Dual-frequency-comb two-photon spectroscopy

This thesis reports on experimental demonstrations of a novel direct frequency-comb spectroscopic technique for the measurement of one- and two-photon excitation spectra. An optical-frequency-comb generator emits a multitude of highly coherent laser modes whose oscillation frequencies are evenly spaced and uniquely determined by only two measurable and adjustable radio-frequency parameters and the integer-valued mode number. Direct frequency-comb spectroscopy can traditionally be performed by scanning the comb lines of the frequency comb across the transitions of interest and measuring a signal that is proportional to the excitation by all comb lines in concert. Since the modes that contribute to the excitation cannot be singled out, transition frequencies can only be measured modulo the comb-line spacing with this scheme. The so arising limitations are overcome by the technique presented here, where the first frequency comb is spatially overlapped with a second frequency comb. Both combs of this so-called dual-comb setup are ideally identical except for having different carrier-envelope frequencies and slightly different repetition rates. The interference between the two combs leads to beat notes between adjacent comb lines, forming pairs (with one line from each comb) with an effectively modulated excitation amplitudes. Consequently the probability of excitation by any given comb-line pair is also modulated at the respective beat-note frequency. These beat-note frequencies are spaced by the repetition-rate difference and uniquely encode for individual comb-line pairs, thus enabling the identification of the comb lines causing an observed excitation. In a first demonstration, Doppler-limited one-photon excitation spectra of the transitions 5S_{1/2}-5P_{3/2} (at 384 Thz/780 nm), 5P_{3/2}-5D_{3/2}, and 5P_{3/2}-5D_{5/2} (both at 386 Thz/776 nm), and two-photon spectra of the 5S_{1/2}-5D_{5/2} (at 2x385 Thz/2x778 nm) transition, agreeing well with simulated spectra, are simultaneously measured for both stable Rb isotopes. Within an 18-s measurement time, a spectral range of more than 10 THz (20 nm) is covered at a signal-to-noise ratio (SNR) of up to 550. To my knowledge, this is the first demonstration of both dual-comb-based two-photon spectroscopy and fluorescence-based dual-comb spectroscopy. In a follow-up experiment probing the same sample and two-photon transitions, the Doppler-resolution limit is overcome by implementation of an anti-resonant ring configuration. Cancellation of the first-order Doppler effect makes it possible to resolve 33 hyperfine two-photon transitions. The highly resolved (1 MHz point spacing), narrow transition-linewidth (5 MHz), accurate (systematic uncertainty of ~340 kHz), high-SNR (10^4) spectra are shown to be consistent with basic simulation-based predictions. As the spectral span is, in principle, only limited by the bandwidths of the excitation sources, the acquisition of Doppler-free two-photon spectra spanning 10s of THz appears to be in reach. To my knowledge, this is the first demonstration of Doppler-free Fourier-transform spectroscopy. Lastly, the possibility of extending the technique's scope to applications in the field of biochemistry, such as two-photon microscopy, are explored. To that end, first high-speed, low-resolution (>>1 GHz) experiments are carried out identifying comb-stabilization requirements and measurement constraints due to the limited dynamic range of the presented highly multiplexed spectroscopic technique

Investigation into Smart Multifunctional Optical System-On-A-Chip Sensor Platform and Its Applications in Optical Wireless Sensor Networks

