopeptides, called phytochelatins (PCs). These peptides reduce the activity of Cd2+ ions in the plant tissues by forming Cd chelates. The main objective of the present work was to develop an analytical technique, which allowed identication of the most prominent Cd species in plant tissue by SEC-ICP-MS and ESI-TOF-MS. An integrated part of the method development was to test the hypothesis that dierential Cd tolerance between two barley genotypes was linked to dierences in Cd speciation. Only one fraction of Cd species, ranging from 7001800 Da, was detected in the shoots of both genotypes. In the roots, two additional fractions ranging from 29004600 and 670015 000 Da were found. The Cd-rich SEC fractions were heart-cut, de-salted and demetallized using reversed-phase chromatography (RPC), followed by ESI-MS-TOF to identify the ligands. Three dierent families of PCs, viz. (gGlu-Cys)n-Gly (PCn), (gGlu-Cys)n-Ser (iso-PCn) and Cys-(gGlu-Cys)n-Gly (des-gGlu-PCn), the last lacking the N-terminal amino acid, were identied. The PCs induced by Cd toxicity also bound several essential trace elements in plants, including Zn, Cu, and Ni, whereas no Mn species were detected. Zn, Cu and Ni-species were distributed between the 7001800 Da and 670015 000 Da fractions, whereas only Cd species were found in the 29004600 Da fraction dominated by PC3 ligands. Although the total tissue concentration of Cd was similar for the two species, the tolerant barley genotype synthesized signicantly more CdPC3 species with a high Cd specicity than the intolerant genotype, clearly indicating a correlation between Cd tolerance and the CdPC speciation
Bismuth(III) bromide-thioamide complexes: synthesis, characterization and cytotoxic properties
New bismuth(III) bromine compounds of the heterocyclic thioamides were prepared and structurally characterized. The reaction of heterocyclic thioamides with bismuth(III) bromide resulted in the formation of the {[BiBr2(mu(2)-Br)(MMI)(2)](2)center dot CH3COCH3 center dot H2O} (1), {[BiBr2(MBZIM)(4)]center dot Br center dot 2H(2)O} (2), {[BiBr2(mu(2)-Br)(tHPMT)(2)](2)center dot CH3CN} (3), {[BiBr2(mu(2)-Br)(PYT)(2)](2)center dot CH3CN} (4) and {[BiBr2(mu(2)-Br)(MBZT)(2)](2) 2CH(3)OH} (5) complexes (MMI: 2-mercapto-1-methylimidazole, MBZIM: 2-mercaptobenzimidazole, tHPMT: 2-mercapto-3,4,5,6-tetrahydro-pyrimidine, PYT: 2-mercaptopyridine and MBZT: 2-mercaptobenzothiazole). The complexes 1-5 were characterized by melting point (m.p.), elemental analysis (c.a.), molar conductivity, Fourier-transform infrared (FT-IR), Fourier-transform Raman (FT-Raman), nuclear magnetic resonance (H-1 and (CNMR)-C-13) spectroscopy, UV-Vis spectroscopy and thermogravimetric-differential thermal analysis (TG-DTA). The molecular structures of 1-5 were determined by single-crystal X-ray diffraction. Complex 2 is a first ionic monomuclear octahedral bismuth(III) bromide, while the complexes 1,3-5 are the first examples of dinuclear bismuth(III) bromide derivatives. Complexes 1-5 were evaluated in terms of their in vitro cytotoxic activity against human adenocarcinoma breast (MCF-7) and cervix (HeLa) cells. The toxicity on normal human fetal lung fibroblast cells (MRC-5) was also evaluated. Moreover, the complexes 1-5 and free heterocyclic thioamide ligands were studied upon the catalytic peroxidation of the linoleic acid by the enzyme lipoxygenase (LOX).Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [114Z457](a) I.I.O. and M.C. acknowledge the financial support from The Scientific and Technological Research Council of Turkey (TUBITAK, Project No. 114Z457). (b) CNB and SKH would like to thank the Unit of Bioactivity Testing of Xenobiotics of the University of Ioannina for providing access to their facilities. (c) The International Graduate Program in 'Biological Inorganic Chemistry', which operates at the University of Ioannina within the collaboration of the Departments of Chemistry of the Universities of Ioannina, Athens, Thessaloniki, Patras, Crete and the Department of Chemistry of the University of Cyprus (http://bic.chem.uoi.gr/BIC-En/index-en.html), is acknowledged for the stimulating discussion forum
Effect of molecular and electronic structure on the light harvesting properties of dye sensitizers
The systematic trends in structural and electronic properties of perylene
diimide (PDI) derived dye molecules have been investigated by DFT calculations
based on projector augmented wave (PAW) method including gradient corrected
exchange-correlation effects. TDDFT calculations have been performed to study
the visible absorbance activity of these complexes. The effect of different
ligands and halogen atoms attached to PDI were studied to characterize the
light harvesting properties. The atomic size and electronegativity of the
halogen were observed to alter the relaxed molecular geometries which in turn
influenced the electronic behavior of the dye molecules. Ground state molecular
structure of isolated dye molecules studied in this work depends on both the
halogen atom and the carboxylic acid groups. DFT calculations revealed that the
carboxylic acid ligands did not play an important role in changing the
HOMO-LUMO gap of the sensitizer. However, they serve as anchor between the PDI
and substrate titania surface of the solar cell or photocatalyst. A
commercially available dye-sensitizer, ruthenium bipyridine (RuBpy), was also
studied for electronic and structural properties in order to make a comparison
with PDI derivatives for light harvesting properties. Results of this work
suggest that fluorinated, chlorinated, brominated, and iyodinated PDI compounds
can be useful as sensitizers in solar cells and in artificial photosynthesis.Comment: Single pdf file, 14 pages with 7 figures and 4 table
New physics effects to the lepton polarizations in the B -> K l^+ l^- decay
Using the general, model independent form of the effective Hamiltonian, the
general expressions of the longitudinal, normal and transversal polarization
asymmetries for (l^-) and (l^+) and combinations of them for the exclusive (B
-> K l^+ l^-) decay are found. The sensitivity of lepton polarizations and
their combinations on new Wilson coefficients are studied. It is found that
there exist regions of Wilson coefficients for which the branching ratio
coincides with the Standard Model result while the lepton polarizations differ
substantially from the standard model prediction. Hence, studying lepton
polarization in these regions of new Wilson coefficients can serve as a
promising tool for establishing new physics beyond the Standard Model.Comment: 18 pp, 14 figures (postscript formatted), LaTex formatte
Author Correction: Elucidating causative gene variants in hereditary Parkinson’s disease in the Global Parkinson’s Genetics Program (GP2)
Correction to: s41531-023-00526-9 npj Parkinson’s Disease, published online 27 June 2023 In this article the Global Parkinson’s Genetics Program (GP2) members names and affiliations were missing in the main author list of the Original article which are listed in the below
Defining the causes of sporadic Parkinson’s disease in the global Parkinson’s genetics program (GP2)
The Global Parkinson’s Genetics Program (GP2) will genotype over 150,000 participants from around the world, and integrate genetic and clinical data for use in large-scale analyses to dramatically expand our understanding of the genetic architecture of PD. This report details the workflow for cohort integration into the complex arm of GP2, and together with our outline of the monogenic hub in a companion paper, provides a generalizable blueprint for establishing large scale collaborative research consortia
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