Etude d'architectures et d'empilements innovants de mémoires Split-Gate (grille séparée) à couche de piégeage discret

Du fait de l'augmentation de la demande de produits pour les applications grand public, industrielles et automobiles, des mémoires embarquées fiables et à faible coût de fabrication sont de plus en plus demandées. Dans ce contexte, les mémoires split-gate à piégeage discret sont proposées pour des microcontrôleurs. Elles combinent l'avantage d'une couche de stockage discrète et de la con guration split-gate. Durant ce travail de recherche, des mémoires split-gate à couche de piégeage discret ayant des longueurs de grille de 20nm sont présentées pour la première fois. Celles-ci on été réalisées avec des nanocristaux de silicium (Si-nc), du nitrure de silicium (SiN) ou un hybride Si-nc/SiN avec diélectrique de control de type SiO2 ou AlO et sont comparées en termes de performances lors des procédures d'eff acement et de rétention. Ensuite, la miniaturisation des mémoires split-gate à piégeage de charge est étudié, en particulier au travers de l'impact de la réduction de la longueur de grille sur la fenêtre de mémorisation, la rétention et la consommation. Le rôle des défauts dans le diélectrique de contrôle (alumine) utilisé dans les mémoires de type TANOS a été étudié. Des travaux ont été menés pour déterminer l'origine des pièges dans ce matériau, par le biais de la simulation atomistique ainsi que d'analyses physico-chimiques précises. Nous avons montré que la concentration de pièges dans AlO pouvait être réduite par ajustement des conditions de procédé de fabrication, débouchant ainsi sur l'amélioration de la rétention dans les mémoires à piégeage de charge. Ce résultat est convenable pour les applications de type embarquéDue to the increasing demand for consumer, industrial and automotive products, highly reliable, and low integration cost embedded memories are more and more required. In this context, split-gate charge trap memories were proposed for microcontroller products, combining the advantage of a discrete storage layer and of the split-gate con guration. In this thesis, split-gate charge trap memories with electrical gate length down to 20nm are presented for the 1st time. Silicon nanocristals (Si-nc), or silicon nitride (SiN) and hybrid Si-nc/SiN based split-gate memories, with SiO2 or AlO control dielectrics, are compared in terms of program erase and retention. Then, the scalability of split-gate charge trap memories is studied, investigating the impact of gate length reduction on the memory window, retention and consumption. We thus studied the role of defects on alumina control dielectric employed in TANOS-like memory. We used atomistic simulation, consolidated by a detailed alumina physico-chemical material analysis, to investigate the origin of traps in alumina. We showed that the trap concentration in AlO can be decreased by adjusting the process conditions leading to improved retention behaviour in charge trap memory, suitable for embedded applications.SAVOIE-SCD - Bib.électronique (730659901) / SudocGRENOBLE1/INP-Bib.électronique (384210012) / SudocGRENOBLE2/3-Bib.électronique (384219901) / SudocSudocFranceF

Design, Modeling and Analysis of Non-classical Field Effect Transistors

Transistor scaling following per Moore\u27s Law slows down its pace when entering into nanometer regime where short channel effects (SCEs), including threshold voltage fluctuation, increased leakage current and mobility degradation, become pronounced in the traditional planar silicon MOSFET. In addition, as the demand of diversified functionalities rises, conventional silicon technologies cannot satisfy all non-digital applications requirements because of restrictions that stem from the fundamental material properties. Therefore, novel device materials and structures are desirable to fuel further evolution of semiconductor technologies. In this dissertation, I have proposed innovative device structures and addressed design considerations of those non-classical field effect transistors for digital, analog/RF and power applications with projected benefits. Considering device process difficulties and the dramatic fabrication cost, application-oriented device design and optimization are performed through device physics analysis and TCAD modeling methodology to develop design guidelines utilizing transistor\u27s improved characteristics toward application-specific circuit performance enhancement. Results support proposed device design methodologies that will allow development of novel transistors capable of overcoming limitation of planar nanoscale MOSFETs. In this work, both silicon and III-V compound devices are designed, optimized and characterized for digital and non-digital applications through calibrated 2-D and 3-D TCAD simulation. For digital functionalities, silicon and InGaAs MOSFETs have been investigated. Optimized 3-D silicon-on-insulator (SOI) and body-on-insulator (BOI) FinFETs are simulated to demonstrate their impact on the performance of volatile memory SRAM module with consideration of self-heating effects. Comprehensive simulation results suggest that the current drivability degradation due to increased device temperature is modest for both devices and corresponding digital circuits. However, SOI FinFET is recommended for the design of low voltage operation digital modules because of its faster AC response and better SCEs management than the BOI structure. The FinFET concept is also applied to the non-volatile memory cell at 22 nm technology node for low voltage operation with suppressed SCEs. In addition to the silicon technology, our TCAD estimation based on upper projections show that the InGaAs FinFET, with superior mobility and improved interface conditions, achieve tremendous drive current boost and aggressively suppressed SCEs and thereby a strong contender for low-power high-performance applications over the silicon counterpart. For non-digital functionalities, multi-fin FETs and GaN HEMT have been studied. Mixed-mode simulations along with developed optimization guidelines establish the realistic application potential of underlap design of silicon multi-Fin FETs for analog/RF operation. The device with underlap design shows compromised current drivability but improve analog intrinsic gain and high frequency performance. To investigate the potential of the novel N-polar GaN material, for the first time, I have provided calibrated TCAD modeling of E-mode N-polar GaN single-channel HEMT. In this work, I have also proposed a novel E-mode dual-channel hybrid MIS-HEMT showing greatly enhanced current carrying capability. The impact of GaN layer scaling has been investigated through extensive TCAD simulations and demonstrated techniques for device optimization

