Fabrication and Characterization of Supercapacitors toward Self-Powered System

Ever increasing energy demand urges to impelled extensive research in the development of new eco-friendly energy harvesting and storage technologies. Energy harvesting technology exploiting renewable energy sources is an auspicious method for sustainable, autonomous, and everlasting operation of a variety of electronic devices. A new concept of an integrated self-powered system by combining an energy harvesting device with an energy storage device has been established to harvest renewable energy and simultaneously store it for sustainable operation of electronic devices. In this chapter, describes the fabrication of a self-powered system by integrating the supercapacitor with energy harvesting devices such as nanogenerator and solar cells to power portable electronic devices. Initially synthesis and electrochemical characterization of various electroactive materials for supercapacitors and further, fabrication of supercapacitor device were discussed. In conclusion, this chapter demonstrates self-powered system by the integration of energy harvesting, energy storage module with portable electronic devices. The various result validates the feasibility of using supercapacitors as efficient energy storage components in self-powered devices. The proposed self-powered technology based on energy conversion of renewable energy to electrical energy which stored in energy storage device and it will be used to operate several electronic devices as a self-powered device

Applications of Additive Manufacturing Technologies to Ambient Energy Harvesters for Microwave and Millimeter-Wave Autonomous Wireless Sensing Networks and 3D Packaging Integration

The objectives of my researches are developing new RF and mm-wave energy harvester topologies and realizing them with new additive manufacturing fabrication processes. The proposed energy harvester topologies are utilized to achieve energy-autonomous wireless sensing networks for 5G communication and IoT solutions. The developed additive manufacturing fabrication process is adopted to realize not only energy harvesters but also mm-wave IC packaging process. Ambient energy harvesting techniques collect ambient energy such as solar, RF, heat, and vibration and convert them into DC power sources to support the energy requirement of electronics. Since the energy is provided autonomously and constantly, maintenance or replacement for the batteries inside wireless electronics is not necessary resulting in enormous cost reduction. The researches of energy harvester focus on three categories, new topologies to enhance the performances, increased harvested power levels, and applied energy harvester to find new killer applications. This work proposes new designs and improvements in all three categories. Various proof-of-concept backscattered sensing systems with integrated RF energy harvesters for 5G and IoT applications are demonstrated. In this research, high-efficiency and broadband rectifiers are proposed to support high-performance rectifications as well as increase harvested energy. New topologies to utilize both DC and harmonics are demonstrated to increase the reading range of on-body wireless sensing networks. Furthermore, energy-autonomous microfluidic sensing systems are demonstrated to unleash the potential of microfluidic applications. 5G energy harvester is proposed and integrated inside the multi-layered additive manufacturing IC packages to achieve fully-functional SiP modules. While determining the fabrication methods, low-cost, fast-prototyping, and scalable methods with great material and structural flexibilities are preferable, and thus, additive manufacturing technologies including inkjet printing, 3D printing, and glass semi-additive patterning process are adopted. This research utilizes inkjet-printed masks, substrates, and metal traces to simplify the conventional fabrication process. The new low-loss inkjet-printable ink is developed to push the additive manufacturing technologies to mm-wave ranges. The flexible 3D-printed materials are characterized and used for wearable sensor designs, microfluidic channels, and flexible packaging topologies. The 3D features are included inside the IC packages to achieve high-performance multi-layer packaging structures with shorter lengths, lower loss, and smaller parasitics. The high-precision glass semi-additive patterning process is used to realized AiP and SiP designs with great performances. Furthermore, through combining inkjet and 3D printing, this work proposes a fast, cost-effective, scalable, and environmentally-friendly fabrication process for various high-performance and compact antenna designs, microwave/mm-wave components, microfluidic channels, RF energy harvesters, and SiP designs. In summary, this work utilizes additive manufacturing processes to realize various innovative topologies of energy harvesters to harvest more power and achieve higher rectification efficiency with smaller sizes. Additive manufacturing processes and energy harvesting techniques are also used to demonstrate new applications including the first on-body long-range sensing network, the first energy-autonomous long-range microfluidic sensing system, and the first fully-functional energy-autonomous 5G SiP module design. The proposed topologies are suitable for smart cities, smart skin, and IoT applications.Ph.D

Recent Advances in Energy Harvesting from the Human Body for Biomedical Applications