Wireless sensor networks (WSNs) have been widely used in various applications to acquire distributed information through cooperative efforts of sensor nodes. Most of the sensor nodes used in WSNs are based on mechanical or electrical sensing mechanisms, which are susceptible to electromagnetic interference (EMI) and can hardly be used in harsh environments. Although these disadvantages of conventional sensor nodes can be overcome by employing optical sensing methods, traditional optical systems are usually bulky and expensive, which can hardly be implemented in WSNs. Recently, the emerging technologies of silicon photonics and photonic crystal promise a solution of integrating a complete optical system through a complementary metal-oxide-semiconductor (CMOS) process. However, such an integration still remains a challenge. The overall objective of this dissertation work is to develop a smart multifunctional optical system-on-a-chip (SOC) sensor platform capable of both phase modulation and wavelength tuningfor heterogeneous sensing, and implement this platform in a sensor node to achieve an optical WSN for various applications, including those in harsh environments. The contributions of this dissertation work are summarized as follows. i)A smart multifunctional optical SOC sensor platform for heterogeneous sensing has beendeveloped for the first time. This platform can be used to perform phase modulation and demodulation in a low coherence interferometric configuration or wavelength tuning in a spectrum sensing configuration.The multifunctional optical sensor platform is developed through hybrid integration of a light source, an optical modulator, and multiple photodetectors. As the key component of the SOC platform, two types of modulators, namely, the opto-mechanical and electro-optical modulators, are investigated. For the first time, interrogating different types of heterogeneous sensors, including various Fabry-Perot (FP) sensors and fiber Bragg grating (FBG) sensors, with a single SOC sensor platform, is demonstrated. ii)Enhanced understanding of the principles of the multifunctional optical platform withanopto-mechanical modulator has been achieved.As a representative of opto-mechanical modulators, a microelectromechanical systems (MEMS) based FP tunable filter is thoroughly investigated through mechanical and optical modeling. The FP tunable filter is studied for both phase modulation and wavelength tuning, and design guidelines are developed based on the modeling and parametric studies. It is found that the MEMS tunable filter can achieve a large modulation depth, but it suffers from a trade-off between modulation depth and speed. iii) A novel silicon electro-optical modulator based on microring structures for optical phase modulation and wavelength tuning has been designed. To overcome the limitations of the opto-mechanical modulators including low modulation speed and mechanical instability, a CMOS compatible high speed electro-optical silicon modulator is designed, which combines microring and photonic crystal structures for phase modulation in interferometric sensors and makes use of two cascaded microrings for wavelength tuning in sensors that require spectrum domain signal processing. iv)A novel optical SOC WSN node has been developed. The optical SOC sensor platform and the associated electric circuit are integrated with a conventional WSN module to achieve an optical WSN node, enabling optical WSNs for various applications. v) A novel cross-axial dual-cavity FP sensor has been developed for simultaneous pressure and temperature sensing.Across-axial sensor is useful in measuring static pressures without picking up dynamic pressures in the presence of surface flows. The dual-cavity sensing structure is used for both temperature and pressure measurements without the need for another temperature sensor for temperature drift compensation. This sensor can be used in moderate to high temperature environments, which demonstrates the potential of using the optical WSN sensor node in a harsh environment

Dual-frequency-comb two-photon spectroscopy

This thesis reports on experimental demonstrations of a novel direct frequency-comb spectroscopic technique for the measurement of one- and two-photon excitation spectra. An optical-frequency-comb generator emits a multitude of highly coherent laser modes whose oscillation frequencies are evenly spaced and uniquely determined by only two measurable and adjustable radio-frequency parameters and the integer-valued mode number. Direct frequency-comb spectroscopy can traditionally be performed by scanning the comb lines of the frequency comb across the transitions of interest and measuring a signal that is proportional to the excitation by all comb lines in concert. Since the modes that contribute to the excitation cannot be singled out, transition frequencies can only be measured modulo the comb-line spacing with this scheme. The so arising limitations are overcome by the technique presented here, where the first frequency comb is spatially overlapped with a second frequency comb. Both combs of this so-called dual-comb setup are ideally identical except for having different carrier-envelope frequencies and slightly different repetition rates. The interference between the two combs leads to beat notes between adjacent comb lines, forming pairs (with one line from each comb) with an effectively modulated excitation amplitudes. Consequently the probability of excitation by any given comb-line pair is also modulated at the respective beat-note frequency. These beat-note frequencies are spaced by the repetition-rate difference and uniquely encode for individual comb-line pairs, thus enabling the identification of the comb lines causing an observed excitation. In a first demonstration, Doppler-limited one-photon excitation spectra of the transitions 5S_{1/2}-5P_{3/2} (at 384 Thz/780 nm), 5P_{3/2}-5D_{3/2}, and 5P_{3/2}-5D_{5/2} (both at 386 Thz/776 nm), and two-photon spectra of the 5S_{1/2}-5D_{5/2} (at 2x385 Thz/2x778 nm) transition, agreeing well with simulated spectra, are simultaneously measured for both stable Rb isotopes. Within an 18-s measurement time, a spectral range of more than 10 THz (20 nm) is covered at a signal-to-noise ratio (SNR) of up to 550. To my knowledge, this is the first demonstration of both dual-comb-based two-photon spectroscopy and fluorescence-based dual-comb spectroscopy. In a follow-up experiment probing the same sample and two-photon transitions, the Doppler-resolution limit is overcome by implementation of an anti-resonant ring configuration. Cancellation of the first-order Doppler effect makes it possible to resolve 33 hyperfine two-photon transitions. The highly resolved (1 MHz point spacing), narrow transition-linewidth (5 MHz), accurate (systematic uncertainty of ~340 kHz), high-SNR (10^4) spectra are shown to be consistent with basic simulation-based predictions. As the spectral span is, in principle, only limited by the bandwidths of the excitation sources, the acquisition of Doppler-free two-photon spectra spanning 10s of THz appears to be in reach. To my knowledge, this is the first demonstration of Doppler-free Fourier-transform spectroscopy. Lastly, the possibility of extending the technique's scope to applications in the field of biochemistry, such as two-photon microscopy, are explored. To that end, first high-speed, low-resolution (>>1 GHz) experiments are carried out identifying comb-stabilization requirements and measurement constraints due to the limited dynamic range of the presented highly multiplexed spectroscopic technique