Top-down Si nanowire technology in discrete charge storage nonvolatile memory application

Ph.DDOCTOR OF PHILOSOPH

High performance floating gate memories using graphene as charge storage medium and atomic layer deposited high-k dielectric layers as tunnel barrier

Ankara : Materials Science and Nanotechnology Program of the Graduate School of Engineering and Science of Bilkent Univerity, 2013.Thesis (Master's) -- Bilkent University, 2013.Includes bibliographical references leaves 87-98.With the ongoing development in portable electronic devices, low power consumption, improved data retention rate and higher operation speed are the merits demanded by modern non-volatile memory technology. Flash memory devices with discrete charge-trapping media are regarded as an alternative solution to conventional floating gate technology. Flash memories utilizing Sinitride as charge storage media dominate due to enhanced endurance, better scaling capability and simple fabrication. The use of high-k dielectrics as tunnel layer and control layer is also crucial in charge-trap flash memory devices since they allow further scaling and enhanced charge injection without data retention degradation. Atomic layer deposition (ALD) is a powerful technique for the growth of pinhole-free high-k dielectrics with precisely controlled thickness and high conformality. The application of graphene as charge trapping medium in flash memory devices is promising to obtain improved charge storage capability with miniaturization. Graphene acts as an effective charge storage medium due to high density of states in deep energy levels. In this thesis, we fabricate graphene flash memory devices with ALD-grown HfO2/AlN as tunnel layer and Al2O3 as control layer. Graphene oxide nanosheets are derived from the acid exfoliation of natural graphite by Hummers Method. The graphene layer is obtained by spin-coating of water soluble graphene oxide suspension followed by a thermal annealing process. Memory performance including hysteresis window, data retention rate and program transient characteristics for both electron and hole storage mechanisms are determined by performing high frequency capacitance-voltage measurements. For comparing the memory effect of graphene on device performance, we also fabricate and characterize identical flash capacitors with Si-rich SiN layer as charge storage medium and HfO2 as tunnel oxide layer. The Si-nitride films are deposited with high SiH4/NH3 gas flow ratio by plasma-enhanced chemical vapor deposition system. Graphene flash memory devices exhibit superior memory performance. Compared with Si-nitride based cells, hysteresis window, retention performance and programming speed are both significantly enhanced with the use of graphene. For electron storage, graphene flash memory provides a saturated flat band shift of 1.2 V at a write-pulse duration of 100 ns with a voltage bias of 5 V. The high density of states and high work function of graphene improve the memory performance, leading to increased charge storage capability, enhanced retention rate and faster programming operation at low voltages. The use of graphene as charge storage medium and ALD-grown high-k dielectrics as tunnel and control layers improves the existing flash technology and satisfies the requirements including scalability, at least 10-year retention, low voltage operation, faster write performance and CMOS-compatible fabrication.Kocaay, DenizM.S

Organic molecular floating gate memories

Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, 2011.Cataloged from PDF version of thesis.Includes bibliographical references (p. 42-45).Flash memory devices dominate the non-volatile memory market, with device structures that utilize charge storage in polysilicon floating gates imbedded in insulating silicon oxide films'. As demands for high storage density, high chip memory capacity, and decreasing process costs continue to mount, conventional flash memory has found it challenging to continue scaling and it may reach fundamental scaling limits because of the minimum tunnel oxide thickness and poor charge retention due to defects in the tunneling oxide, necessitating modification in the implementation of the flash memory technology . In this study nano-segmented floating gate memories consisting of a uniform set of identical organic dye molecules were fabricated and evaluated for potential use as programmable charge storage and charge retention elements in a future flash memory technology. Viability of molecular thin films to serve as an energetically-uniform set of ~1nm in size charge- retaining sites is tested on a series of molecular materials, the best performing of which are thermally evaporated thin films of 3,4,9,10- perylenetetracarboxylic bis-benzimidazole (PTCBI). The initial results show device durability over 105 program/erase cycles, with hysteresis window of up to 3.3V, corresponding to charge storage density as high as 5 x 1012 cm2. Data shows that charge retention is improved for molecular films with lower carrier mobility, which for the first time experimentally confirms in a coherent material set that inhibiting charge transport by nano-segmented floating-gate structures benefits the memory retention. These results show a first step towards a possible approach to miniaturization of non-volatile memory by using molecules as segmented charge storage elements in the floating gate flash memory technology.by Sarah Paydavosi.S.M

Tunnel Field Effect Transistors:from Steep-Slope Electronic Switches to Energy Efficient Logic Applications

The aim of this work has been the investigation of homo-junction Tunnel Field Effect Transistors starting from a compact modelling perspective to its possible applications. Firstly a TCAD based simulation study is done to explain the main device characteristics. The main differences of a Tunnel FET with respect to a conventional MOSFET is pointed out and the differences have been explained. A compact DC/AC model has been developed which is capable of describing the I-V characteristics in all regimes of operation. The model takes in to account ambi-polarity, drain side breakdown and all tunneling related physics. A temperature dependence is also added to the model to study the temperature independent behavior of tunneling. The model was further implemented in a Verilog-A based circuit simulator. Following calibration to experimental results of Silicon and strained-Silicon TFETs, the model has been also used to benchmark against a standard CMOS node for digital and analog applications. The circuits built with Tunnel FETs showed interesting temperature behavior which was superior to the compared CMOS node. In the same work, we also explore and propose solutions for using TFETs for low power memory applications. Both volatile and non-volatile memory concepts are investigated and explored. The application of a Tunnel FET as a capacitor-less memory has been experimentally demonstrated for the first time. New device concepts have been proposed and process flows for the same are developed to realize them in the clean room in EPFL