Energy harvesters serve as continuous and long-lasting sources of energy that can be integrated into wearable and implantable sensors and biomedical devices. This review paper presents the current progress, the challenges, the advantages, the disadvantages and the future trends of energy harvesters which can harvest energy from various sources from the human body. The most used types of energy are chemical; thermal and biomechanical and each group is represented by several nano-generators. Chemical energy can be harvested with a help of microbial and enzymatic biofuel cells, thermal energy is collected via thermal and pyroelectric nano-generators, biomechanical energy can be scavenged with piezoelectric and triboelectric materials, electromagnetic and electrostatic generators and photovoltaic effect allows scavenging of light energy. Their operating principles, power ratings, features, materials, and designs are presented. There are different ways of extracting the maximum energy and current trends and approaches in nanogenerator designs are discussed. The ever-growing interest in this field is linked to a larger role of wearable electronics in the future. Possible directions of future development are outlined; and practical biomedical applications of energy harvesters for glucose sensors, oximeters and pacemakers are presented. Based on the increasingly accumulated literature, there are continuous promising improvements which are anticipated to lead to portable and implantable devices without the requirement for batteries

New generation of interactive platforms based on novel printed smart materials

Programa doutoral em Engenharia Eletrónica e de Computadores (área de Instrumentação e Microssistemas Eletrónicos)The last decade was marked by the computer-paradigm changing with other digital devices suddenly becoming available to the general public, such as tablets and smartphones. A shift in perspective from computer to materials as the centerpiece of digital interaction is leading to a diversification of interaction contexts, objects and applications, recurring to intuitive commands and dynamic content that can proportionate more interesting and satisfying experiences. In parallel, polymer-based sensors and actuators, and their integration in different substrates or devices is an area of increasing scientific and technological interest, which current state of the art starts to permit the use of smart sensors and actuators embodied within the objects seamlessly. Electronics is no longer a rigid board with plenty of chips. New technological advances and perspectives now turned into printed electronics in polymers, textiles or paper. We are assisting to the actual scaling down of computational power into everyday use objects, a fusion of the computer with the material. Interactivity is being transposed to objects erstwhile inanimate. In this work, strain and deformation sensors and actuators were developed recurring to functional polymer composites with metallic and carbonaceous nanoparticles (NPs) inks, leading to capacitive, piezoresistive and piezoelectric effects, envisioning the creation of tangible user interfaces (TUIs). Based on smart polymer substrates such as polyvinylidene fluoride (PVDF) or polyethylene terephthalate (PET), among others, prototypes were prepared using piezoelectric and dielectric technologies. Piezoresistive prototypes were prepared with resistive inks and restive functional polymers. Materials were printed by screen printing, inkjet printing and doctor blade coating. Finally, a case study of the integration of the different materials and technologies developed is presented in a book-form factor.A última década foi marcada por uma alteração do paradigma de computador pelo súbito aparecimento dos tablets e smartphones para o público geral. A alteração de perspetiva do computador para os materiais como parte central de interação digital levou a uma diversificação dos contextos de interação, objetos e aplicações, recorrendo a comandos intuitivos e conteúdos dinâmicos capazes de tornarem a experiência mais interessante e satisfatória. Em simultâneo, sensores e atuadores de base polimérica, e a sua integração em diferentes substratos ou dispositivos é uma área de crescente interesse científico e tecnológico, e o atual estado da arte começa a permitir o uso de sensores e atuadores inteligentes perfeitamente integrados nos objetos. Eletrónica já não é sinónimo de placas rígidas cheias de componentes. Novas perspetivas e avanços tecnológicos transformaram-se em eletrónica impressa em polímeros, têxteis ou papel. Neste momento estamos a assistir à redução da computação a objetos do dia a dia, uma fusão do computador com a matéria. A interatividade está a ser transposta para objetos outrora inanimados. Neste trabalho foram desenvolvidos atuadores e sensores e de pressão e de deformação com recurso a compostos poliméricos funcionais com tintas com nanopartículas (NPs) metálicas ou de base carbónica, recorrendo aos efeitos capacitivo, piezoresistivo e piezoelétrico, com vista à criação de interfaces de usuário tangíveis (TUIs). Usando substratos poliméricos inteligentes tais como fluoreto de polivinilideno (PVDF) ou politereftalato de etileno (PET), entre outos, foi possível a preparação de protótipos de tecnologia piezoelétrica ou dielétrica. Os protótipos de tecnologia piezoresistiva foram feitos com tintas resistivas e polímeros funcionais resistivos. Os materiais foram impressos por serigrafia, jato de tinta, impressão por aerossol e revestimento de lâmina doctor blade. Para terminar, é apresentado um caso de estudo da integração dos diferentes materiais e tecnologias desenvolvidos sob o formato de um livro.This project was supported by FCT – Fundação para a Ciência e a Tecnologia, within the doctorate grant with reference SFRH/BD/110622/2015, by POCH – Programa Operacional Capital Humano, and by EU – European Union