Optical Gas Sensing: Media, Mechanisms and Applications

Optical gas sensing is one of the fastest developing research areas in laser spectroscopy. Continuous development of new coherent light sources operating especially in the Mid-IR spectral band (QCL—Quantum Cascade Lasers, ICL—Interband Cascade Lasers, OPO—Optical Parametric Oscillator, DFG—Difference Frequency Generation, optical frequency combs, etc.) stimulates new, sophisticated methods and technological solutions in this area. The development of clever techniques in gas detection based on new mechanisms of sensing (photoacoustic, photothermal, dispersion, etc.) supported by advanced applied electronics and huge progress in signal processing allows us to introduce more sensitive, broader-band and miniaturized optical sensors. Additionally, the substantial development of fast and sensitive photodetectors in MIR and FIR is of great support to progress in gas sensing. Recent material and technological progress in the development of hollow-core optical fibers allowing low-loss transmission of light in both Near- and Mid-IR has opened a new route for obtaining the low-volume, long optical paths that are so strongly required in laser-based gas sensors, leading to the development of a novel branch of laser-based gas detectors. This Special Issue summarizes the most recent progress in the development of optical sensors utilizing novel materials and laser-based gas sensing techniques

Ultrafast pulse dynamics in low noise Tm/Ho doped mode-locked fiber lasers

Mode-locked fiber lasers have attracted significant scientific and commercial interest since they offer a compact and highly stable platform with straightforward operation for exploiting ultrafast and nonlinear phenomena. They have enabled a vast range of applications that span from distinct disciplines such as medical diagnostics, molecular spectroscopy, and high-power precise mechanical cutting, to optical metrology. Various gain media have been utilized to achieve laser emission at different wavelengths. We have developed unique thulium/holmium (Tm/Ho) doped mode-locked fiber laser systems to address the needs of low-noise ultrafast optical sources in the wavelength vicinity of 2 μm at higher repetition rates. Since the 2 μm wavelength regime has recently attracted more attention with the emergence of thulium gain fibers, the rich underlying cavity dynamics, novel pulse operation regimes and nonlinear phenomena in compact fiber configurations have not been fully explored yet. In this thesis, research is conducted on novel Tm fiber laser cavity configurations and on the formation of unique, polarization-based pulsing regimes. Particularly, this research is focused on the exploration of novel ultrafast and nonlinear phenomena, and the development of optical sources emitting unprecedented ultrafast pulse trains beyond conventional equal-intensity distribution using Tm/Ho doped gain media. The research presented features four main results: 1) development of a high repetition rate and low-noise Tm/Ho doped mode-locked fiber laser platform as an attractive optical source for a wide variety of applications 2) investigation of a novel mode-locked state in which the ultrafast pulse train is composed of co-generated, consecutive, equal intensity and orthogonally polarized pulses in order to achieve dual RF comb generation for dual-comb spectroscopy applications, 3) exploration of controllable ultrafast waveform generation utilizing vector soliton and harmonic mode-locking mechanisms for optical telecommunication applications, and 4) demonstration of unique transitional mode-locked states showing exceptional features such as powerful irregular bursts of ultrafast pulses and rogue wave behavior without damaging the laser elements. The aim of these projects has been to explore the novel optical properties of Tm/Ho co-doped fiber lasers in order to achieve advanced functionalities in commonly practiced applications such as telecommunication, metrology and spectroscopic applications.2019-10-22T00:00:00

