Study made of resistance of stainless steels to zinc-vapor corrosion

Study of the corrosion resistance of several stainless steels to zinc vapor revealed that some stainless steels could be employed for use in zinc processing equipment housings or vapor lines

Frictional and structural characterization of ion-nitrided low and high chromium steels

Low Cr steels AISI 41410, AISI 4340, and high Cr austenitic stainless steels AISI 304, AISI 316 were ion nitrided in a dc glow discharge plasma consisting of a 75 percent H2 - 25 percent N2 mixture. Surface compound layer phases were identified, and compound layer microhardness and diffusion zone microhardness profiles were established. Distinct differences in surface compound layer hardness and diffusion zone profiles were determined between the low and high Cr alloy steels. The high Cr stainless steels after ion nitriding displayed a hard compound layer and an abrupt diffusion zone. The compound layers of the high Cr stainless steels had a columnar structure which accounts for brittleness when layers are exposed to contact stresses. The ion nitrided surfaces of high and low Cr steels displayed a low coefficient of friction with respect to the untreated surfaces when examined in a pin and disk tribotester

Classic and local analysis of corrosion behaviour of graphite and stainless steels in polluted phosphoric acid

In phosphoric acid solution (40% H3PO4), the corrosion behaviour of graphite and stainless steels was studied by the use of different electrochemical methods, namely polarization curve analysis, electrochemical impedance spectroscopy (EIS) and scanning vibrating electrode technique (SVET). The combined effect of chemical impurities and the increase of medium temperature was studied to approach the real conditions in the process of phosphoric acid manufacturing. It was found that the current density measured by polarization curves increased with the presence of chloride and sulphate ions in the acid solution whatever the tested material. Compared to stainless steels, graphite had the best corrosion resistance in polluted phosphoric acid. However, for graphite the increase of temperature from 20 to 80 ◦C induced an increase of the corrosion rate and potential and a decrease of the resistance confirmed by EIS results. Subsequently, local currents were detected at the surface of the sample by using the scanning vibrating electrode technique. From the data obtained, graphite surface manifested a distinctive behaviour from that of stainless steels. A generalized corrosion was occurred on graphite whereas a localized corrosion was observed for stainless steels. These results show a clear interest of graphite as component material in some of the equipments of the phosphoric acid industry

Nitrogen retention/enrichment of 316LN austenitic stainless steel welds

The development of nitrogen enriched austenitic stainless steels has been a source of recent interest due to the abundant availability of nitrogen and by the manner in which nitrogen contributes several beneficial material property effects over a wide service temperature range. It is widely recognised that, in the case of nitrogen enriched 316L, improvements in mechanical property and corrosion resistance are derived from the interstitial influence of nitrogen within the matrix. Consequently, having the best combination of strength, toughness and corrosion resistance relationships found in any group of steels, nitrogen strengthened austenitic stainless steels have tremendous scope for application in areas as diverse as the cryogenic, nuclear, power generation and chemical transportation industries

Duplex and superduplex stainless steels: microstructure and properties evolution by surface modification processes

The paper presents an overview of diffusion surface treatments, especially nitriding processes, applied to duplex and superduplex stainless steels in the last five years. Research has been done mainly to investigate different nitriding processes in order to optimize parameters for the most appropriate procedure. The scope has been to improve mechanical and wear resistance without prejudice to the corrosion properties of the duplex and superduplex stainless steels. Our investigation also aimed to understand the effect of the nitriding layer on the precipitation of secondary phases after any heating step.Peer ReviewedPostprint (published version

Spectrographic analysis of bismuth-tin eutectic alloys by spark-ignited low-voltage ac-arc excitation

Spectrographic method determines individual stainless steel components in molten bismuth-42 w/o tin eutectic to determine the solubility of Type 304 stainless steels. It utilizes the high sensitivity and precision of the spark-ignited, low-voltage ac-arc excitation of samples rendered homogeneous by dissolution

Machining and grinding of ultrahigh-strength steels and stainless steel alloys

Machining and grinding of ultrahigh-strength steels and stainless steel alloy

The susceptibility of six stainless steels to stress corrosion at ambient and elevated temperatures

Stress corrosion of six stainless steels at ambient and elevated temperature

Experimental assessment of ferritic stainless steel composite slabs

This paper describes investigations into the structural behaviour of ferritic stainless steel floor decking in composite construction. Although commonly used in the automotive and industrial sectors, structural applications of ferritic stainless steels are rare owing to a relative lack of knowledge, performance data and design guidance. These materials display considerably better atmospheric corrosion resistance than carbon steels, as well as having good ductility, formability and excellent impact resistance. As part of a wider investigation into the use of ferritic stainless steels in structural applications, an experimental study has been undertaken to assess the viability of using these materials for the profiled decking in composite floors. The shear connection behaviour between the steel beams and the composite slab is clearly critical and this is influenced by the through-deck welding process of the shear connectors. The practicality of this welding technique is assessed and described in this paper. Furthermore, the results of a series of push tests are presented. These enable the resistance of the shear connectors to be established and compared with the strengths specified in EN 1994-1-1 for composite slabs using galvanized steel decking

Stress corrosion cracking evaluation of precipitation-hardening stainless steel

Accelerated test program results show which precipitation hardening stainless steels are resistant to stress corrosion cracking. In certain cases stress corrosion susceptibility was found to be associated with the process procedure