Systems for pervasive electronics and interfaces

Energy Harvesting Active Networked Tags (EnHANTs) are a new type of wireless device in the domain between RFIDs and sensor networks. Future EnHANTs will be small, flexible, and self-powered devices that can be attached to everyday objects that are traditionally not networked to enable "Internet of Things" applications. This work describes the design and development of the EnHANT prototypes and testbed. The current prototypes use thin-film photovoltaics optimized for indoor light harvesting, form multihop networks using ultra-low-power Ultra-Wideband Impulse Radio (UWB-IR) transceivers, and implement energy harvesting adaptive networking protocols. The current testbed enables the evaluation of different algorithms by exposing individual prototypes to repeatable light conditions based on real-world irradiance data. New approaches to characterizing the energy available to energy harvesting devices were explored. A mobile data-logger was used to record the intensity of ambient light, determine the light source, and record the acceleration from motion during different real world activities. These traces were used to model the behavior of photovoltaic and inertial energy harvesters in real world deployments and can be replayed in the EnHANTs testbed. In addition, new techniques to evaluate the efficiency of different photovoltaic technologies under indoor illumination were developed. A proof-of-concept system was built to characterize photovoltaics under a standardized set of conditions in which the radiant intensity and spectral composition of the light source were systematically varied. Techniques to structure student research projects within the EnHANTs project were developed. Project-based learning approaches were implemented to engage students using real-world system development constraints. A survey of the students showed that this approach is an effective method for developing technical, professional, and soft skills. Open source hardware was also applied to EnHANTs project and extended into other domains. A laboratory-based class in flat panel display technology was developed. The course introduces fundamental concepts of display systems and reinforces these concepts through the fabrication of three display devices. A lab kit platform was developed to enable remote students to use low-cost, course specific hardware to complete the lab exercises remotely. This platform was also applied to external projects targeted at non-university students. A workshop was developed to teach artists, designers, and hobbyists how to design and build custom user interfaces using thin-film electronics and rapid prototyping tools. Surveys of the students and workshop participants showed that this platform is an effective teaching tool and can be easily adapted and expanded

3D printed pneumatic soft actuators and sensors: their modeling, performance quantification, control and applications in soft robotic systems

Continued technological progress in robotic systems has led to more applications where robots and humans operate in close proximity and even physical contact in some cases. Soft robots, which are primarily made of highly compliant and deformable materials, provide inherently safe features, unlike conventional robots that are made of stiff and rigid components. These robots are ideal for interacting safely with humans and operating in highly dynamic environments. Soft robotics is a rapidly developing field exploiting biomimetic design principles, novel sensor and actuation concepts, and advanced manufacturing techniques. This work presents novel soft pneumatic actuators and sensors that are directly 3D printed in one manufacturing step without requiring postprocessing and support materials using low-cost and open-source fused deposition modeling (FDM) 3D printers that employ an off-the-shelf commercially available soft thermoplastic poly(urethane) (TPU). The performance of the soft actuators and sensors developed is optimized and predicted using finite element modeling (FEM) analytical models in some cases. A hyperelastic material model is developed for the TPU based on its experimental stress-strain data for use in FEM analysis. The novel soft vacuum bending (SOVA) and linear (LSOVA) actuators reported can be used in diverse robotic applications including locomotion robots, adaptive grippers, parallel manipulators, artificial muscles, modular robots, prosthetic hands, and prosthetic fingers. Also, the novel soft pneumatic sensing chambers (SPSC) developed can be used in diverse interactive human-machine interfaces including wearable gloves for virtual reality applications and controllers for soft adaptive grippers, soft push buttons for science, technology, engineering, and mathematics (STEM) education platforms, haptic feedback devices for rehabilitation, game controllers and throttle controllers for gaming and bending sensors for soft prosthetic hands. These SPSCs are directly 3D printed and embedded in a monolithic soft robotic finger as position and touch sensors for real-time position and force control. One of the aims of soft robotics is to design and fabricate robotic systems with a monolithic topology embedded with its actuators and sensors such that they can safely interact with their immediate physical environment. The results and conclusions of this thesis have significantly contributed to the realization of this aim