Modern Applications in Optics and Photonics: From Sensing and Analytics to Communication

Optics and photonics are among the key technologies of the 21st century, and offer potential for novel applications in areas such as sensing and spectroscopy, analytics, monitoring, biomedical imaging/diagnostics, and optical communication technology. The high degree of control over light fields, together with the capabilities of modern processing and integration technology, enables new optical measurement systems with enhanced functionality and sensitivity. They are attractive for a range of applications that were previously inaccessible. This Special Issue aims to provide an overview of some of the most advanced application areas in optics and photonics and indicate the broad potential for the future

Highly Multiplexed Superconducting Detectors and Readout Electronics for Balloon-Borne and Ground-Based Far-Infrared Imaging and Polarimetry

abstract: This dissertation details the development of an open source, frequency domain multiplexed (FDM) readout for large-format arrays of superconducting lumped-element kinetic inductance detectors (LEKIDs). The system architecture is designed to meet the requirements of current and next generation balloon-borne and ground-based submillimeter (sub-mm), far-infrared (FIR) and millimeter-wave (mm-wave) astronomical cameras, whose science goals will soon drive the pixel counts of sub-mm detector arrays from the kilopixel to the megapixel regime. The in-flight performance of the readout system was verified during the summer, 2018 flight of ASI's OLIMPO balloon-borne telescope, from Svalbard, Norway. This was the first flight for both LEKID detectors and their associated readout electronics. In winter 2019/2020, the system will fly on NASA's long-duration Balloon Borne Large Aperture Submillimeter Telescope (BLAST-TNG), a sub-mm polarimeter which will map the polarized thermal emission from cosmic dust at 250, 350 and 500 microns (spatial resolution of 30", 41" and 59"). It is also a core system in several upcoming ground based mm-wave instruments which will soon observe at the 50 m Large Millimeter Telescope (e.g., TolTEC, SuperSpec, MUSCAT), at Sierra Negra, Mexico. The design and verification of the FPGA firmware, software and electronics which make up the system are described in detail. Primary system requirements are derived from the science objectives of BLAST-TNG, and discussed in the context of relevant size, weight, power and cost (SWaP-C) considerations for balloon platforms. The system was used to characterize the instrumental performance of the BLAST-TNG receiver and detector arrays in the lead-up to the 2019/2020 flight attempt from McMurdo Station, Antarctica. The results of this characterization are interpreted by applying a parametric software model of a LEKID detector to the measured data in order to estimate important system parameters, including the optical efficiency, optical passbands and sensitivity. The role that magnetic fields (B-fields) play in shaping structures on various scales in the interstellar medium is one of the central areas of research which is carried out by sub-mm/FIR observatories. The Davis-Chandrasekhar-Fermi Method (DCFM) is applied to a BLASTPol 2012 map (smoothed to 5') of the inner ~1.25 deg2 of the Carina Nebula Complex (CNC, NGC 3372) in order to estimate the strength of the B-field in the plane-of-the-sky (B-pos). The resulting map contains estimates of B-pos along several thousand sightlines through the CNC. This data analysis pipeline will be used to process maps of the CNC and other science targets which will be produced during the upcoming BLAST-TNG flight. A target selection survey of five nearby external galaxies which will be mapped during the flight is also presented.Dissertation/ThesisDoctoral Dissertation Astrophysics 201

Spatially integrated erbium-doped fiber amplifiers enabling space-division multiplexing