Additive manufacturing of multifunctional materials

In the last decade, there have been significant advances on multifunctional materials development through additive manufacturing techniques, boosted by the Industry 4.0 and the Internet of Things revolution. However, in the particular case of the use of lightweight materials, the performance and multifunctionality is sometimes limited. After a short introduction, this chapter provides a comprehensive assessment of those limitations at the same time as the materials, techniques and challenges on the additive manufacturing of multifunctional materials. In the final paragraphs of this work, the future trends will be presented and discussed.FCT- Fundação para a Ciência e Tecnologia- for financial support in the framework of the Strategic Funding UID/FIS/04650/2020 and under project PTDC/BTM-MAT/28237/2017 and PTDC/EMD-EMD/28159/2017. P. Martins (CEECIND/03975/2017- assistant researcher contract Individual Support – 2017 Call) and V. Correia (DL57/2016 junior researcher contract) thank FCT for the contract under the Stimulus of Scientific Employment. The authors acknowledge funding from the Basque Government Industry and Education Department under the ELKARTEK, HAZITEK and PIBA (PIBA-2018-06) programs, respectively. Funding from the European Union’s Horizon 2020 Programme for Research, ICT-02-2018 - Grant agreement no. 824339 – WEARPLE

Thermal and Mechanical Energy Harvesting Using Lead Sulfide Colloidal Quantum Dots

The human body is an abundant source of energy in the form of heat and mechanical movement. The ability to harvest this energy can be useful for supplying low-consumption wearable and implantable devices. Thermoelectric materials are usually used to harvest human body heat for wearable devices; however, thermoelectric generators require temperature gradient across the device to perform appropriately. Since they need to attach to the heat source to absorb the heat, temperature equalization decreases their efficiencies. Moreover, the electrostatic energy harvester, working based on the variable capacitor structure, is the most compatible candidate for harvesting low-frequency-movement of the human body. Although it can provide a high output voltage and high-power density at a small scale, they require an initial start-up voltage source to charge the capacitor for initiating the conversion process. The current methods for initially charging the variable capacitor suffer from the complexity of the design and fabrication process. In this research, a solution-processed photovoltaic structure was proposed to address the temperature equalization problem of the thermoelectric generators by harvesting infrared radiations emitted from the human body. However, normal photovoltaic devices have the bandgap limitation to absorb low energy photons radiated from the human body. In this structure, mid-gap states were intentionally introduced to the absorbing layer to activate the multi-step photon absorption process enabling electron promotion from the valence band to the conduction band. The fabricated device showed promising performance in harvesting low energy thermal radiations emitted from the human body. Finally, in order to increase the generated power, a hybrid structure was proposed to harvest both mechanical and heat energy sources available in the human body. The device is designed to harvest both the thermal radiation of the human body based on the proposed solution-processed photovoltaic structure and the mechanical movement of the human body based on an electrostatic generator. The photovoltaic structure was used to charge the capacitor at the initial step of each conversion cycle. The simple fabrication process of the photovoltaic device can potentially address the problem associated with the charging method of the electrostatic generators. The simulation results showed that the combination of two methods can significantly increase the harvested energy

Advance in Energy Harvesters/Nanogenerators and Self-Powered Sensors

This reprint is a collection of the Special Issue "Advance in Energy Harvesters/Nanogenerators and Self-Powered Sensors" published in Nanomaterials, which includes one editorial, six novel research articles and four review articles, showcasing the very recent advances in energy-harvesting and self-powered sensing technologies. With its broad coverage of innovations in transducing/sensing mechanisms, material and structural designs, system integration and applications, as well as the timely reviews of the progress in energy harvesting and self-powered sensing technologies, this reprint could give readers an excellent overview of the challenges, opportunities, advancements and development trends of this rapidly evolving field