L'augmentation exponentielle de la demande de bande passante pour les communications laisse présager une saturation prochaine de la capacité des réseaux de télécommunications qui devrait se matérialiser au cours de la prochaine décennie. En effet, la théorie de l’information prédit que les effets non linéaires dans les fibres monomodes limite la capacité de transmission de celles-ci et peu de gain à ce niveau peut être espéré des techniques traditionnelles de multiplexage développées et utilisées jusqu’à présent dans les systèmes à haut débit. La dimension spatiale du canal optique est proposée comme un nouveau degré de liberté qui peut être utilisé pour augmenter le nombre de canaux de transmission et, par conséquent, résoudre cette menace de «crise de capacité». Ainsi, inspirée par les techniques micro-ondes, la technique émergente appelée multiplexage spatial (SDM) est une technologie prometteuse pour la création de réseaux optiques de prochaine génération. Pour réaliser le SDM dans les liens de fibres optiques, il faut réexaminer tous les dispositifs intégrés, les équipements et les sous-systèmes. Parmi ces éléments, l'amplificateur optique SDM est critique, en particulier pour les systèmes de transmission pour les longues distances. En raison des excellentes caractéristiques de l'amplificateur à fibre dopée à l'erbium (EDFA) utilisé dans les systèmes actuels de pointe, l'EDFA est à nouveau un candidat de choix pour la mise en œuvre des amplificateurs SDM pratiques. Toutefois, étant donné que le SDM introduit une variation spatiale du champ dans le plan transversal de la fibre, les amplificateurs à fibre dopée à l'erbium spatialement intégrés (SIEDFA) nécessitent une conception soignée. Dans cette thèse, nous examinons tout d'abord les progrès récents du SDM, en particulier les amplificateurs optiques SDM. Ensuite, nous identifions et discutons les principaux enjeux des SIEDFA qui exigent un examen scientifique. Suite à cela, la théorie des EDFA est brièvement présentée et une modélisation numérique pouvant être utilisée pour simuler les SIEDFA est proposée. Sur la base d'un outil de simulation fait maison, nous proposons une nouvelle conception des profils de dopage annulaire des fibres à quelques-modes dopées à l'erbium (ED-FMF) et nous évaluons numériquement la performance d’un amplificateur à un étage, avec fibre à dopage annulaire, à ainsi qu’un amplificateur à double étage pour les communications sur des fibres ne comportant que quelques modes. Par la suite, nous concevons des fibres dopées à l'erbium avec une gaine annulaire et multi-cœurs (ED-MCF). Nous avons évalué numériquement le recouvrement de la pompe avec les multiples cœurs de ces amplificateurs. En plus de la conception, nous fabriquons et caractérisons une fibre multi-cœurs à quelques modes dopées à l'erbium. Nous réalisons la première démonstration des amplificateurs à fibre optique spatialement intégrés incorporant de telles fibres dopées. Enfin, nous présentons les conclusions ainsi que les perspectives de cette recherche. La recherche et le développement des SIEDFA offriront d'énormes avantages non seulement pour les systèmes de transmission future SDM, mais aussi pour les systèmes de transmission monomode sur des fibres standards à un cœur car ils permettent de remplacer plusieurs amplificateurs par un amplificateur intégré.The exponential increase of communication bandwidth demand is giving rise to the so-called ‘capacity crunch’ expected to materialize within the next decade. Due to the nonlinear limit of the single mode fiber predicted by the information theory, all the state-of-the-art techniques which have so far been developed and utilized in order to extend the optical fiber communication capacity are exhausted. The spatial domain of the lightwave links is proposed as a new degree of freedom that can be employed to increase the number of transmission paths and, subsequently, overcome the looming ‘capacity crunch’. Therefore, the emerging technique named space-division multiplexing (SDM) is a promising candidate for creating next-generation optical networks. To realize SDM in optical fiber links, one needs to investigate novel spatially integrated devices, equipment, and subsystems. Among these elements, the SDM amplifier is a critical subsystem, in particular for the long-haul transmission system. Due to the excellent features of the erbium-doped fiber amplifier (EDFA) used in current state-of-the-art systems, the EDFA is again a prime candidate for implementing practical SDM amplifiers. However, since the SDM introduces a spatial variation of the field in the transverse plane of the optical fibers, spatially integrated erbium-doped fiber amplifiers (SIEDFA) require a careful design. In this thesis, we firstly review the recent progress in SDM, in particular, the SDM optical amplifiers. Next, we identify and discuss the key issues of SIEDFA that require scientific investigation. After that, the EDFA theory is briefly introduced and a corresponding numerical modeling that can be used for simulating the SIEDFA is proposed. Based on a home-made simulation tool, we propose a novel design of an annular based doping profile of few-mode erbium-doped fibers (FM-EDF) and numerically evaluate the performance of single stage as well as double-stage few-mode erbium-doped fiber amplifiers (FM-EDFA) based on such fibers. Afterward, we design annular-cladding erbium-doped multicore fibers (MC-EDF) and numerically evaluate the cladding pumped multicore erbium-doped fiber amplifier (MC-EDFA) based on these fibers as well. In addition to fiber design, we fabricate and characterize a multicore few-mode erbium-doped fiber (MC-FM-EDF), and perform the first demonstration of the spatially integrated optical fiber amplifiers incorporating such specialty doped fibers. Finally, we present the conclusions as well as the perspectives of this research. In general, the investigation and development of the SIEDFA will bring tremendous benefits not only for future SDM transmission systems but also for current state-of-the-art single-mode single-core transmission systems by replacing plural amplifiers by one integrated amplifier

Novel Specialty Optical Fibers and Applications

Novel Specialty Optical Fibers and Applications focuses on the latest developments in specialty fiber technology and its applications. The aim of this reprint is to provide an overview of specialty optical fibers in terms of their technological developments and applications. Contributions include:1. Specialty fibers composed of special materials for new functionalities and applications in new spectral windows.2. Hollow-core fiber-based applications.3. Functionalized fibers.4. Structurally engineered fibers.5. Specialty fibers for distributed fiber sensors.6. Specialty fibers for communications

High-Resolution Molecular Spectroscopy With An Optical Frequency Comb

Optical spectroscopy provides a window into the world of molecules and their environment by the absorption of electric dipole radiation with frequencies characteristic to each molecular species. The temperature, concentration, and pressures of molecules in a gas sample can theoretically be obtained through examination of optical absorption spectra. This is provided the spectrum is of high enough resolution and sufficient bandwidth that the complicated molecular absorption spectrum may be observed, particularly in cases with multiple molecular species present in a sample. The invention of a fully-stabilised optical frequency comb in recent decades has revolutionised molecular spectroscopy. It provides a near-ideal spectral interrogation source for the high-resolution study of molecules, combining absolute frequency accuracy, broad singleshot bandwidth, and dense spectral sampling. The comb light is contained within a single beam, and must be dispersed into its component frequencies in order for a molecular spectrum to be extracted. There are numerous methods to perform this, with the technique employed in this thesis utilising a dispersive spectrometer based on a virtually imaged phased array. The spectrometer spreads the comb light from a single beam into a two-dimensional array of its component frequencies, allowing the power of each comb frequency to be measured. This thesis details the development and construction of a virtually imaged phased array spectrometer system for use with an optical frequency comb. Additionally, code that extracts the traditional absorption spectrum from the two-dimensional arrays of frequencies produced by the spectrometer were developed and demonstrated, along with a model to extract physical parameters of molecules. The theoretical basis to model the characteristic absorption fingerprints is presented for each of the molecules examined in the course of this thesis (hydrogen cyanide, carbon dioxide, and acetylene), as well as the differences in spectra caused by changes to the pressure, temperature, and concentration of molecules in the sample. The results chapters walk through the development of the spectrometer into a reliable system capable of rapidly acquiring high-quality molecular spectra from which highly accurate and precise measurements of concentration and temperature were demonstrated. The capability of the system to easily differentiate between isotopologues of the same species in the same sample makes this spectrometer a powerful spectroscopic tool that, with further development, may find use in out-of-lab applications such as medical breath analysis and environmental monitoring. Additionally, the demonstrated capability to measure extremely high-resolution spectra beyond the resolution limit of the spectrometer may find use in measurements of the thermodynamic properties of molecules.Thesis (Ph.D.) -- University of Adelaide, School of Physical Sciences, 201